公开(公告)号：US4820676A

公开(公告)日：1989-04-11

申请号：US199744

申请日：1988-05-26

Applicant: Simon G. Kukes ,  Karlheinz K. Brandes

Inventor： Simon G. Kukes ,  Karlheinz K. Brandes

IPC: B01J35/10 ,  C10G45/04 ,  B01J21/04 ,  B01J23/74 ,  B01J23/85 ,  B01J27/053

CPC classification number: C10G45/04 ,  B01J21/04 ,  B01J35/00 ,  B01J35/108 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042

Abstract: A process for preparing impregnated substantially spherical alumina-containing particles comprises the steps of impregnating specific starting material with (NH.sub.4).sub.2 SO.sub.4 and then heating the thus impregnated material at about 500.degree.-900.degree. C. for improved crush strength retention. In a preferred embodiment a fixed catalyst bed comprises at least one layer of the alumina-containing particles and at least one layer of catalyst particles comprising a refractory inorganic carrier and at least one hydrogenation promoter.

Abstract translation: 制备浸渍的基本上呈球形的含氧化铝颗粒的方法包括以下步骤：用（NH 4）2 SO 4浸渍特定原料，然后在约500-900℃下加热所浸渍的材料，以改善压碎强度保留。 在优选的实施方案中，固定的催化剂床包括至少一层含氧化铝的颗粒和至少一层包含耐火无机载体和至少一种氢化促进剂的催化剂颗粒层。

公开(公告)号：US4552642A

公开(公告)日：1985-11-12

申请号：US507864

申请日：1983-06-27

Applicant: William P. Hettinger, Jr.

Inventor： William P. Hettinger, Jr.

IPC: B01J23/85 ,  B01J35/00 ,  C10G1/00 ,  C10G1/08

CPC classification number: B01J35/00 ,  B01J23/85 ,  C10G1/002 ,  C10G1/086

Abstract: An H-Coal Process hydrogenation operation and catalyst life is substantially improved when using colloidal particles of catalyst comprising a colloidal matrix of silica, alumina, titania and combinations thereof coated with hydrogenating components selected from cobalt, molybdenum, nickel, tungsten and combinations thereof. The colloidal catalyst activity may be altered by alkaline promoters, other metals and acidic promoters.

公开(公告)号：US4432872A

公开(公告)日：1984-02-21

申请号：US274622

申请日：1981-06-17

Applicant: Wolfgang Faul ,  Bertel Kastening

Inventor： Wolfgang Faul ,  Bertel Kastening

IPC: C02F1/46 ,  B01J10/00 ,  B01J19/00 ,  B01J21/18 ,  B01J23/42 ,  B01J35/00 ,  B01J35/04 ,  C25C7/02 ,  H01M4/86 ,  B01J8/06

CPC classification number: H01M4/86 ,  B01J35/00 ,  C25C7/02

Abstract: A plate or hollow cylinder of coarsely porous graphite is coated with a layer of finely porous activated carbon that has previously been heat-treated. The fine layer is impregnated with a catalyst either before or after application to the graphite body. A gas is caused to flow through the graphite body and out through the finely porous layer containing the catalyst, to react with substances in a solution in which the carrier body is immersed. For oxidation, air can be used, and for reduction, hydrogen. In this manner, sulfite can be oxidized or chromate reduced and hydrogen gas can also be used to precipitate platinum, rhodium, copper and other metals from solution. Electro-chemical activation or regeneration of the catalyst is possible by applying a potential to the carrier body. The reaction can be carried on in solutions in which solids are suspended without clogging the catalyst.

Abstract translation: 涂有粗过孔石墨的板或中空圆筒，其上已经进行过热处理的细孔活性炭层。 在施加到石墨体之前或之后，用催化剂浸渍细层。 使气体通过石墨体流过包含催化剂的细孔层，与载体体浸入溶液中的物质反应。 为了氧化，可以使用空气，还可以还原氢气。 以这种方式，亚硫酸盐可以被氧化或铬酸盐还原，也可以使用氢气从溶液中沉淀出铂，铑，铜和其他金属。 催化剂的电化学活化或再生可以通过向载体体施加电位。 反应可以在其中悬浮固体而不堵塞催化剂的溶液中进行。

公开(公告)号：US4424248A

公开(公告)日：1984-01-03

申请号：US276169

申请日：1981-06-22

Applicant: Gu/ nter H. Tesch ,  Johannes J. V. Colijn

Inventor： Gu/ nter H. Tesch ,  Johannes J. V. Colijn

IPC: B32B5/16 ,  A01G31/00 ,  B01D17/02 ,  B01D39/00 ,  B01D39/08 ,  B01J20/28 ,  B01J35/00 ,  B01J47/12 ,  B32B5/06 ,  B32B5/30 ,  B32B7/04 ,  C02F1/68 ,  D04H13/00

