公开(公告)号：CZ23899A3

公开(公告)日：1999-04-14

申请号：CZ23899

申请日：1997-07-23

Applicant: BASF AG

Inventor： FISCHER ROLF ,  PACIELLO ROCCO ,  ROPER MICHAEL ,  SCHNURR WERNER

IPC: B01J31/18 ,  B01J31/24 ,  C07C209/26 ,  C07C253/30 ,  C07C255/24 ,  C07F9/6574

Abstract: PCT No. PCT/EP97/03988 Sec. 371 Date Feb. 1, 1999 Sec. 102(e) Date Feb. 1, 1999 PCT Filed Jul. 23, 1997 PCT Pub. No. WO98/05632 PCT Pub. Date Feb. 12, 1998Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst from the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5-formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6-aminocapronitrile and if necessary hexamethylene diamine.

公开(公告)号：AU6828998A

公开(公告)日：1998-10-12

申请号：AU6828998

申请日：1998-03-06

Applicant: BASF AG

Inventor： KANAND JURGEN ,  PACIELLO ROCCO ,  ROPER MICHAEL

IPC: C07C27/06 ,  C07B61/00 ,  C07C29/132 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C41/54 ,  C07C45/51 ,  C07C47/02 ,  C07C43/303

Abstract: PCT No. PCT/EP98/01324 Sec. 371 Date Sep. 15, 1999 Sec. 102(e) Date Sep. 15, 1999 PCT Filed Mar. 6, 1998 PCT Pub. No. WO98/41494 PCT Pub. Date Sep. 24, 1998Process for the preparation of n-butyraldehyde and/or n-butanol, wherein a) 1,3-Butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of the formula IROHI, where R is C2-C20-alkyl or alkenyl which is unsubstituted or substituted by 1 or 2 C1-C10-alkoxy or hydroxyl groups, or is C6-C10-aryl, C7-C11-aralkyl or methyl, at elevated temperatures and superatmospheric pressure in the presence of a Br+E,uml o+EE nsted acid or in the presence of a complex of an element of Group Ia, VIIA or VIIIA of the Periodic Table of Elements with phosphorus- or nitrogen-containing ligands to give a mixture of the adducts of the formulae II and III b) the adduct III is isomerized to the adduct II, c) the adduct II is converted into the acetal of the formula IV d) n-butyraldehyde and/or n-butanol are then produced from this acetal IV by reacting it, in the liquid phase, with hydrogen and water or water in the presence of a homogeneous or heterogeneous transition metal catalyst which differs from dicobaltoctacarbonyl or hydridocobalttetracarbonyl.

公开(公告)号：AU1195797A

公开(公告)日：1997-07-17

申请号：AU1195797

申请日：1996-12-16

Applicant: BASF AG

Inventor： ROPER MICHAEL ,  GEISSLER BERNHARD ,  LANGGUTH ERNST ,  KNEUPER HEINZ-JOSEF

IPC: C10L1/22 ,  C07C209/60 ,  C08F8/30 ,  C08F8/32 ,  C08L23/36 ,  C10L1/222 ,  C10L1/2383 ,  C10L10/00 ,  C10L10/08 ,  C10M133/06 ,  C10M133/54 ,  C10N30/04 ,  C10N40/25

Abstract: PCT No. PCT/EP96/05635 Sec. 371 Date Jun. 2, 1998 Sec. 102(e) Date Jun. 2, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23586 PCT Pub. Date Jul. 3, 1997A fuel or lubricant composition containing polyisobutene amines and which contains at least one secondary polyisobutene amine of the formula I, in which R denotes a polyisobutene radical containing from 6 to 45 isobutylene units, up to 20% of the isobutylene units being replaceable by n-butylene units, provided that the amount of the secondary polyisobutene amine is larger than the amount of any corresponding primary or tertiary polyisobutene amine which may also be present.

