CARBON-GRADED LAYER FOR IMPROVED ADHESION OF LOW-K DIELECTRICS TO SILICON SUBSTRATES
    1.
    发明申请
    CARBON-GRADED LAYER FOR IMPROVED ADHESION OF LOW-K DIELECTRICS TO SILICON SUBSTRATES 审中-公开
    用于改善低介电常数硅基底粘附的碳分层

    公开(公告)号:WO03009380A3

    公开(公告)日:2003-08-07

    申请号:PCT/GB0201370

    申请日:2002-03-21

    Applicant: IBM IBM UK

    Abstract: A structure and method for an insulator layer having carbon-graded layers above a substrate is disclosed, wherein the concentration of carbon increases in each successive carbon-graded layer above the substrate. The insulator comprises a low-k dielectric having a dielectric constant less than 3.3. The carbon-graded layer increases adhesion between the substrate and the insulator and between the insulator and the conductor layer. The structure may also include stabilization interfaces between the carbon-graded layers. More specifically, the carbon-graded layers include a first layer adjacent the substrate having a carbon content between about 5% and 20%, a second layer above the first layer having a carbon content between about 10% and 30%, and a third layer above the second layer having a carbon content between about 20% and 40%.

    Abstract translation: 公开了一种用于在衬底上方具有碳渐变层的绝缘体层的结构和方法,其中在衬底上方的每个连续碳渐变层中的碳浓度增加。 绝缘体包括具有小于3.3的介电常数的低k电介质。 碳渐变层增加了衬底和绝缘体之间以及绝缘体和导体层之间的粘附力。 该结构还可以包括碳梯度层之间的稳定界面。 更具体地说,碳缓变层包括与碳含量在约5%和20%之间的衬底相邻的第一层,在第一层之上的含碳量在约10%和30%之间的第二层,以及第三层 在碳含量在约20%和40%之间的第二层之上。

    ETCHING OF BORON NITRIDE
    2.
    发明专利

    公开(公告)号:JPH076996A

    公开(公告)日:1995-01-10

    申请号:JP3886194

    申请日:1994-03-09

    Applicant: IBM

    Abstract: PURPOSE: To allow an etching step to match existing semiconductor device manufacturing processes by etching a boron nitride layer, after doping the layer with an element selected from elements in the IVA group of the periodic table. CONSTITUTION: A boron nitride layer is doped with an element selected from group IVA of the periodic table of the elements such as silicon, carbon or germanium. Then, the doped boron nitride layer is etched using an appropriate etchant, such as a wet etchant (a nitride etchant such as thermal phosphate, hydrofluoric acid, buffer hydrofluoric acid at about 165 deg.C). The amount of dopant used is up to about 20% in atomic composition, but is preferably in a range of amount 2 to 10%. The etching speed of the boron nitride layer is controlled by changing the amount of dopant. As a result, the etching step can match existing semiconductor device manufacturing processes.

    METHOD FOR FORMING SEPARATION REGION ON SILICON SUBSTRATE AND STRUCTURE OF SEPARATION REGION

    公开(公告)号:JPH10214886A

    公开(公告)日:1998-08-11

    申请号:JP874398

    申请日:1998-01-20

    Abstract: PROBLEM TO BE SOLVED: To form an effective O2 diffusion barrier by forming a conformal layer that is selected from a group consisting of a double layer that is made of oxide and nitride in a separation groove and on a protection layer, depositing a CVD layer consisting of an oxide-filling material on the layer, and releasing the protection layer and the conformal layer. SOLUTION: A conformal layer 20 with a thickness of approximately 5-15mm being selected from a group consisting of an acid nitride, a double layer consisting of oxide and nitride, and a double layer consisting of acid nitride and nitride is formed on a protection layer (a pad nitride layer 14 and a pad oxide layer 12) and a separation groove (thermal oxide liner) 18. Then, an oxide-filling material 22 such as tetraethylortosilicate with a thickness of 450-500nm is deposited by the CVD supported by ozone, and the oxide-filling material 22 is subjected to anneal treatment and high-density treatment. Then, the conformal layer 20 and the pad nitride layer 14 and the pad oxide layer 12 are released. Then, the oxide-filling material 22 is flattened so that it is flush with the surface of a substrate.

    RESISTOR AND ITS MANUFACTURE
    5.
    发明专利

    公开(公告)号:JPH1041465A

    公开(公告)日:1998-02-13

    申请号:JP10727497

    申请日:1997-04-24

    Applicant: IBM SIEMENS AG

    Abstract: PROBLEM TO BE SOLVED: To manufacture a high resistance resistor by using materials and a method common the those used for the integrated circuit process. SOLUTION: As a method for manufacturing a resistor element for an integrated circuit semiconductor device, and insulation film 120 formed is silicon nitride and the like is deposited first. Then, a a film 130 containing titanium is deposited on the insulation film 120. The film 130 and the insulation film 120 are heat-treated so as the diffuse titanium in the insulation film 120. As a result, titanium is diffused in the insulation film 120. Thus, a resistor element with relatively high resistance is manufactured. The merit of this method is that it can be easily integrated with the conventional integrated circuit manufacturing technologies.

    7.
    发明专利
    未知

    公开(公告)号:DE69618548D1

    公开(公告)日:2002-02-21

    申请号:DE69618548

    申请日:1996-10-24

    Applicant: IBM

    Abstract: A method of forming interlevel studs in an insulating layer on a semiconductor wafer. First, a conformal BPSG layer is formed on a Front End of the Line (FEOL) semiconductor structure. Vias are opened through the BPSG layer to the FEOL structure. A layer of poly is formed (deposited) on the BPSG layer, filling the vias. The poly layer may be insitu doped poly or implanted after it is deposited. The wafer is annealed to diffuse dopant from the poly to form diffusions wherever the poly contacts the substrate. A non-selective slurry of colloidal silica and at least 1% ammonium hydroxide is used to chem-mech polish the poly from the BPSG layer and, simultaneously, planarize the BPSG layer.

    8.
    发明专利
    未知

    公开(公告)号:DE69534699D1

    公开(公告)日:2006-01-26

    申请号:DE69534699

    申请日:1995-09-22

    Applicant: IBM

    Abstract: Fluorine-doped oxide is formed that is resistant to water absorption by the use of two sources of silicon, one being the fluorine precursor and the other being available to react with excess fluorine from the fluorine precursor, thereby reducing the number of fluorine radicals in the layer; the fluorine precursor containing a glass-forming element that combines with the other glass constituents to carry into the gas a diatomic radical containing one atom of fluorine and one atom of the glass-forming element. In particular, comparison between traces of undoped oxide and fluorosilicate glass clearly shows that the former has a greater SIOH concentration which is a manufacturing yield detractor.

    10.
    发明专利
    未知

    公开(公告)号:DE69737469T2

    公开(公告)日:2007-11-29

    申请号:DE69737469

    申请日:1997-04-24

    Applicant: SIEMENS AG IBM

    Abstract: According to the preferred embodiment of the present invention, an improved resistor and method of fabrication is provided. The method for fabricating a resistive element into an integrated circuit semiconductor device comprises the steps of: depositing a dielectric film, such as silicon nitride; depositing a titanium film upon the dielectric film; and annealing the titanium and dielectric films. This causes titanium to be diffused into the dielectric film. This creates a resistive element having a relatively high resistivity. The preferred embodiment method has the advantage of being easily integrated into conventional integrated circuit fabrication techniques.

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