Abstract:
The disclosure relates generally to methods and apparatus for using a fiber array spectral translator-based (“FAST”) spectroscopic system for performing spectral unmixing of a mixture containing multiple polymorphs. In an embodiment, a first spectrum of a mixture containing polymorphs of a compound is obtained using a photon detector and a fiber array spectral translator having plural fibers. A set of second spectra is provided where each spectrum of the set of second spectra may be representative of a different polymorph of the compound. The first spectrum and the set of second spectra may be compared, and based on the comparison, the presence of one or more polymorphs in the mixture may be determined.
Abstract:
An encoder spectrograph is used to analyze radiation from one or more samples in various configurations. The radiation is analyzed by spatially modulating the radiation after it has been dispersed by wavelength or imaged along a line. Dual encoder spectrographs may be used to encode radiation using a single modulator. An encoder spectrograph includes a modulator with radiation filters having non-equal widths and centered at non-equal intervals along the encoding axis of the modulator.
Abstract:
An apparatus and a method for optically analyzing a sample are provided. The apparatus includes a first optical device that transmits a narrow waveband of light and has a first filter and a first monochromator that provide different paths for the narrow waveband of the light. The apparatus may also include a light source that generates the light as broadband excitation light, in which case the first optical device transmits a narrow waveband of the broadband excitation light through the first filter or the first monochromator. Further, the apparatus may include a second optical device that directs the narrow waveband of the broadband excitation light onto the sample and receives emission light from the sample, a third optical device that transmits a narrow waveband of the emission light, and a detector that converts the narrow waveband of the emission light into an electrical signal.
Abstract:
An optical method and system for measuring characteristics of a sample using a broadband metrology tool in a purge gas flow environment are disclosed. In the method a beam path for the metrology tool is purged with purge gas at a first flow rate. A surface of the sample is illuminated by a beam of source radiation having at least one wavelength component in a vacuum ultraviolet (VUV) range and/or at least one wavelength component in an ultraviolet-visible (UV-Vis) range. A flow rate of a purge gas is adjusted between the first flow rate for metrology measurements made when the source radiation is in the VUV spectral region and a second flow rate for metrology measurements made when the source radiation is in the UV-Vis spectral region. The system includes a light source, illumination optics, collection optics, detector, a purge gas source and a controller. The purge gas source is configured to supply a flow of purge gas to a beam path in the light source and/or illumination optics and/or sample and/or collection optics and/or detector. The controller is configured to control a flow rate of the purged gas flow in response to an output signal from the detector.
Abstract:
A two-channel spectrometer has a shared objective and a pair of slits at a common image plane. Each of the slits receives a portion of the output beam of the shared objective and is optimized for transmitting different wavelengths. A shared double-pass reflective triplet receives the output beams of the slits. The output of the reflective triplet is incident upon a beamsplitter, which sends a collimated first reflective triplet output of a first wavelength to a first dispersive element, and a collimated second reflective triplet output of a second wavelength to a second dispersive element. The outputs of the dispersive elements are directed back to the beamsplitter and the reflective triplet to imaging detectors located at two different locations of the common image plane.
Abstract:
The present invention relates to the production of instantaneous or non-instantaneous multi-band images, to be transformed into multi- or hyperspectral images, comprising light collecting means (11), an image sensor (12) with at least one two dimensional sensor array (121), and an instantaneous colour separating means (123), positioned before the image sensor array (121) in the optical path (OP) of the arrangement (1), and first uniform spectral filters (13) in the optical path (OP), with the purpose of restricting imaging to certain parts of the electromagnetic spectrum. The present invention specifically teaches that a filter unit (FU) comprising colour or spectral filter mosaics and/or uniform colour or spectral filters mounted on filter wheels (114) or displayed by transmissive displays (115), is either permanently or interchangeably positioned before the colour separating means (123) in the optical path (OP) in, or close to, converged light (B). Each colour or spectral filter mosaic consists of a multitude of homogeneous filtering regions. The transmission curves (TC) of the filtering regions of a colour or spectral filter mosaic can be partly overlapping, in addition to overlap between these transmission curves and those belonging to the filtering regions of the colour separating means (123). The transmission curves (TC) of the colour or spectral filter mosaics and the colour separating means (123) are suitably spread out in the intervals of a spectrum to be studied. The combination of the colour separating means (123) and the spectral or colour or spectral filter mosaics produces different sets of linearly independent transmission curves (TC). The multiple-filter image captured by the image sensor (12) is demosaicked by identifying and segmenting the image regions that are affected by the regions of the multiple filter mosaic, and after an optional interpolation step, a multi-band image is obtained. The resulting multi-band image is transformed into a multi- or hyperspectral image.
Abstract:
In a multi-wavelength spectroscopic apparatus using diffraction gratings, a first diffraction grating is a diffraction grating with diffraction efficiencies of p-polarized light and s-polarized light being equal on a short wavelength side of an operating wavelength range, and a second diffraction grating is a diffraction grating with diffraction efficiencies of p-polarized light and s-polarized light being equal on a long wavelength side of an operating wavelength range. By performing dispersion with two such diffraction gratings, it is possible to enlarge the amount of angular dispersion, and to produce a spectroscopic apparatus, which cancels wavelength dependencies of the diffraction efficiencies and has a small wavelength dependency of the diffraction efficiency.
Abstract:
The development of a multiple-channel dual phase lock-in optical spectrometer (LIOS) is presented, which enables parallel phase-sensitive detection at the output of an optical spectrometer. The light intensity from a spectrally broad source is modulated at the reference frequency, and focused into a high-resolution imaging spectrometer. The height at which the light enters the spectrometer is controlled by an acousto-optic deflector, and the height information is preserved at the output focal plane. A two-dimensional InGaAs focal plane array collects light that has been dispersed in wavelength along the horizontal direction, and in time along the vertical direction. The data is demodulated using a high performance computer-based digital signal processor. This parallel approach greatly enhances (by more than 100×) the speed at which spectrally resolved lock-in data can be acquired.
Abstract:
A spectrometer system (1) comprising an IR (infrared) spectrometer (2) and an IR microscope (3), wherein a sample (42) and a first detector (21; 31) are provided in the IR microscope (3), wherein the IR microscope (3) is designed such that during measurement, the sample (42) is imaged on the first detector (21; 31) via an intermediate focus (44), is characterized in that at least one second detector (24, 25; 33) is provided whose detector surface (26, 27; 34) extends parallel to the detector surface (22; 32) of the first detector (21; 31), the detector surface (26, 27; 34) of the at least one second detector (24, 25; 33) is at least 5 times larger than the detector surface (22; 32) of the first detector (21; 31), and the first (21; 31) and the at least one second detector (24, 25; 33) are disposed directly next to each other, wherein the detector surface (26, 27; 34) of the at least one second detector (24, 25; 33) largely surrounds the detector surface (22; 32) of the first detector (21, 31), and the first detector (21; 31) can be read out independently of the at least one second detector (24, 25; 33). The inventive spectrometer system yields a good signal-to-noise ratio both for large and small selected sample areas.
Abstract:
An encoder spectrograph is used to analyze radiation from one or more samples in various configurations. The radiation is analyzed by spatially modulating the radiation after it has been dispersed by wavelength or imaged along a line. Dual encoder spectrographs may be used to encode radiation using a single modulator. A spectra sorting algorithm is used to determine calibration training spectra for a spectrometer in a spectrometer calibration training mode.