公开(公告)号：US09561492B2

公开(公告)日：2017-02-07

申请号：US14869138

申请日：2015-09-29

Applicant: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

Inventor： Dong Won Hwang ,  Jong-San Chang ,  Pravin P. Upare ,  U-Hwang Lee ,  Young Kyu Hwang

IPC: C07D319/00 ,  B01J23/14 ,  C07D319/10 ,  C07D319/12 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J35/00 ,  C01G19/02 ,  B01J37/03 ,  B01J29/03 ,  B01J29/40 ,  B01J29/70

CPC classification number: B01J23/14 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J29/0308 ,  B01J29/405 ,  B01J29/7057 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/031 ,  B01J37/035 ,  C01G19/02 ,  C07D319/10 ,  C07D319/12

Abstract: The present invention provides a method for directly producing lactide by subjecting lactic acid to a dehydration reaction in the presence of a catalyst comprising a tin compound, preferably, a tin (IV) compound, wherein lactide can be produced directly or by one step from lactic acid, without going through the step of producing or separating lactic acid oligomer. The method of the present invention has advantages of causing no loss of lactic acid, having a high conversion ratio to lactic acid and a high selectivity to optically pure lactide, and maintaining a long life time of the catalyst. Further, since lactic acid oligomer is not or hardly generated and the selectivity of meso-lactide is low, the method also has an advantage that the cost for removing or purifying this can be saved.

公开(公告)号：US09555400B2

公开(公告)日：2017-01-31

申请号：US14187587

申请日：2014-02-24

Applicant: Clean Diesel Technologies, Inc.

Inventor： Zahra Nazarpoor ,  Stephen J. Golden

IPC: B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J23/32 ,  B01J23/89 ,  B01J23/889 ,  B01J37/02 ,  B01D53/94 ,  B01J37/03

CPC classification number: B01J23/8986 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/20715 ,  B01D2255/2073 ,  B01D2255/20761 ,  B01D2255/405 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2258/012 ,  B01J23/005 ,  B01J23/8892 ,  B01J37/0244 ,  B01J37/035 ,  B01J37/038 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/72 ,  B01J2523/31 ,  B01J2523/824

Abstract: Synergized Platinum Group Metals (SPGM) catalyst system for TWC application is disclosed. Disclosed SPGM catalyst system may include a washcoat that includes stoichiometric Cu—Mn spinel structure, supported on doped ZrO2, and an overcoat that includes PGM, such as platinum (Pt) supported on carrier material oxides, such as alumina. SPGM catalyst system shows significant improvement in nitrogen oxide reduction performance under lean and also rich operating conditions. Additionally, disclosed SPGM catalyst system exhibits enhanced catalytic activity for carbon monoxide conversion. Furthermore, disclosed SPGM catalyst systems are found to have enhanced catalytic activity compared to PGM catalyst system, showing that there is a synergistic effect between PGM catalyst, such as Pt, and Cu—Mn spinel within disclosed SPGM catalyst system, which help in activity and thermal stability of disclosed SPGM catalyst.

Abstract translation: 公开了用于TWC应用的协同铂族金属（SPGM）催化剂体系。 公开的SPGM催化剂体系可以包括修补基面涂层，其包括负载在掺杂的ZrO 2上的化学计量的Cu-Mn尖晶石结构，以及包含PGM的外涂层，例如负载在载体材料氧化物如氧化铝上的铂（Pt）。 SPGM催化剂体系在稀薄和丰富的操作条件下显示出氮氧化物还原性能的显着改善。 另外，所公开的SPGM催化剂体系对一氧化碳转化表现出增强的催化活性。 此外，发现所公开的SPGM催化剂体系与PGM催化剂体系相比具有增强的催化活性，表明在所公开的SPGM催化剂体系内的PGM催化剂如Pt和Cu-Mn尖晶石之间存在协同作用，这有助于活性和 公开的SPGM催化剂的热稳定性。

公开(公告)号：US20160372759A1

公开(公告)日：2016-12-22

申请号：US15141824

申请日：2016-04-29

Applicant: Panasonic Corporation

Inventor： YASUHIRO UEYAMA ,  TOSHIYUKI KOJIMA ,  YASUSHI TANIGUCHI ,  KAZUNORI KUBOTA ,  HIDEYUKI TAKAHASHI ,  SHUN YOKOYAMA ,  KAZUYUKI TOHJI ,  SHUZO TSUCHIDA

