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公开(公告)号:AU2095497A
公开(公告)日:1997-09-22
申请号:AU2095497
申请日:1997-03-05
Applicant: BASF AG
Inventor: MULLER ULRICH , SCHULZ MICHAEL , MAROSI LASZLO , HARDER WOLFGANG
IPC: C07D301/08 , B01J27/18 , B01J27/185 , B01J27/24 , B01J37/02 , C01B15/029 , C07D301/12
Abstract: PCT No. PCT/EP97/01113 Sec. 371 Date Sep. 4, 1998 Sec. 102(e) Date Sep. 4, 1998 PCT Filed Mar. 5, 1997 PCT Pub. No. WO97/32866 PCT Pub. Date Sep. 12, 1997A noble metal-free catalyst composition is obtainable by a) preparing an aqueous mixture comprising i) a salt of at least one base metal selected from among the elements having atomic numbers 21-32, 39-42, 48-51, 57-75 and 81-83; ii) phosphate ions; and iii) at least one nitrogen source; and b) evaporating the aqueous mixture obtained and drying the catalyst composition thus formed. The catalyst composition prepared can be used for producing hydrogen peroxide and for the epoxidation of olefins.
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公开(公告)号:GC0000315A
公开(公告)日:2006-11-01
申请号:GCP20021802
申请日:2002-01-08
Applicant: BASF AG
Inventor: VANOPPEN DOMINIC , SCHWAB EKKEHARD , BASSET JEAN-MARIE , THIVOLLE-CAZAT JEAN , TAOUFIK MOSTAPHA , SCHULZ MICHAEL , HOEHN ARTHUR
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公开(公告)号:CA2248545C
公开(公告)日:2005-11-08
申请号:CA2248545
申请日:1997-03-05
Applicant: BASF AG
Inventor: MAROSI LASZLO , MULLER ULRICH , HARDER WOLFGANG , SCHULZ MICHAEL
IPC: C07D301/08 , B01J27/18 , B01J27/185 , B01J27/24 , B01J37/02 , C01B15/029 , C07D301/12 , C07B33/00 , C07C39/04 , C07D303/04 , C07C37/60
Abstract: The invention concerns a catalyst composition which is free from noble metal s and is obtained by: a) preparing an aqueous mixture which comprises: i) a sa lt of at least one base metal selected from elements having the atomic numbers 21 to 32, 39 to 42, 48 to 51, 57 to 75 and 81 to 83; ii) phosphate ions; and ii i) at least one nitrogen source; and b) concentrating the aqueous mixture produced and drying the resultant catalyst compound. The invention further concerns the preparation of this composition and its use in the production o f hydrogen peroxide and the epoxidation of olefins.
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公开(公告)号:AT280147T
公开(公告)日:2004-11-15
申请号:AT99968384
申请日:1999-12-23
Applicant: BASF AG
Inventor: DAHLHAUS JUERGEN , KARL JOERN , SCHULZ MICHAEL , WENZEL ANNE , HARDER WOLFGANG , HOEHN ARTHUR
IPC: B01J23/04 , B01J31/40 , C07B61/00 , C07C231/10 , C07C233/03
Abstract: In the process for preparing formamide by reaction of ammonia and carbon monoxide in the presence of at least one catalyst, sodium diformylamide is used as catalyst. If sodium methoxide is used as further active component, sodium diformylamide can be formed from this. In this process, sodium diformylamide is a particularly active and stable catalyst which can be recycled.
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公开(公告)号:AT230722T
公开(公告)日:2003-01-15
申请号:AT99946100
申请日:1999-09-02
Applicant: BASF AG
Inventor: SLANY MICHAEL , SCHAEFER MARTIN , SCHULZ MICHAEL
IPC: B01J31/24 , C07B61/00 , C07C253/30 , C07C255/19 , C07F9/6568 , C07F15/00
Abstract: The process comprises reacting 2-, 3- or 4-pentenenitrile or mixtures thereof with carbon monoxide and a hydroxyl compound in the presence of a catalyst system comprising (i) a palladium(II) compound, (ii) a bidentate diphosphine ligand and (iii) an anion source. Novel catalyst systems containing diphosphine ligands of the bis(phosphinomethyl)amine type are also described.
