公开(公告)号：DE4127733A1

公开(公告)日：1993-02-25

申请号：DE4127733

申请日：1991-08-22

Applicant: BASF AG

Inventor： HARTMANN HEINRICH ,  DENZINGER WALTER ,  KROENER MICHAEL ,  NILZ CLAUDIA ,  LINHARDT FRIEDRICH ,  STANGE ANDREAS

IPC: C08F251/02 ,  C08F251/00 ,  D21H17/34 ,  D21H17/35 ,  D21H17/37 ,  D21H21/18

Abstract: (1) Graft polymers (I) obtainable by polymerisation of (A) monomers or monomer mixts. comprising (A1) 10-100 % (all pts. wt.) N-vinylcarboxylic amides. CH2=CH-N(R2)C(O)R' (1), where R1, R2 = H or 1-6 C alkyl (A2) 0-90 % other monoethylenically unsatd., carboxylic gp.-free monomer copolymerisation with (A1) (A3) 0-5 % monomer with at least 2 ethylenically unsatd., non-conjugated double bonds in mol. in presence of (B) mono-, oligo-, or poly-saccharide; oxidatively, hydrolytically, or enzymatically degraded polysaccharide; oxidatively-hydrolytically or oxidatively-enzymatically degraded polysaccharide; chemically modified mono-, oligo-, or poly-sacchardie, or mixt. of these in ratio (A):(B) = 95-20:5-80 and op. subsequent splitting off of gp. -C(:O)R1 from polymerised monomers (A) of (I) with formation of units -CH2-CNHR2H- are claimed. (2) Also claimed are (I) obtainable by process wherein mixt. of 1-99 % N-vinylformamide (II) and 99-1 % vinyl acetate (III) is used as (A), 2-100 % formyl gps. of polymerised (II) are split off with formation of units -CH2-C(NH2)H- (3) and 2-100 % acetate gps. of polymerisated (III) and split off with formation of units -CH20C(OH)H- (4). USE/ADVANTAGE - Dry- and wet-stength agents in prepn. of paper, carboard, and paperboard, (I), prepd. partly with renewable raw materials, are less expensi

公开(公告)号：CA2186289C

公开(公告)日：2008-01-29

申请号：CA2186289

申请日：1995-03-11

Applicant: BASF AG

Inventor： HARTMANN HEINRICH ,  DENZINGER WALTER ,  NILZ CLAUDIA

IPC: C08F271/00 ,  C05G3/00 ,  C08F263/00 ,  C08F265/00 ,  C09B67/00 ,  C09B67/46 ,  C09D17/00 ,  C09K17/20 ,  C09K23/00 ,  C09K23/52 ,  C11D3/37 ,  D21H17/34 ,  D21H21/20

Abstract: Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least % by weight of units of the formulae (see formulae I and II) where R1 and R2 are each H or C1-C6-alkyl, monoethylenically un-saturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5 % strength by weight aqueous solution at 25.degree.C and pH 7), are prepared by poly-merization of monoethylenically unsaturated monomers in the pres-ence of polymers which in each case contain at least 5 % by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as disper-sants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.

公开(公告)号：CA2143747C

公开(公告)日：2005-03-22

申请号：CA2143747

申请日：1993-09-23

Applicant: BASF AG

Inventor： NILZ CLAUDIA ,  SENDHOFF NORBERT ,  BREITSCHAFT WALTER ,  ZILLIG MANFRED ,  LORENCAK PRIMOZ

IPC: D21H17/34 ,  D21H21/28 ,  D21H17/72 ,  D21H17/03 ,  D21H17/45

Abstract: a process for dyeing paper in connection with paper manufacture by adding water-soluble anionic dyes and cationic polymers which contain vinylamine units to the paper pulp as fixing agents and removing water from the paper pulp with the formation of dyed paper is described.