CPC classification number: B01J20/28033 ,  A01G31/001 ,  B01D17/0202 ,  B01D39/00 ,  B01D39/2058 ,  B01D39/2065 ,  B01J20/106 ,  B01J20/28004 ,  B01J20/28023 ,  B01J20/2803 ,  B01J35/00 ,  B32B5/06 ,  C02F1/681 ,  D04H1/4291 ,  D04H1/498 ,  D04H13/00 ,  B01D2239/0407 ,  B01D2239/0414 ,  B01D2239/065 ,  B01D2239/1241 ,  Y10S55/43 ,  Y10T428/234 ,  Y10T428/24562 ,  Y10T428/24612

Abstract: Fine grain or fibrous solid active particles are immobilized in an areal or flat, flexible stratified body. The active particles serve for treating a liquid or gaseous medium circulating between the stratified body and the surroundings. The treatment, among other things, encompasses the sorption of substances, if desired, followed by desorption for regenerating the active particles, the emission of substances, the ion exchange and the catalysts of chemical reactions. The active substances or particles are enclosed between a base or substratum layer and a fiber-containing cover layer. Both layers are held together by means of holding fibers which are densely distributed over the entire surface and simultaneously anchored in both layers, whereby at the same time there are also immobilized the active particles. According to a preferred method the holding fibers are removed from the cover layer by fiber-orienting needles.

Abstract translation: 细颗粒或纤维状固体活性颗粒固定在面或平的柔性分层体内。 活性颗粒用于处理在分层体和周围环境之间循环的液体或气体介质。 除其他之外，处理包括物质的吸附，如果需要，然后解吸用于再生活性颗粒，物质的排放，离子交换和化学反应的催化剂。 活性物质或颗粒被包封在基底层或基层和含纤维的覆盖层之间。 通过保持密集分布在整个表面上并同时锚定在两个层中的纤维将两层保持在一起，从而同时固定有活性颗粒。 根据优选的方法，通过纤维定向针将保持纤维从覆盖层去除。

公开(公告)号：US3902545A

公开(公告)日：1975-09-02

申请号：US38556573

申请日：1973-08-03

Applicant: CORNING GLASS WORKS

Inventor： DOMICONE JOSEPH J ,  PARKER CHARLES J

IPC: B01J21/16 ,  B01J33/00 ,  B01J35/00 ,  C04B41/48 ,  C04B41/49 ,  C04B41/83 ,  C04B41/84 ,  F28D19/04 ,  F28D7/02 ,  B32B27/06

CPC classification number: B01J21/16 ,  B01J33/00 ,  B01J35/00 ,  C04B41/4838 ,  C04B41/4961 ,  C04B41/83 ,  C04B41/84 ,  F28D19/042 ,  Y10T428/31645 ,  Y10T428/31938

Abstract: Beta-spodumene ceramic articles such as gas turbine regenerators are rendered more resistant to attack by moist sulfur oxidecontaining gases such as the exhaust gases from certain hydrocarbon combustion processes by providing a protective layer of fluorinated ethylene-propylene copolymer thereon.

Abstract translation: 诸如燃气轮机再生器的β-锂辉石陶瓷制品通过在其上提供氟化乙烯 - 丙烯共聚物的保护层而更耐受含湿硫氧化物的气体（例如来自某些烃燃烧过程的废气）的侵蚀。

公开(公告)号：US12076710B2

公开(公告)日：2024-09-03

申请号：US18174695

申请日：2023-02-27

Applicant: Mitsubishi Chemical Corporation

Inventor： Kazuharu Tazawa ,  Takanori Taniguchi ,  Takuya Nakamura

IPC: B01J23/887 ,  B01J21/08 ,  B01J23/00 ,  B01J23/843 ,  B01J23/883 ,  B01J35/00 ,  B01J35/30 ,  B01J35/40 ,  B01J35/50 ,  B01J35/61 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/06 ,  B01J37/08 ,  C07C45/35 ,  C07C51/25

CPC classification number: B01J23/8877 ,  B01J21/08 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/883 ,  B01J23/8876 ,  B01J35/00 ,  B01J35/30 ,  B01J35/40 ,  B01J35/50 ,  B01J35/613 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/0228 ,  B01J37/0236 ,  B01J37/0244 ,  B01J37/038 ,  B01J37/06 ,  B01J37/08 ,  C07C45/35 ,  C07C51/252 ,  B01J2523/00

Abstract: A ring-shaped catalyst may have a straight body part and a hollow body part, which is used when a gas-phase catalytic oxidation reaction of a material substance is conducted to produce a target substance, wherein a length of the straight body part is shorter than a length of the hollow body part and at least at one end part, a region from an end part of the straight body part to an end part of the hollow body part is concavely curved.