IPC: H01M4/92

CPC classification number: H01M4/926 ,  B01J23/42 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/008 ,  B01J37/031 ,  B01J37/035 ,  B82Y30/00 ,  H01M2008/1095

Abstract: A manufacturing method of a supported platinum catalyst, includes: generating a platinum group salt solution using platinum group salts and a complexing agent; mixing the platinum group salt solution and a carbon powder dispersion in which carbon powder is dispersed; and adding a reducing agent to a mixed solution of the platinum group salt solution and the carbon powder dispersion, and reducing the platinum group salts to allow the platinum group particles to be supported on the carbon powder.

Abstract translation: 负载铂催化剂的制造方法包括：使用铂族盐和络合剂生成铂族盐溶液; 混合铂族盐溶液和分散有碳粉末的碳粉分散体; 并将还原剂加入到铂族盐溶液和碳粉末分散体的混合溶液中，还原铂族盐，使铂族粒子负载在碳粉末上。

公开(公告)号：US20160310931A1

公开(公告)日：2016-10-27

申请号：US15135958

申请日：2016-04-22

Applicant: OSAKA UNIVERSITY ,  N.E. CHEMCAT CORPORATION

Inventor： KIYOTOMI KANEDA ,  YUKIO TAKAGI

IPC: B01J23/66 ,  C07C29/141 ,  B01J37/00 ,  B01J23/02 ,  B01J35/00

CPC classification number: B01J23/66 ,  B01J23/007 ,  B01J27/232 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/0086 ,  B01J37/0236 ,  B01J37/035 ,  B01J2523/00 ,  C07C1/247 ,  C07C29/141 ,  C07C2523/10 ,  C07C2523/50 ,  C07C2523/66 ,  B01J2523/18 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/23 ,  C07C33/32 ,  C07C15/52

Abstract: Conventionally, a silver-cerium oxide composite containing a silver particle and cerium oxide covering the surface of the silver particle has been synthesized through a multi-stage process, and is disadvantageous not only in that there is a need to use an organic solvent and a surfactant, causing the time and cost to be increased, but also in that there is a possiblity that fulminating silver is formed, leading to a problem about the safety. A method for producing a catalyst having a silver-cerium oxide composite and an alkaline carrier having supported thereon the oxide composite, the silver-cerium oxide composite containing a silver particle and cerium oxide covering the surface of the silver particle, the method having preparing a mixture containing a silver compound, a cerium compound, and an alkaline carrier, and drying the mixture is provided.

Abstract translation: 通常，通过多级方法合成了含有覆盖银粒子表面的银粒子和氧化铈的银 - 氧化铈复合体，不仅在于需要使用有机溶剂和 表面活性剂，导致时间和成本增加，而且由于存在形成暴发性银的可能性，导致安全性问题。 一种制备具有银 - 氧化铈复合物的催化剂和负载有氧化物复合物的碱性载体的方法，包含覆盖银颗粒表面的银颗粒和氧化铈的银 - 氧化铈复合材料，该方法具有制备 提供含有银化合物，铈化合物和碱性载体的混合物，并干燥该混合物。

公开(公告)号：US20160296921A1

公开(公告)日：2016-10-13

申请号：US15101160

申请日：2014-12-09

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Debasish Das ,  Onen Amiruddin Attarwala

IPC: B01J29/08 ,  C07C2/86 ,  B01J37/04 ,  B01J23/75 ,  B01J35/00

CPC classification number: B01J29/082 ,  B01J23/75 ,  B01J29/143 ,  B01J35/0006 ,  B01J37/035 ,  B01J37/04 ,  C07C2/864 ,  C07C2521/02 ,  C07C2523/04 ,  C07C2523/75 ,  C07C2529/14 ,  C07C15/46

Abstract: The invention relates to a process for the preparation of a catalyst composition comprising the steps of: A) preparing a salt of boric acid or phosphoric acid and a bivalent or trivalent metal and B) mixing the salt obtained by step A) with a crystalline aluminosilicate zeolite of the faujasite structure with SiO2/Al2O3 mole ratio in the range of about 2 to about 8 and including potassium, rubidium or cesium cations or combinations thereof, wherein step A) comprises the sub-steps of A1) mixing a borate or a phosphate of an alkali metal and a water soluble salt of the bivalent or trivalent metal to obtain a suspension, A2) adding an alkaline solution to the suspension obtained by sub-step A1) to obtain a solution having a pH of 7.0-11.5 and A3) mixing the solution obtained by sub-step A2) to obtain the salt.

