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公开(公告)号:PL2628762T3
公开(公告)日:2019-09-30
申请号:PL13155900
申请日:2013-02-20
Applicant: BASF SE
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公开(公告)号:SG11201906757PA
公开(公告)日:2019-08-27
申请号:SG11201906757P
申请日:2018-02-09
Applicant: BASF SE
Inventor: FLECKENSTEIN CHRISTOPH , BARO JUERGEN , BECK ERICH , KALLER MARTIN , MISSKE ANDREA , FLEISCHHAKER FRIEDERIKE
IPC: B41M7/00 , C09D11/101 , C09D4/00 , C09D11/30
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 16 August 2018 (16.08.2018) WIP0 I PCT omit IIl °nolo iflo oimIE (10) International Publication Number WO 2018/146259 Al (51) International Patent Classification: C09D 11/101 (2014.01) C09D 4/00 (2006.01) B41M 7/00 (2006.01) CO9D 11/30 (2014.01) (21) International Application Number: PCT/EP2018/053304 (22) International Filing Date: 09 February 2018 (09.02.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 17155623.6 10 February 2017 (10.02.2017) EP (71) Applicant: BASF SE [DE/DE]; Carl-Bosch-Str. 38, 67056 Ludwigshafen am Rhein (DE). (72) Inventors: FLECKENSTEIN, Christoph; Carl-Bosch- Str. 38, 67056 Ludwigshafen (DE). BARO, Juergen; Carl- Bosch-Str. 38, 67056 Ludwigshafen (DE). BECK, Erich; Carl-Bosch-Str. 38, 67056 Ludwigshafen (DE). KALLER, Martin; Carl-Bosch-Str. 38, 67056 Ludwigshafen (DE). MISSKE, Andrea; Carl-Bosch-Str. 38, 67056 Lud- wigshafen (DE). FLEISCHHAKER, Friederike; Carl- Bosch-Str. 38, 67056 Ludwigshafen (DE). = (74) Agent: RIPPEL, Hans Christoph; Isenbruck Bosl Horschler LLP Patentanwalte, EASTSITE ONE, Secken- heimer LandstraBe 4, 68163 Mannheim (DE). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(ii)) of inventorship (Rule 4.17(iv)) Published: with international search report (Art. 21(3)) W O 20 18/ 146 25 9 Al (54) Title: ACRYLATE-BASED MONOMERS FOR USE AS REACTIVE DILUENTS IN PRINTING FORMULATIONS (57) : The invention relates to compositions, comprising. a)1.00 to 65.00% by weight of at least one compound of formula (I), wherein R 1 , R 2 , 0 R 3 , R 4 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy- (I) Ci-C6-alkyl; R is H or Ci-C6-alkyl; Xis CR6R7, 0, or NR 8 ; R 6 R are each in- 7 dependently H, C1-C6-alkyl, Ci-C6-alkoxy, or C1-C6-alkoxy-Ci-C6-alkyl; R8 0 R 5 is H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as com- ponent A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and having a molecular weight of no more than 500 Dal- ton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight of no more than 600 Dalton, as component C; and d) 1.00 to 30.00% by weight of at least one polymer having at least two (meth)acrylate groups and having a molecular weight of at least 700 Dalton, as component D; with the proviso that the amount of components A + B is at least 50% by weight, as well as the use of these compositions as printing inks, in particular inkjet printing inks. R1 R2 R:R4 X N
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公开(公告)号:AU2018213816A1
公开(公告)日:2019-08-22
申请号:AU2018213816
申请日:2018-01-22
Applicant: BASF SE
Inventor: MISSKE ANDREA , FLECKENSTEIN CHRISTOPH , FLEISCHHAKER FRIEDERIKE
Abstract: The invention relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to (meth)acrylic acid, f) the mixture is heated to a temperature of 75 to 110°C, g) norbornene is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture. The invention further relates to a method for producing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as a catalyst, characterised in that e) boron trifluoride is added to an organic solvent, f) the mixture is heated to a temperature of 75 to 110°C, g) a mixture containing norbornene and (meth)acrylic acid is added, and h) the norbornyl-(meth)acrylate obtained is isolated from the reaction mixture.