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公开(公告)号:DE10100485A1
公开(公告)日:2002-08-01
申请号:DE10100485
申请日:2001-01-08
Applicant: BASF AG
Inventor: VANOPPEN DOMINIC , SCHWAB EKKEHARD , BASSET JEAN-MARIE , THIVOLLE-CAZAT JEAN , TAOUFIK MOSTAPHA , SCHULZ MICHAEL , HOEHN ARTHUR
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公开(公告)号:NO20020349D0
公开(公告)日:2002-01-23
申请号:NO20020349
申请日:2002-01-23
Applicant: BASF AG
Inventor: AUER HEINZ , DAHLHAUS JUERGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
IPC: B01J3/00 , B01D3/00 , B01J3/02 , B01J19/00 , C07B61/00 , C07C29/80 , C07C31/04 , C07C67/36 , C07C69/06 , C07C
Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.
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公开(公告)号:ES2162300T3
公开(公告)日:2001-12-16
申请号:ES97925025
申请日:1997-05-30
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH , MUELLER ULRICH , SCHULZ MICHAEL , RIEBER NORBERT , WUERZ HARALD
IPC: C07D301/06 , B01J29/04 , B01J29/89 , C07D301/04 , C07D301/10 , C07D303/04
Abstract: PCT No. PCT/EP97/02821 Sec. 371 Date Dec. 14, 1998 Sec. 102(e) Date Dec. 14, 1998 PCT Filed May 30, 1997 PCT Pub. No. WO97/47386 PCT Pub. Date Dec. 18, 1997An oxidation catalyst based on titanium silicalites or vanadium silicalites having a zeolite structure and containing from 0.01 to 30% by weight of one or more noble metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver has been molded by a compacting shaping process. This oxidation catalyst is used for the preparation of epoxides, in particular propylene oxide, from olefins, hydrogen and oxygen.
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公开(公告)号:ES2160323T3
公开(公告)日:2001-11-01
申请号:ES97903335
申请日:1997-02-20
Applicant: BASF AG
Inventor: MULLER ULRICH , BROCKER FRANZ JOSEF , GROSCH GEORG HEINRICH , PUTTER HERMANN , SCHULZ MICHAEL , RIEBER NORBERT
IPC: B01J21/06 , B01J23/22 , B01J29/04 , B01J29/89 , B01J35/04 , B01J35/06 , B01J37/02 , C01B15/029 , C01B21/14 , C07D301/12
Abstract: PCT No. PCT/EP97/00804 Sec. 371 Date Aug. 26, 1998 Sec. 102(e) Date Aug. 26, 1998 PCT Filed Feb. 20, 1997 PCT Pub. No. WO97/31711 PCT Pub. Date Sep. 4, 1997The present invention relates to a gauze catalyst based on titanium or vanadium zeolites and inert gauze fabrics which is suitable for accelerating oxidation reactions such as epoxidation of olefins, hydrogen peroxide production or hydroxylamine synthesis.
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公开(公告)号:DE59704251D1
公开(公告)日:2001-09-13
申请号:DE59704251
申请日:1997-05-30
Applicant: BASF AG
Inventor: GROSCH GEORG HEINRICH , MUELLER ULRICH , SCHULZ MICHAEL , RIEBER NORBERT , WUERZ HARALD
IPC: C07D301/06 , B01J29/04 , B01J29/89 , C07D301/04 , C07D301/10 , C07D303/04
Abstract: PCT No. PCT/EP97/02821 Sec. 371 Date Dec. 14, 1998 Sec. 102(e) Date Dec. 14, 1998 PCT Filed May 30, 1997 PCT Pub. No. WO97/47386 PCT Pub. Date Dec. 18, 1997An oxidation catalyst based on titanium silicalites or vanadium silicalites having a zeolite structure and containing from 0.01 to 30% by weight of one or more noble metals selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver has been molded by a compacting shaping process. This oxidation catalyst is used for the preparation of epoxides, in particular propylene oxide, from olefins, hydrogen and oxygen.
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