Abstract translation: 本发明涉及一种制备催化剂组合物的方法，包括以下步骤：A）制备硼酸或磷酸和二价或三价金属的盐，以及B）将由步骤A）得到的盐与结晶硅铝酸盐 八面沸石结构的沸石，其SiO 2 / Al 2 O 3摩尔比在约2至约8的范围内，并且包括钾，铷或铯阳离子或其组合，其中步骤A）包括以下子步骤：A1）将硼酸盐或磷酸盐 的碱金属和二价或三价金属的水溶性盐以获得悬浮液，A2）向通过步骤A1）得到的悬浮液中加入碱性溶液，得到pH为7.0-11.5的溶液和A3） 将通过步骤A2）得到的溶液混合，得到盐。

公开(公告)号：US20160288105A1

公开(公告)日：2016-10-06

申请号：US15185326

申请日：2016-06-17

Applicant: CELANESE INTERNATIONAL CORPORATION

Inventor： Zhenhua ZHOU ,  Victor J. JOHNSTON ,  Heiko WEINER

IPC: B01J23/89 ,  B01J35/00 ,  C07C29/149 ,  B01J35/02 ,  B01J35/08 ,  B01J21/08 ,  B01J35/10

CPC classification number: B01J23/8993 ,  B01J21/08 ,  B01J23/8966 ,  B01J35/0006 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/035 ,  B01J2523/00 ,  C07C29/147 ,  C07C29/149 ,  C07C31/08 ,  B01J2523/41 ,  B01J2523/43 ,  B01J2523/821 ,  B01J2523/845

Abstract: A process is disclosed for producing ethanol, comprising contacting hydrogen and a feed stream comprising acetic acid in a reactor in the presence of a catalyst comprising a binder and a mixed oxide comprising a promoter metal and tin, and preferably also comprising cobalt. The promoter metal is selected from the group consisting of rhenium, ruthenium, rhodium, palladium, osmium, iridium, platinum, and combinations thereof. The feed stream may comprises pure acetic acid or may comprise a mixture of 50 to 95 wt. % acetic acid and 5 to 50 wt. % ethyl acetate.

Abstract translation: 公开了一种用于生产乙醇的方法，包括在包含粘合剂和包含助催化剂金属和锡的混合氧化物，优选还包含钴的催化剂存在下，在反应器中使氢气和包含乙酸的进料流接触。 助催化剂金属选自铼，钌，铑，钯，锇，铱，铂及其组合。 进料流可以包含纯乙酸，或可以包含50至95wt。 ％乙酸和5〜50wt。 ％ 乙酸乙酯。

公开(公告)号：US09458072B2

公开(公告)日：2016-10-04

申请号：US14740797

申请日：2015-06-16

Applicant: Celanese International Corporation

Inventor： Heiko Weiner ,  Zhenhua Zhou ,  Victor J. Johnston

IPC: C07C29/149 ,  B01J23/89 ,  B01J23/835 ,  B01J23/75 ,  B01J23/14 ,  B01J37/03 ,  B01J35/10

CPC classification number: C07C29/149 ,  B01J23/14 ,  B01J23/75 ,  B01J23/835 ,  B01J23/8966 ,  B01J35/1019 ,  B01J37/035 ,  B01J2523/00 ,  C07C31/08 ,  B01J2523/31 ,  B01J2523/43 ,  B01J2523/845

Abstract: A process is disclosed for producing ethanol, comprising contacting acetic acid and hydrogen in a reactor in the presence of a catalyst comprising a binder and a mixed oxide comprising cobalt and preferably tin, wherein the mixed oxide is present in an amount from 60 to 90 wt. %, based on the total weight of the catalyst.

