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    Gasoline additives and gasoline containing soluble platinum group metal compounds and use in internal combustion engines
    66.
    发明授权
    Gasoline additives and gasoline containing soluble platinum group metal compounds and use in internal combustion engines 失效
    含有可溶性铂族金属化合物的汽油添加剂和汽油，用于内燃机

    公开(公告)号：US4891050A

    公开(公告)日：1990-01-02

    申请号：US897869

    申请日：1986-08-19

    Applicant: Wayne E. Bowers ,  Barry N. Sprague

    Inventor： Wayne E. Bowers ,  Barry N. Sprague

    IPC: C07F15/00 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/22 ,  C10L1/30 ,  C10L3/00 ,  C10L10/02

    CPC classification number: C10L1/14 ,  C07F15/0086 ,  C10L1/1814 ,  C10L1/301 ,  C10L1/305 ,  C10L10/02 ,  C10L3/003 ,  C10L1/1608 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/1855 ,  C10L1/1857 ,  C10L1/231

    Abstract: The invention provides gasoline additive compositions comprising solutions of at least one fuel-soluble platinum group metal compound in a solvent miscible in the gasoline, the platinum group metal complex being present in an amount sufficient to supply from 0.01 to 1.0 parts per million of the platinum group metal when added to a predetermined amount of gasoline.Preferred solvents are oxygenated hydrocarbons such as ethanol, tetrahydrofuran, and methyl tertiary butyl ether, and will preferably be employed in amounts of less than 5% of the weight of the gasoline to provide oxygen and the metal at a weight ratio of from 1,000:1 to 100,000:1. Especially preferred compounds are those of the formula:X M.sup.II R.sub.2wherein X is a cyclooctadienyl ligand; M is a platinum group metal; and R is benzyl, phenyl or nitrobenzyl.The additive compositions and fuel treated therewith improve operating efficiency of internal combustion engines in terms of increased power output per unit of fuel burned and reduce the emissions of particulates and noxious gases such as carbon monoxide and nitrogen monoxide. The additives provide beneficial results upon immediate use and over long periods of continuous use.

    Abstract translation: 本发明提供了汽油添加剂组合物，其包含至少一种可溶于燃料的铂族金属化合物在可与汽油混合的溶剂中的溶液，铂族金属络合物的存在量足以提供0.01至1.0ppm的铂 当添加到预定量的汽油时，将金属组合。 优选的溶剂是含氧烃如乙醇，四氢呋喃和甲基叔丁基醚，并且优选以低于汽油重量的5％的量使用以提供氧和重量比为1,000:1的金属 至100,000：1。 特别优选的化合物是下式的化合物：X MII R2其中X是环辛二烯基配体; M是铂族金属; R为苄基，苯基或硝基苄基。 添加剂组合物和经过处理的燃料可以提高内燃机的运行效率，从而提高每单位燃料燃料的功率输出，并减少颗粒物和有毒气体如一氧化碳和一氧化氮的排放。 这些添加剂在立即使用和长时间连续使用时提供有益的结果。

    Fuel composition and method for control of engine octane requirements
    67.
    发明授权
    Fuel composition and method for control of engine octane requirements 失效
    用于控制发动机辛烷值要求的燃料组成和方法

    公开(公告)号：US4844717A

    公开(公告)日：1989-07-04

    申请号：US185148

    申请日：1988-04-22

    Applicant: Michael C. Croudace ,  Timothy Wusz ,  Stephen Brass

    Inventor： Michael C. Croudace ,  Timothy Wusz ,  Stephen Brass

    IPC: C10L1/14 ,  C10L1/18 ,  C10L1/22

    CPC classification number: C10L10/10 ,  C10L1/14 ,  C10L1/1857 ,  C10L1/224

    Abstract: The octane requirement increase phenomenon in a spark ignition internal combustion engine is controlled by introducing with the combustion charge a fuel composition containing an octane requirement increase-inhibiting amount of a combination of compounds, the combination comprising a first compound being (1) a gasoline soluble amide and (2) a second compound being a gasoline soluble ketone. Usually the first and second compounds are each added to the fuel in an amount between about 0.001 and 3 weight percent of the fuel. In particular, the combination of N,N-dibutyl formamide and either benzophenone or methylcyclohexanone provides an effective octane requirement increase-inhibiting additive for unleaded gasoline.

    Abstract translation: 火花点火式内燃机中的辛烷值要求增加现象是通过向燃烧装置中引入包含化合物组合的辛烷值增加抑制量的燃料组合物来控制的，所述组合包括第一化合物，其为（1）汽油可溶 酰胺和（2）第二化合物是汽油可溶性酮。 通常，第一和第二化合物各自以燃料的约0.001重量％至3重量％的量加入到燃料中。 特别地，N，N-二丁基甲酰胺和二苯甲酮或甲基环己酮的组合为无铅汽油提供了有效的辛烷值增加抑制添加剂。

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