公开(公告)号：US12023656B2

公开(公告)日：2024-07-02

申请号：US17577747

申请日：2022-01-18

Applicant: Saudi Arabian Oil Company ,  JGC Catalysts & Chemicals Ltd. ,  Japan Cooperation Center for Petroleum and Sustainable Energy

Inventor： Omer Refa Koseoglu ,  Robert Peter Hodgkins ,  Koji Uchida

IPC: B01J29/08 ,  B01J29/12 ,  B01J29/16 ,  B01J29/89 ,  B01J29/90 ,  B01J35/00

CPC classification number: B01J29/088 ,  B01J29/126 ,  B01J29/166 ,  B01J29/89 ,  B01J29/90 ,  B01J35/00 ,  B01J2229/183 ,  B01J2229/42

Abstract: Catalyst particles comprising one or more active metal components and methods for manufacturing such catalyst particles are provided. The particles are a composite of a granulating agent or binder material such as an inorganic oxide, and an ultra-stable Y (hereafter “USY”) zeolite in which some of the aluminum atoms in the framework are substituted with zirconium atoms and/or titanium atoms and/or hafnium atoms. The one or more active phase components are incorporated prior to mixing the binder with the post-framework modified USY zeolite, extruding the resulting composite mixture, and forming the catalyst particles. The one or more active phase components are incorporated in the binder material prior to forming the catalyst particles.

公开(公告)号：US11980874B2

公开(公告)日：2024-05-14

申请号：US17296204

申请日：2020-04-14

Applicant: DALIAN UNIVERSITY OF TECHNOLOGY ,  DALIAN QIYUAN TECHNOLOGY CO., LTD.

Inventor： Hongchen Guo ,  Cuilan Miao ,  Quanren Zhu

IPC: B01J29/89 ,  B01J29/035 ,  B01J35/00 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10

CPC classification number: B01J29/89 ,  B01J29/035 ,  B01J35/00 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/082 ,  B01J37/10 ,  B01J2229/18 ,  B01J2229/30

Abstract: An alkali metal ion modified titanium silicalite zeolite TS-1 for gas phase epoxidation of propylene and hydrogen peroxide and a preparation method thereof. The method includes: 1: preparing an alkali metal hydroxide modification solution containing a small amount of TPA+ ions; 2: conducting a controlled hydrothermal treatment on a TS-1 zeolite matrix by using the alkali metal hydroxide solution containing a small amount of TPA+ ions; and 3: conducting post-treatment on the hydrothermally modified TS-1 zeolite. In the washing process, the modified TS-1 zeolite wet material is washed with a low concentration alkali metal hydroxide solution; and alkali metal ions are reserved on the silicon hydroxyl of the modified titanium silicalite zeolite. The prepared alkali metal ion modified titanium silicalite zeolite has significantly improved catalytic performance in the gas phase epoxidation of propylene and hydrogen peroxide.

公开(公告)号：US20160089665A1

公开(公告)日：2016-03-31

申请号：US14862341

申请日：2015-09-23

Applicant: CHEVRON U.S.A. INC.

Inventor： Yihua ZHANG ,  Kamala Raghunathan KRISHNA ,  Guan-Dao LEI ,  Theodorus Ludovicus Michael MAESEN

IPC: B01J29/74 ,  C10M101/02 ,  C10G45/64 ,  B01J35/10 ,  B01J35/00

CPC classification number: B01J29/74 ,  B01J21/04 ,  B01J29/7461 ,  B01J29/7492 ,  B01J35/00 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/1085 ,  C10G45/60 ,  C10G45/64 ,  C10G2300/1033 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/302 ,  C10G2300/304 ,  C10M101/02

Abstract: The present invention is directed to an improved finished hydroisomerization catalyst manufactured from a first high nanopore volume (HNPV) alumina having a broad pore size distribution (BPSD), and a second HNPV alumina having narrow pore size distribution (NPSD). Their combination yields a HNPV base extrudate having a low particle density as compared to a conventional base extrudates.

Abstract translation: 本发明涉及由具有宽孔径分布（BPSD）的第一高纳米孔体积（HNPV）氧化铝和具有窄孔径分布（NPSD）的第二HNPV氧化铝制成的改进的成品加氢异构化催化剂。 与传统的基础挤出物相比，它们的组合产生具有低颗粒密度的HNPV基础挤出物。

公开(公告)号：US20160089663A1

公开(公告)日：2016-03-31

申请号：US14862302

申请日：2015-09-23

Applicant: CHEVRON U.S.A. INC.

Inventor： Yihua ZHANG ,  Kamala Raghunathan KRISHNA ,  Guan-Dao LEI ,  Theodorus Ludovicus Michael MAESEN

IPC: B01J29/74 ,  C10G45/64 ,  C10M101/02 ,  B01J35/10

CPC classification number: B01J29/74 ,  B01J21/04 ,  B01J29/7461 ,  B01J29/7492 ,  B01J35/00 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J2229/20 ,  C10G45/64 ,  C10M101/02

Abstract: The present invention is directed to an improved finished hydroisomerization catalyst manufactured from a first high nanopore volume (HNPV) alumina having a broad pore size distribution (BPSD), and a second HNPV alumina having narrow pore size distribution (NPSD). Their combination yields a HNPV base extrudate having larger porosity with a bimodal pore size distribution as compared to a conventional base extrudates.

Abstract translation: 本发明涉及由具有宽孔径分布（BPSD）的第一高纳米孔体积（HNPV）氧化铝和具有窄孔径分布（NPSD）的第二HNPV氧化铝制成的改进的成品加氢异构化催化剂。 与常规的基础挤出物相比，它们的组合产生具有更大孔隙率的HNPV基础挤出物，具有双峰孔径分布。