公开(公告)号：US20160228853A1

公开(公告)日：2016-08-11

申请号：US15022956

申请日：2014-10-30

Applicant: MAZDA MOTOR CORPORATION

Inventor： Yasuhiro MATSUMURA ,  Masahiko SHIGETSU ,  Hisaya KAWABATA ,  Yuki KODA

IPC: B01J23/63 ,  B01D53/94 ,  B01J37/08 ,  B01J37/03 ,  B01J23/00 ,  B01J37/16

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/1025 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2068 ,  B01D2255/20715 ,  B01D2255/407 ,  B01J23/002 ,  B01J35/0066 ,  B01J35/04 ,  B01J35/1014 ,  B01J37/03 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  B01J37/16 ,  B01J2523/00 ,  F01N2370/02 ,  Y02T10/22 ,  B01J2523/36 ,  B01J2523/3706 ,  B01J2523/48 ,  B01J2523/822

Abstract: An exhaust gas purification catalytic material is made of a composite oxide. This composite oxide contains Zr and a plurality of rare earth metals, and is doped with Rh. An surface portion of the composite oxide has a higher concentration of at least one of the rare earth metals than an inner portion thereof.

Abstract translation: 废气净化催化剂材料由复合氧化物制成。 该复合氧化物含有Zr和多种稀土金属，并掺杂有Rh。 复合氧化物的表面部分比其内部具有比稀土金属中的至少一种更高的浓度。

公开(公告)号：US09404045B2

公开(公告)日：2016-08-02

申请号：US13396160

申请日：2012-02-14

Applicant: Anne Mae Gaffney

Inventor： Anne Mae Gaffney

IPC: B01J29/06 ,  C10G1/10 ,  B01J29/44 ,  B01J29/064 ,  B01J29/068 ,  B01J29/076 ,  B01J29/42 ,  B01J29/90 ,  B01J37/03 ,  B01J37/16 ,  B01J38/12 ,  C10B49/22 ,  C10B53/07 ,  C10B57/06 ,  C10G45/70 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  B01J37/10 ,  B01J37/28

CPC classification number: B01J29/068 ,  B01J23/40 ,  B01J23/70 ,  B01J23/89 ,  B01J29/064 ,  B01J29/072 ,  B01J29/076 ,  B01J29/42 ,  B01J29/44 ,  B01J29/90 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0215 ,  B01J37/035 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088 ,  B01J37/10 ,  B01J37/16 ,  B01J37/28 ,  B01J38/12 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C10B49/22 ,  C10B53/07 ,  C10B57/06 ,  C10G1/10 ,  C10G45/70 ,  C10G2300/1003 ,  C10G2300/4081 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30 ,  Y02P20/143

Abstract: The presently disclosed and claimed inventive concept(s) generally relates to a solid catalyst component comprising a zeolite with a modifier and at least one Group VIII metal alloyed with at least one transition metal. The presently disclosed and claimed inventive concept(s) further relates to a method of making the solid catalyst component and a process of converting mixed waste plastics into low molecular weight organic compounds using the solid catalyst component.

Abstract translation: 目前公开和要求保护的发明概念通常涉及包含具有改性剂的沸石和与至少一种过渡金属合金化的至少一种Ⅷ族金属的固体催化剂组分。 目前公开和要求保护的发明构思还涉及制备固体催化剂组分的方法和使用固体催化剂组分将混合废塑料转化为低分子量有机化合物的方法。

公开(公告)号：US20160207899A1

公开(公告)日：2016-07-21

申请号：US15023668

申请日：2014-09-17

Applicant: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH

Inventor： Guangshun YI ,  Yugen ZHANG

IPC: C07D307/68 ,  B01J23/00 ,  B01J35/00 ,  B01J23/52

CPC classification number: C07D307/68 ,  B01J23/007 ,  B01J23/52 ,  B01J23/66 ,  B01J35/0013 ,  B01J37/035 ,  C07D307/48

Abstract: The present invention relates to a method for synthesizing an optionally substituted furoic acid by dehydrating a biomass and oxidizing the optionally substituted furan derived from the dehydration reaction. Water extraction has been incorporated as a step between the dehydration and the oxidation in order to purify the intermediate optionally substituted furan before having it oxidized. Prior to this water extraction, the organic solvent used for dehydration may be separated by evaporation. The provision of the water extraction allows impurities to be separated from the intermediate optionally substituted furan.

Abstract translation: 本发明涉及通过使生物质脱水并氧化来自脱水反应的任选取代的呋喃来合成任选取代的糠酸的方法。 水提取作为脱水和氧化之间的步骤被并入，以在中和任选取代的呋喃被氧化之前进行纯化。 在这种水提取之前，用于脱水的有机溶剂可以通过蒸发分离。 提供水提取允许杂质与中间任选取代的呋喃分离。