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公开(公告)号:BR112013016682A2
公开(公告)日:2016-10-04
申请号:BR112013016682
申请日:2011-12-23
Applicant: BASF SE
Inventor: FLECKENSTEIN CHRISTOPH , JANSSENS GEERT , DENECKE HARTMUT , BELLIN INGO , WAGNER JOCHEN , HAHN KLAUS , MASSONNE KLEMENS , DÖRING MANFRED , HOFMANN MAXIMILIAN , CIESIELSKI MICHAEL , SPIES PATRICK , DEGLMANN PETER , OSTERMANN RAINER , FUCHS SABINE
Abstract: sistema retardante de chama, usos de uma mistura dos sinergistas retardantes de chama, e de uma composição polimérica isenta de halogênio e/ou de uma composição polimérica, processos para tornar polímeros espumados ou não espumados retardantes de chama, para produzir um polímero de estireno expansível, e para produzir uma espuma de estireno extrusada, e, composição polimérica a invenção diz respeito a um sistema retardante de chama que compreende: a) pelo menos um composto de enxofre da fórmula (i), onde as definições dos símbolos e índices são como segue: r, sendo idênticos ou diferentes, preferivelmente idênticos, é arila c~ 6~-c~ 12~, um grupo heteroarila de 5 a 10 membros que compreende um ou mais heteroátomos do grupo de n, o e s, alquila c~ 1~-c~ 18~, alquila c~ 1~-c~ 18~, alquenila c~ 2~-c~ 18~, alquinila c~ 2~-c~ 18~ ou cicloalquila c~ 3~-c~ 10~; x, sendo idênticos ou diferentes, preferivelmente idênticos, é or^ 2^, sr^ 2^, nr^ 2^r^ 3^, coor^ 2^, so~ 2~r^ 2^, f, cl, br, r, h, ou um grupo -y^ 1^-p(y^ 2^)pr'r''; y^ 1^ é o, s ou nr'''; y^ 2^ é o ou s; p é 0 ou 1; r' e r'', sendo idênticos ou diferentes, preferivelmente idênticos, são alquila c~ 1~-c~ 18~, alquenila c~ 2~-c~ 18~, alquinila c~ 2~-c~ 18~, arila c~ 6~-c~ 12~, cicloalquilac~ 3~-c~ 10~, arila c~ 3~-c~ 10~, arila c~ 6~-c~ 12~-alquila c~ 1~-c~ 18~, um grupo heteroarila ou grupo heteroarilóxi que compreende um ou mais heteroátomos do grupo de n, o e s, o-alquila (c~ 1~-c~ 18~), o-alquenila (c~ 2~-c~ 18~), o-alquinila (c~ 2~-c~ 10~), o-arila (c~ 6~-c~ 12~), o-cicloalquila (c~ 3~-c~ 10~) ou arila (c~ 6~-c~ 12~)-alquila (c~ 1~-c~ 18~)-o; r''' é h, alquila c~ 1~-c~ 18~ ou (p(y^ 2^)pr'r''); r1, sendo idênticos ou diferentes, preferivelmente idênticos, é alquila c~ 1~-c~ 18~, alquenila c~ 2~-c~ 18~, alquinila c~ 2~-c~ 18~, arila c~ 6~-c~ 12~, cicloalquila c~ 3~-c~ 10~, arila c~ 6~-c~ 12~-alquila c~ 1~-c~ 18~, um grupo heteroarila que compreende um ou mais heteroátomos do grupo de n, o e s, o-alquila (c~ 1~-c~ 18~), o-alquenila (c~ 2~-c~ 18~), o-alquinila (c~ 2~-c~ 18~), o-arila (c~ 6~-c~ 12~), o-cicloalquila (c~ 3~-c~ 10~), arila (c~ 6~-c~ 12~)-alquila (c~ 1~-c~ 18~)-o, s-alquila (c~ 1~-c~ 18~), s-alquenila (c~ 1~-c~ 18~), s alquinila (c~ 2~-c~ 18~), s-arila (c~ 6~-c~ 12~), s-cicloalquila (c~ 3~-c~ 10~), arila (c~ 6~-c~ 12~)-alquila (c~ 1]-c~ 18~)-s, oh, f, cl, br ou h; r2 e r3, sendo idênticos ou diferentes, preferivelmente idênticos, são h, alquila c~ 1~-c~ 18~) alquenila c~ 2~-c~ 18~, alquinila c~ 2~-c~ 18~, arila c~ 6~-c~ 12~, cicloalquila c~ 3~-c~ 10~, arila c~ 6~-c~ 12~-alquila c~ 1~-c~ 18~ ou um grupo heteroarila que compreende um ou mais heteroátomos do grupo de n, o e s; n é um número inteiro de 1 a 8 e m é um número de 1 a 1000; b) pelo menos um composto de orgnofósforo isento de halogênio com teor de fósforo na faixa de 0,5 a 40% em peso, com base no composto de fósforo.