公开(公告)号：AT250638T

公开(公告)日：2003-10-15

申请号：AT96914965

申请日：1996-04-20

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  RUEBENACKER MARTIN ,  NILZ CLAUDIA ,  LORENCAK PRIMOZ ,  MOENCH DIETMAR ,  SCHUHMACHER RUDOLF ,  STANGE ANDREAS

IPC: C08B31/12 ,  C08F8/12 ,  C08F283/00 ,  C08F283/06 ,  C09B67/46 ,  C09D17/00 ,  D21H17/34 ,  D21H17/53 ,  D21H19/20 ,  D21H21/10 ,  D21H21/16 ,  D21H21/18

公开(公告)号：DK0884945T3

公开(公告)日：2002-07-15

申请号：DK97908173

申请日：1997-03-04

Applicant: BASF AG

Inventor： GEBHARDT NORBERT ,  ZELLER DIETER ,  NILZ CLAUDIA ,  STEUERLE ULRICH ,  JOHANSEN CHARLOTTE

IPC: A01N25/10 ,  A01N33/04 ,  A01N25/04 ,  A01N37/18 ,  A01N37/34 ,  A01N43/50 ,  A01N61/00

Abstract: The use of polymers (I) as biocides is new, where (I) comprises: (a) 0.1-100 mol. % vinylamine (VA) or ethyleneimine units; (b) 0-99.9 mol.% units derived from at least one monomer selected from N-vinylcarboxamides of formula CH2=CH-N(R1)-CO-R2 (II), vinyl formate, vinyl acetate, vinyl propionate, vinyl alcohol, (1-6C) alkyl-vinyl ethers, monoethylenically unsaturated 3-8C carboxylic acids, or their esters, nitriles, amides and anhydrides, N-vinylurea, N-vinylimidazoles and N-vinylimidazolines; and (c) 0-5 mol.% units derived from monomers with at least two ethylenically unsaturated double bonds. The sum of (a)-(c) is 100 mol.%. R1, R2 = H or 1-6C alkyl.

公开(公告)号：ES2168613T3

公开(公告)日：2002-06-16

申请号：ES97909334

申请日：1997-09-29

Applicant: BASF AG

Inventor： NIESSNER MANFRED ,  NILZ CLAUDIA ,  HOSSEL PETER ,  KOTHRADE STEPHAN ,  SANNER AXEL

IPC: A61K8/00 ,  A61K8/36 ,  A61K8/42 ,  A61K8/49 ,  A61K8/72 ,  A61K8/81 ,  A61K8/898 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/10 ,  A61Q5/12 ,  A61Q11/00 ,  A61Q19/00 ,  C08F226/02 ,  C08F226/06 ,  A61K7/06 ,  A61K7/48

Abstract: A cosmetic composition comprising water-soluble copolymer, which as characteristic structural elements comprisesa) vinylcarboxamide units of the general formula IwhereR1 and R2 independently of one another are H, alkyl, cycloalkyl, aryl or aralkyl, andb) units of the general formula IIwhereA is a chemical bond or an alkylene group,the radicals R3 independently of one another are H, alkyl, cycloalkyl, aryl or aralkyl, or together with the nitrogen atom to which they are bonded, form an unsubstituted, mono- or polysubstituted, five- to seven-membered, heterocyclic, aromatic or nonaromatic ring, which if appropriate contains one or two further heteroatoms, selected from among O, N and S, it being possible for the heterocyclic ring to be fused to a further five- or six-membered, aromatic or nonaromatic ring,R4 is H, alkyl or aralkyl.

