Abstract:
Aspects of the disclosure include suppression of optical interference fringes in optical spectra via a modification to the refractive index of media that forms or is contained in one or more components of equipment utilized for optical spectroscopy. Such a modification can yield changes in the optical path of light propagating through at least one of the media, with the ensuing changes in the spectral structure of interference between light propagating through different optical paths. In certain embodiments, the refractive index of the media that forms or is contained in one or more components can be modified via application of a time-dependent stimulus to at least one of the one or more components. The applied stimulus can include pressure, mechanical strain or stress, temperature, a combination thereof, or the like.
Abstract:
Disclosed is a spectroscopy device, including an analysis zone for receiving a sample; at least one light-emitting diode arranged to emit a light beam towards the analysis zone, having a luminous intensity spectral profile in a working wavelength interval; unit for varying with time the luminous intensity spectral profile emitted by the diode in the working wavelength interval of the diode; a detector, arranged to receive, during a variation with time of the luminous intensity spectral profile emitted by the diode, the light beam emitted by the diode and having crossed the analysis zone, and supplying a detection signal of the light beam emitted by the diode and received by the detector, in the form of a signal which depends on at least one characteristic representative of the luminous intensity spectral profile of the light-emitting diode. Application to derivative spectroscopy.
Abstract:
Spectrally analyzing an unknown sample (10A) includes (i) providing a spatially homogeneous region (10B) of the unknown sample (10A); (ii) directing a plurality of interrogation beams (16) at the spatially homogeneous region (10B) with a laser source (14), (iii) acquiring a separate output image (245) while the unknown sample (10A) is illuminated by each of the interrogation beams (16) with an image sensor (26A); and (iv) analyzing less than fifty output images (245) to analyze whether a characteristic is present in the unknown sample (10A) with a control system (28) that includes a processor. Each of the interrogation beams (16) is nominally monochromatic and has a different interrogation wavelength that is in the mid-infrared spectral range.
Abstract:
A multidimensional spectrometer encodes frequency information into laser pulses so that a frequency insensitive detector may be used to collect data for a multi-dimensional spectrograph only from intensity information and knowledge of a modulation providing the encoding. In one embodiment the frequency encoding may be done by a conventional interferometer greatly simplifying construction of the spectrometer.
Abstract:
Method and gas analyzer for measuring the concentration of a gas component in a sample gas, wherein to measure the concentration of a gas component in a sample gas, a laser diode is actuated by a current and light generated by the laser diode is guided through the sample gas to a detector, the current is simultaneously varied within periodically successive sampling intervals for the wavelength-dependent sampling of an absorption line of interest of the gas component, and the current can be additionally modulated sinusoidally based on wavelength modulation spectroscopy with a low frequency and small amplitude, such that a measuring signal generated by the detector is evaluated to form a measurement result, where to improve the measuring signal-noise ratio and achieve a much lower detection limit with the same measuring distance, the current is modulated with a high (RF) frequency in the GHz range so that no wavelength modulation occurs, and an RF modulation amplitude is selected at the maximum level using the linear control range of the laser diode where, before evaluation, the measuring signal is demodulated at the radio frequency.
Abstract:
If the specific gas concentration is relatively high, controller sets 0 as the modulation amplitude in a modulation amplitude controlling voltage generator for frequency modulation of laser light, controls a switching unit to select the output of a second ADC, and causes a computation unit to compute according to the direct absorption detection method to calculate the water molecule volume concentration. If the specific gas concentration is relatively low, the modulation amplitude is set to A, not 0, controls switching unit to select the output of a first ADC, which digitizes a synchronized detection signal, and causes the computation unit to compute according to the harmonic synchronous detection method to calculate the water molecule volume concentration. The concentration calculated using either of the methods is compared against a threshold value, and if decided that an accurate result cannot be obtained, the method is switched as the measurements are continuously executed.
Abstract:
A method in which the wavelength of the light of a tunable light source is varied periodically over an absorption line of interest for the gas component to measure the concentration of a gas component in a measurement gas based on one of two measurement methods of direct absorption spectroscopy and wavelength modulation spectroscopy and, where in the case of wavelength modulation spectroscopy, the wavelength of the light is additionally sinusoidally modulated at a high frequency and with a small amplitude, where the intensity of the light is detected after transradiation of the measurement gas and processed to yield a measurement result, and where in order to increase the accuracy and reliability of the measurement, the two measurement methods are applied simultaneously during each period, or alternately in consecutive periods, and their results are combined by averaging to form the measurement result.
Abstract:
Methods and optical detection systems (200, 300, 800, 900) for generating and processing a real-time time-domain cavity ringdown spectroscopy (CRDS) signal (831, 931) from an absorbing species in an optical detection system (200, 300, 800, 900) having an optical ringdown cavity (200, 300) are disclosed. The optical ringdown cavity (200, 300) is adapted for accepting a sample of an absorbing species. One or more modulated light signals (241,243,245,341) are generated using one or more light sources (240, 242, 244, 340). The light source(s) (240, 242, 244, 340) is pulsed at a specified pulse rate(s). The modulated light signal(s) (241,243,245, 341) is resonated using the optical ringdown cavity (200, 300) comprising a plurality of mirrors (220, 230), or sets of mirrors (320, 330), to produce the CRDS signal (831, 931). The reflectivity of the mirrors (220, 230), or sets of mirrors (320, 330), is dependent upon the pulse rate of the modulated light signals (241,243,245,341). Different beamlines (212, 214, 216, 312, 314, 316) are established by the modulated light signal(s) (241,243,245, 341) and the mirrors (220, 230, 320, 330) interacting with the absorbing species sample.
Abstract:
A spectroscopic measurement device includes a variable wavelength interference filter provided with a first reflecting film, a second reflecting film, and an electrostatic actuator for changing a gap amount of a gap between the first reflecting film and the second reflecting film, a detection section adapted to detect the light intensity of the light taken out by the variable wavelength interference filter, a voltage setting section and a voltage control section for applying an analog voltage varying continuously to the electrostatic actuator, a voltage monitoring section for monitoring the voltage applied to the electrostatic actuator, a storage section for storing V-λ data, and a light intensity acquisition section for obtaining the light intensity detected by the detection section at a timing at which the light transmitted through the variable wavelength interference filter has the measurement target wavelength based on the voltage monitored by the voltage monitoring section.
Abstract:
Gas analyzer and method for measuring the concentration of a gas component in a sample gas, wherein the wavelength of the light of a wavelength-tunable light source is varied within periodically successive sampling intervals and, in the process, additionally modulated with a frequency to perform wavelength dependent sampling of an absorption line of a gas component to be measured in the sample gas.