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公开(公告)号:CA2977710A1
公开(公告)日:2016-09-01
申请号:CA2977710
申请日:2016-02-24
Applicant: BASF SE
Inventor: MISSKE ANDREA , FLEISCHHAKER FRIEDERIKE , FLECKENSTEIN CHRISTOPH , KALLER MARTIN , STENGEL ULRIK , BLANCHOT MATHIEU , STOER CLAUDIA , NAIR RITESH
IPC: C07D493/04 , C09J4/02
Abstract: The invention relates to a method for producing isosorbide ethoxylate dimethacrylate by the transesterification of alkyl(meth)acrylate with isosorbide ethoxylate, comprising the following steps: (i) ethoxylating isosorbide to isosorbide ethoxylate; (ii) permitting alkyl(meth)acrylate to react with isosorbide ethoxylate in the presence of potassium phosphate as a catalyst and of a stabilizer and in the presence of an entrainer, forming an azeotrope with the alcohol bonded in the alkyl(meth)alcylate; (iii) continuously distilling off the azeotrope that consists of entrainer and alcohol, steps (ii) and (iii) being carried out simultaneously until isosorbide ethoxylate is substantially completely converted; (iv) separating the catalyst from the isosorbide ethoxylate dimethacrylate-containing product mixture; and (v) distilling off non-converted alkyl(meth)acrylate and entrainer from the product mixture.
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公开(公告)号:SG11201510183UA
公开(公告)日:2016-01-28
申请号:SG11201510183U
申请日:2014-06-02
Applicant: BASF SE
Inventor: RHUDY KEVIN , KRÄMER ROLAND HELMUT , HUPKA BIRGIT , KÖNIG ALEXANDER , FLECKENSTEIN CHRISTOPH , KÖNIG CHRISTIAN , HERBST HEINZ
IPC: C07F9/655 , C07F9/40 , C08K5/5313 , C09K21/00
Abstract: The present invention relates to a phosphorus containing alcohol, obtainable or obtained by a process comprising the reaction of at least one alcohol with a phosphorus containing compound of the general formula (I) as defined herein, as well as the process for preparing a phosphorus containing alcohol, comprising the reaction of at least one alcohol with a phosphorus containing compound of the general formula (I). Furthermore, the present invention relates to the use of a phosphorus containing alcohol as disclosed herein as a flame retardant, to a process for the preparation of a polyurethane and the polyurethane as such.