公开(公告)号：NO329097B1

公开(公告)日：2010-08-23

申请号：NO20044447

申请日：2004-10-19

Applicant: BASF AG

Inventor： KAIBEL GERD ,  ZEHNER PETER ,  ROPER MICHAEL ,  SLANY MICHAEL ,  SCHAFER MARTIN ,  KARL JORN ,  ADAMI CHRISTOPH

IPC: C07C67/36

Abstract: The invention relates to a process for the preparation of methyl formate by reacting methanol with carbon monoxide at a pressure of from 0.5 to 10 MPa abs. and a temperature of from 50 to 150° C. in the presence of a metal alkoxide as catalyst in a reactor, in which a gas stream is withdrawn from the reactor, entrained methyl formate is removed from this gas stream by condensation, and all or some of the remaining gas stream is returned to the reactor as circulating-gas stream and a mean gas superficial velocity of from 1 to 20 cm/s is set in at least one region of the reactor in which the gas flows essentially in one direction.

公开(公告)号：CA2421940C

公开(公告)日：2009-11-24

申请号：CA2421940

申请日：2001-09-11

Applicant: BASF AG

Inventor： ROPER MICHAEL ,  BLANKERTZ HEINRICH-JOSEF ,  SCHONMANN WILLI ,  KROKOSZINSKI ROLAND ,  GRENACHER ARMIN VOLKER

IPC: B01J31/20 ,  C08F8/00 ,  C08C19/00

Abstract: The invention relates to a method for the continuous hydroformylation of polyalkenes having 30 to 700 carbon atoms and being unsaturated essentially once. The inventive method involves i) producing a cobalt carbonyl catalyst which is active for hydroformylation from a catalyst precursor which is dissolved in an aqueous phase, in the absence of the polyalkenes, ii) hydroformylating the polyalkenes with synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, and iii) separating the cobalt carbonyl catalyst from the discharge from the reaction zone while at least partially regenerating the catalyst precursor, and returning the catalyst precursor to step i).

公开(公告)号：ES2290165T3

公开(公告)日：2008-02-16

申请号：ES01967262

申请日：2001-08-10

Applicant: BASF AG

Inventor： MAAS HEIKO ,  NARBESHUBER THOMAS ,  ROPER MICHAEL

IPC: C07C303/06 ,  C07B61/00 ,  C07C15/107 ,  C07C303/32 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

Abstract: Procedimiento para la obtención de alquilarilsulfonatos mediante a) la reacción de una mezcla de olefinas con 4 átomos de carbono sobre un catalizador para la metatesis, para la obtención de una mezcla de olefinas que contiene 2-penteno y/o 3-hexeno y, en caso dado, separación del 2-penteno y/o del 3-hexeno, b) la dimerización del 2-penteno y/o del 3-hexeno obtenidos en la etapa a), sobre un catalizador de dimerización para dar una mezcla que contiene olefinas con 10 a 12 átomos de carbono y, en caso dado, separación de las olefinas con 10 a 12 átomos de carbono, c) la reacción de la mezcla de olefinas con 10 a 12 átomos de carbono, obtenida en la etapa b), con un hidrocarburo aromático en presencia de un catalizador para la alquilación, para la formación de compuestos alquilaromáticos, d) la sulfonación de los compuestos alquilaromáticos, obtenidos en la etapa c) y neutralización para dar los alquilarilsulfonatos.