公开(公告)号：DK0915915T3

公开(公告)日：2002-02-25

申请号：DK97935551

申请日：1997-07-29

Applicant: BASF AG

Inventor： NIESSNER MANFRED ,  RUEBENACKER MARTIN ,  NILZ CLAUDIA ,  HOESSEL PETER

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/81 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/10 ,  A61Q5/12 ,  A61Q11/00 ,  A61Q19/00 ,  C08F8/00 ,  C08F22/38 ,  C08F26/02 ,  C08F226/02 ,  C08F271/00 ,  A61K7/06

公开(公告)号：DE59703956D1

公开(公告)日：2001-08-09

申请号：DE59703956

申请日：1997-02-20

Applicant: BASF AG

Inventor： NIESSNER MANFRED ,  NILZ CLAUDIA ,  UTECHT JENS ,  RUEBENACKER MARTIN ,  SCHUHMACHER RUDOLF

IPC: C08F8/12 ,  C08F26/02 ,  D21H17/34 ,  D21H17/37 ,  D21H17/45 ,  D21H21/18

Abstract: PCT No. PCT/EP97/00801 Sec. 371 Date Aug. 31, 1998 Sec. 102(e) Date Aug. 31, 1998 PCT Filed Feb. 20, 1997 PCT Pub. No. WO97/31518 PCT Pub. Date Sep. 4, 1997Partially hydrolyzed polymers of N-vinylcarboxamides obtainable by sole polymerization of N-vinylcarboxamides of the formula where R1 and R2 are each hydrogen or C1- to C6-alkyl, and elimination from the polymers of from 0.5 to 95 mol % of the groups of the formula where R1 is hydrogen or C1- to C6-alkyl, can be used as paper, paperboard and cardboard dry strength enhancers.

公开(公告)号：DE59606319D1

公开(公告)日：2001-02-15

申请号：DE59606319

申请日：1996-07-09

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  RUEBENACKER MARTIN ,  NILZ CLAUDIA ,  LORENCAK PRIMOZ ,  MOENCH DIETMAR ,  SCHUHMACHER RUDOLF ,  STANGE ANDREAS

IPC: C08B37/00 ,  C08F8/12 ,  C08F261/04 ,  C08F263/02 ,  C08F283/06 ,  C08F291/00 ,  C09D7/45 ,  D21H17/34 ,  D21H17/37 ,  D21H21/10 ,  D21H21/14 ,  D21H21/16 ,  D21H21/18

Abstract: PCT No. PCT/EP96/02991 Sec. 371 Date Jan. 21, 1998 Sec. 102(e) Date Jan. 21, 1998 PCT Filed Jul. 9, 1996 PCT Pub. No. WO97/04014 PCT Pub. Date Feb. 6, 1997Graft polymers are obtainable by free radical polymerization of (A) monomers or monomer mixtures comprising (a) from 1 to 100% by weight of N-vinylcarboxamides of the formula where R1 and R2 are each H or C1-C6-alkyl, (b) from 0 to 99% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule, in the presence of (B) polymers which contain units of vinyl esters of saturated C1-C4-carboxylic acids and/or vinyl alcohol units, or of mixtures which contain these polymers and polymers having at least 3 alkylene oxide units or polytetrahydrofuran, in a weight ratio (A):(B) of from 95:5 to 10:90 and, if required, subsequent elimination of the group from the polymerized monomers (I) of the graft polymer with formation of units of the formula and the graft polymers described above are used in the production of paper, board and cardboard as dry and wet strength agents, as retention and drainage aids and as promoters in diketene sizing and as starch cationization agents, as dispersants for pigments and as creping assistants in the production of tissue papers.

公开(公告)号：DE59701734D1

公开(公告)日：2000-06-21

申请号：DE59701734

申请日：1997-08-21

Applicant: BASF AG

Inventor： UTECHT JENS ,  RUEBENACKER MARTIN ,  NILZ CLAUDIA ,  RAHM RAINER

IPC: B01J20/26 ,  B01J45/00 ,  C08F8/00

Abstract: PCT No. PCT/EP97/04545 Sec. 371 Date Mar. 11, 1999 Sec. 102(e) Date Mar. 11, 1999 PCT Filed Aug. 21, 1997 PCT Pub. No. WO98/11145 PCT Pub. Date Mar. 19, 1998An insoluble, only slight swellable, polymer having modified amino groups, which contain units of the formulae: or both (I) and (II), wherein R1, R2, R3 and Me are as defined herein.