公开(公告)号：DE10258318A1

公开(公告)日：2004-06-24

申请号：DE10258318

申请日：2002-12-13

Applicant: BASF AG

Inventor： MODI ANDREA ,  FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  SIRCH TILMAN

IPC: B01J23/889 ,  C07C29/141 ,  C07C29/149 ,  C07C31/20 ,  C07C67/283

Abstract: Production of 1,6-hexanediol of purity at least 99 % comprises hydroformylating 3-, 4- or 2-pentenoic acid alkyl ester with carbon monoxide and hydrogen in presence of rhodium compounds and tertiary organic polyphosphites, hydrogenating in chromium-free mainly copper-containing catalysts; and purifying the resulting diol mixture by fractional distillation. Production of 1,6-hexanediol of purity at least 99 % comprises: (1) hydroformylating 3-, 4- or 2-pentenoic acid alkyl ester with carbon monoxide and hydrogen in presence of rhodium compounds and tertiary organic polyphosphites to a mixture mainly of 5-, 4- and 3-formylvaleric acid esters; (2) hydrogenating the ester mixture in chromium-free mainly copper-containing catalysts; and (3) purifying the resulting diol mixture by fractional distillation.

公开(公告)号：DE10316658A1

公开(公告)日：2004-10-28

申请号：DE10316658

申请日：2003-04-11

Applicant: BASF AG

Inventor： MODI ANDREA ,  FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  SIRCH TILMAN

IPC: C07C67/31 ,  C07C67/60 ,  C07C29/16 ,  C07C69/675

Abstract: Alkyl 6-hydroxycaproates (I) preparation comprises reacting alkyl 2-, 3- and/or 4-pentenoates (II) with carbon monoxide and hydrogen to form 3-, 4- and 5-formylvalerates (III); hydrogenating and separating (I) from alkyl 6C hydroxycarboxylates (IV) produced. First step is in presence of rhodium compound and tertiary organic polyphosphite (A) and the hydrogenation uses catalyst from subgroup I or VI-VIII. Preparation of alkyl 6-hydroxycaproates (I) comprises reacting alkyl 2-, 3- and/or 4-pentenoates (II) with carbon monoxide and hydrogen to form a mixture consisting mainly of 3-, 4- and 5-formylvalerates (III); hydrogenating this mixture and separating (I) from the mixture of alkyl 6C hydroxycarboxylates (IV) produced. The first step is in presence of a rhodium compound and a tertiary organic polyphosphite (A) and the hydrogenation is in the presence of a catalyst containing at least one element of subgroup I or VI-VIII.

公开(公告)号：DE10253751A1

公开(公告)日：2004-06-03

申请号：DE10253751

申请日：2002-11-19

Applicant: BASF AG

Inventor： MODI ANDREA ,  FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  SIRCH TILMAN

IPC: C07C29/149 ,  C07C31/20

公开(公告)号：DE10313702A1

公开(公告)日：2004-10-07

申请号：DE10313702

申请日：2003-03-27

Applicant: BASF AG

Inventor： HUBER-DIRR SYLVIA ,  HESSE MICHAEL ,  MODI ANDREA ,  JUNICKE HENRIK

IPC: B01J23/83 ,  C07C29/149 ,  C07B41/02 ,  B01J21/04 ,  B01J23/85 ,  B01J21/06

Abstract: A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.

公开(公告)号：DE10308489A1

公开(公告)日：2004-09-09

申请号：DE10308489

申请日：2003-02-26

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  MODI ANDREA ,  NOEBEL THOMAS ,  PINKOS ROLF

IPC: C07C45/48 ,  C07C45/82 ,  C07C49/395 ,  C07D313/04 ,  C07C45/41 ,  B01D3/36 ,  C07C49/297 ,  C07D307/22

公开(公告)号：DE10258316A1

公开(公告)日：2004-06-24

申请号：DE10258316

申请日：2002-12-13

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  MODI ANDREA ,  ROEPER MICHAEL ,  SIRCH TILMAN ,  STUEER WOLFRAM

IPC: C07C29/17 ,  C07C31/20 ,  C07C69/593 ,  B01J23/889

Abstract: Production of 1,6-hexanediol of purity at least 99.5 % comprises: (1) catalytically dimerizing a 1-8C acrylic acid ester in presence of rhodium compounds to a mixture mainly of 2- and 3-hexenedioic acid diesters; (2) hydrogenating the ester mixture in chromium-free mainly copper-containing catalysts; and (3) purifying the resulting diol mixture by fractional distillation.

公开(公告)号：DE10253752A1

公开(公告)日：2004-06-03

申请号：DE10253752

申请日：2002-11-19

Applicant: BASF AG

Inventor： MODI ANDREA ,  FISCHER ROLF-HARTMUTH ,  KRUG THOMAS ,  SIRCH TILMAN

IPC: C07C41/28 ,  C07C59/285