公开(公告)号：MY130941A

公开(公告)日：2007-07-31

申请号：MYPI9704283

申请日：1997-09-16

Applicant: BASF AG

Inventor： KANAND JURGEN ,  ROPER MICHAEL

IPC: B01J31/24 ,  C07C41/00 ,  C07B61/00 ,  C07C41/06 ,  C07C41/20 ,  C07C41/32 ,  C07C43/00 ,  C07C43/04

Abstract: N-BUTYL ALKYL ETHERS ARE PREPARED BY A) REACTING 1,3-BUTADIENE OR A BUTADIENE-CONTAINING HYDROCARBON MIXTURE WITH AN ALCOHOL OF THE FORMULA I WHERE THE RADICAL R IS A C2-C20-ALKYL, ALKENYL, CYCLOALKYL OR CYCLOALKENYL GROUP, EACH OF WHICH MAY BE UNSUBSTITUTED OR SUBSTITUTED BY 1 OR 2 CL-C10-ALKOXY OR HYDROXY GROUPS, A C6-C10-ARYL GROUP OR A C7-C11-ARALKYL GROUP OR THE METHYL GROUP, AT ELEVATED TEMPERATURE AND ELEVATED PRESSURE IN THE PRESENCE OF A BRÖNSTED ACID OR IN THE PRESENCE OF A COMPLEX OF AN ELEMENT FROM GROUP IB, VIIB OR VIIIB OF THE PERIODIC TABLE OF THE ELEMENTS WITH PHOSPHORUSOR NITROGEN-CONTAINING LIGANDS TO GIVE A MIXTURE OF ADDUCTS OF THE FORMULAE II AND III B) SEPARATING THE ISOMERS,C) ISOMERIZING THE ADDUCT III TO GIVE THE ADDUCT II AND D) HYDROGENATING THE ADDUCT II IN THE LIQUID PHASE IN THE PRESENCE OF A HOMOGENEOUS OR HETEROGENEOUS TRANSITION METAL CATALYST OR IN THE GAS PHASE IN THE PRESENCE OF A HETEROGENEOUS TRANSITION METAL-CONTAINING CATALYST TO GIVE AN N-BUTYL ALKYL ETHER OF THE FORMULA IV.

公开(公告)号：ES2269810T3

公开(公告)日：2007-04-01

申请号：ES02800574

申请日：2002-09-26

Applicant: BASF AG

Inventor： SAVA XAVIER ,  SLANY MICHAEL ,  ROPER MICHAEL

IPC: B01J31/28 ,  B01J31/24 ,  C07F9/6568 ,  C07B61/00 ,  C07C51/14 ,  C07C57/03 ,  C07C67/38 ,  C07C69/533 ,  C07F9/6571

Abstract: Difosfina de la fórmula R1>P-(CH2)n-PR2R3 en la que R1 significa un radical bivalente, que representa, junto con el átomo de fósforo, con el que está enlazado, un grupo insubstituido o substituido de 2-fosfa- triciclo[3.3.1.1{3, 7}]decilo o un derivado del mismo, en el que uno o varios de los átomos de carbono están reemplazados por heteroátomos, R2, R3 significan, independientemente entre sí, un radical monovalente con 1 hasta 20 átomos de carbono o un radical conjunto divalente con 2 hasta 20 átomos de carbono, n significa 4 o 5 y sus mezclas.

公开(公告)号：CA2259941C

公开(公告)日：2005-10-04

申请号：CA2259941

申请日：1997-07-23

Applicant: BASF AG

Inventor： FISCHER ROLF ,  ROPER MICHAEL ,  PACIELLO ROCCO ,  SCHNURR WERNER

IPC: C07C253/30 ,  C07C255/24

Abstract: Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst fro m the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5-formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6-aminocapronitrile and if necessary hexamethylene diamine.

公开(公告)号：ES2217015T3

公开(公告)日：2004-11-01

申请号：ES00987265

申请日：2000-11-17

Applicant: BASF AG

Inventor： ZELLER EDGAR ,  WALTER MARC ,  RICHTER WOLFGANG ,  DIEHL KLAUS ,  ROPER MICHAEL ,  TROPSCH JURGEN

IPC: C07B61/00 ,  C07C2/08 ,  C07C2/10 ,  C07C11/02 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C41/03 ,  C07C43/11 ,  C07C45/50 ,  C09K23/38 ,  C07C47/02 ,  C07F9/09 ,  C07F9/11 ,  C11D1/34 ,  C11D7/26

Abstract: A process for preparing a C 13 -alcohol mixture comprises a) bringing a butene-containing C 4 -hydrocarbon stream containing less than 5% by weight, based on the butene fraction, of isobutene into contact with a nickel-containing heterogeneous catalyst at elevated temperature, b) isolating a C 12 -olefin fraction from the reaction mixture, c) hydroformylating the C 12 -olefin fraction by reaction with carbon monoxide and hydrogen in the presence of a cobalt catalyst and d) hydrogenating the product from c). The alcohol mixture is suitable for preparing surfactants by alkoxylation, glycosidation, sulfation, phosphation, alkoxylation and subsequent sulfation or alkoxylation and subsequent phosphation.