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公开(公告)号:PL2513251T3
公开(公告)日:2015-10-30
申请号:PL10790979
申请日:2010-12-15
Applicant: BASF SE
Inventor: FLECKENSTEIN CHRISTOPH , DENECKE HARTMUT , BELLIN INGO , KRIHA OLAF , SPIES PATRICK , FUCHS SABINE , MASSONNE KLEMENS , HAHN KLAUS , DEGLMANN PETER , HOFMANN MAXIMILIAN , KINDLER ALOIS
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公开(公告)号:ES2545331T3
公开(公告)日:2015-09-10
申请号:ES10790979
申请日:2010-12-15
Applicant: BASF SE
Inventor: FLECKENSTEIN CHRISTOPH , DENECKE HARTMUT , BELLIN INGO , KRIHA OLAF , SPIES PATRICK , FUCHS SABINE , MASSONNE KLEMENS , HAHN KLAUS , DEGLMANN PETER , HOFMANN MAXIMILIAN , KINDLER ALOIS
Abstract: Uso de un compuesto de fósforo de la fórmula (I) como agente ignífugo,**Fórmula** donde los símbolos en la fórmula (I) tienen los siguientes significados: A es un grupo **Fórmula** Y es -P(>=X2)sR3R4, H, un grupo alquilo C1-C12 de cadena recta o ramificada, cicloalquilo C5-C6, arilo C6-C12, bencilo, donde los cuatro últimos grupos mencionados son no sustituidos o sustituidos por uno o varios radicales alquilo C1- C4 o alquenilo C2-C4; R1, R2, R3 y R4 son iguales o diferentes a hidrógeno, OH, alquilo C1-C6, alquenilo C2-C16, alcoxi C1-C16, alquenoxi C2- C16, cicloalquilo C3-C10, cicloalcoxi C3-C10, arilo C6-C10, ariloxi C6-C10, arilo C6-C10 alquilo C1-C16, arilo C6-C10-alcoxi C1-C16, SR9 COR10, COR11, CONR12R13 o dos radicales R1, R2, R3, R4 forman junto con el átomo de fósforo al cual están unidos, o el grupo P-O-A-O-P, un sistema de anillo; R5, R6, R7, R8 son iguales o diferentes a H, alquilo C1-C16-, alquenilo C2-C16, alcoxi C1-C16, alquenoxi C2-C16; R9, R10, R11, R12, R13 son iguales o diferentes a H, alquilo C1-C16, alquenilo C2-C16, arilo C6-C10, arilo C6-C10-alquilo- C1-C16, arilo C6-C10-alcoxi C1-C16; X1, X2 son iguales o diferentes a S u O; r, s son iguales o diferentes a 0 o 1; X3, X4, X5, X6 son iguales o diferentes a S u O y n es un número natural de 1 a 50.
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公开(公告)号:ES2502544T3
公开(公告)日:2014-10-03
申请号:ES11702416
申请日:2011-01-27
Applicant: BASF SE
Inventor: BALBO BLOCK MARCO , FERBITZ JENS , HENZE OLIVER STEFFEN , FLECKENSTEIN CHRISTOPH , MASSONNE KLEMENS
Abstract: El uso de al menos una difosfina de fórmula (I),**Fórmula** en la que X es S u O; n es 0 ó 1; R1, R2, R3, R4 son independientemente alquilo C1-C10, hidroxialquilo C1-C10, alcoxi C1-C10, hidroxialcoxi C1-C10, cicloalquilo C3-C10, cicloalcoxi C3-C10, arilo C6-C10, aril C6-C10-oxi, aril C6-C10-alquilo C1-C4, aril C6-C10-alcoxi C1-C4, hidroxiarilo C6-C10, hidroxi-aril C6-C10-oxi, tio-alquilo C1-C10, tioarilo C6-C10 o tioalquil C1-C4-arilo C6-C10, NR5R6, COR2, COOR5 o CONR5R6; R5, R6 son H, alquilo C1-C10, cicloalquilo C3-C10, arilo C6-C10 o aril C1-C10-alquilo C1-C4, como un agente retardador de llama en un material de poliuretano.
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公开(公告)号:CA2799344C
公开(公告)日:2014-09-09
申请号:CA2799344
申请日:2011-05-20
Applicant: BASF SE
Inventor: BALBO BLOCK MARCO , FERBITZ JENS , FLECKENSTEIN CHRISTOPH , CRISTADORO ANNA , BRUCHMANN BERND , MASSONNE KLEMENS
Abstract: The present invention relates to a polycarbonate, containing at least one phosphoric group, to the use of the polycarbonate as a flameproofing agent, to a method for producing a polyurethane in which such a polycarbonate is used, and to a polyurethane which can be obtained by such a method.
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