公开(公告)号：US20160256855A1

公开(公告)日：2016-09-08

申请号：US14427207

申请日：2014-11-18

Applicant: LG CHEM, LTD.

Inventor： Dae Heung CHOI ,  Dong Hyun KO ,  Jun Han KANG ,  Kyong Yong CHA ,  Dae Chul KIM ,  Joo Hyuck LEE ,  Hyun Seok NAM ,  Myung Ji SUH ,  Ye Seul HWANG ,  Jun Kyu HAN ,  Sang Jin HAN

IPC: B01J23/887 ,  C07C5/48 ,  B01J37/02 ,  B01J29/04 ,  B01J35/02

CPC classification number: B01J23/8876 ,  B01J23/002 ,  B01J23/31 ,  B01J29/04 ,  B01J29/076 ,  B01J29/26 ,  B01J29/48 ,  B01J29/7807 ,  B01J29/7815 ,  B01J35/026 ,  B01J37/0221 ,  B01J37/0236 ,  B01J37/0246 ,  B01J2229/64 ,  B01J2523/00 ,  C07C5/48 ,  C07C2523/04 ,  C07C2523/28 ,  C07C2523/31 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/887 ,  C07C11/167 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845

Abstract: The present invention relates to a bismuth molybdate-based composite oxide catalyst having a microporous zeolite coating layer on the surface thereof and thus having high selectivity for 1,3-butadiene, a method of preparing the same, and a method of preparing 1,3-butadiene using the same. The catalyst has a microporous zeolite coating layer, and thus enables only gaseous products (light) to selectively pass through the zeolite coating layer, improving selectivity for 1,3-butadiene.

Abstract translation: 本发明涉及一种在其表面具有微孔沸石涂层的钼酸铋基复合氧化物催化剂，因此对1,3-丁二烯具有高选择性，其制备方法和制备1,3 丁二烯使用相同。 催化剂具有微孔沸石涂层，因此仅使气态产物（光）选择性地通过沸石涂层，提高1,3-丁二烯的选择性。

公开(公告)号：US20190184388A1

公开(公告)日：2019-06-20

申请号：US15735813

申请日：2016-12-21

Applicant: LG CHEM, LTD.

Inventor： Sun Hwan HWANG ,  Dong Hyun KO ,  Kyong Yong CHA ,  Dae Heung CHOI ,  Myung Ji SUH ,  Ye Seul HWANG ,  Jun Kyu HAN ,  Seong Min KIM ,  Jun Han KANG ,  Joo Hyuck LEE ,  Hyun Seok NAM ,  Sang Jin HAN

IPC: B01J37/03 ,  B01J23/80 ,  B01J37/04 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J23/06 ,  C07C5/48

CPC classification number: B01J37/031 ,  B01J21/10 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J23/34 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/80 ,  B01J23/88 ,  B01J37/00 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C07C5/48 ,  C07C2523/80

Abstract: The present invention relates to a catalyst for oxidative dehydrogenation and a method of preparing the same. More particularly, the present invention provides a catalyst for oxidative dehydrogenation allowing oxidative dehydrogenation reactivity to be secured while increasing a first pass yield, and a method of preparing the catalyst.

公开(公告)号：US20170036972A1

公开(公告)日：2017-02-09

申请号：US15021611

申请日：2015-10-20

Applicant: LG CHEM, LTD.

Inventor： Sang Jin HAN ,  Jun Han KANG ,  Dong Hyun KO ,  Hyun Seok NAM ,  Joo Hyuck LEE ,  Jun Kyu HAN ,  Myung Ji SUH ,  Kyong Yong CHA ,  Dae Heung CHOI ,  Ye Seul HWANG

IPC: C07C5/48

CPC classification number: C07C5/48 ,  B01J3/00 ,  C07C5/3332 ,  C07C5/42 ,  C07C7/005 ,  C07C7/05 ,  C07C11/167

Abstract: Disclosed are a method of preparing conjugated diene and a device therefor. More particularly, disclosed a method of preparing conjugated diene, wherein generated gas including butadiene is cooled and then water discharged at a lower part is not directly treated as waste water and subjected to byproduct removal and steam-extraction to utilize converted steam, and an installation issue of an existing biological waste water disposal equipment due to an excessive amount of byproducts can be resolved, and a device therefor are disclosed.

Abstract translation: 公开了一种制备共轭二烯及其装置的方法。 更具体地，公开了一种制备共轭二烯的方法，其中包括丁二烯在内的产生的气体被冷却，然后在下部排出的水不直接作为废水处理，并进行副产物除去和蒸汽萃取以利用转化的蒸汽，以及安装 可以解决由于过量的副产物而产生的现有生物废水处理设备的问题，并且公开了一种其设备。

公开(公告)号：US20180290126A1

公开(公告)日：2018-10-11

申请号：US15765445

申请日：2017-05-18

Applicant: LG CHEM, LTD.

Inventor： Seongmin KIM ,  Dong Hyun KO ,  Kyong Yong CHA ,  Dae Heung CHOI ,  Myung Ji SUH ,  Jun Kyu HAN ,  Sun Hwan HWANG ,  Jun Han KANG ,  Joo Hyuck LEE ,  Hyun Seok NAM ,  Ye Seul HWANG ,  Sang Jin HAN

IPC: B01J23/00 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/825 ,  B01J23/83 ,  B01J23/847 ,  B01J23/86 ,  B01J23/889 ,  B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/16 ,  B01J27/224 ,  B01J27/24 ,  B01J37/02 ,  B01J35/02 ,  B01J37/08 ,  C07C5/48 ,  C07C11/167

Abstract: Disclosed are a catalyst for oxidative dehydrogenation and a method of preparing the same. More particularly, a catalyst for oxidative dehydrogenation of butene having a high butene conversion rate and superior side reaction inhibition effect and thus having high reactivity and high selectivity for a product by preparing metal oxide nanoparticles and then fixing the prepared metal oxide nanoparticles to a support, and a method of preparing the same are provided.

公开(公告)号：US20160368839A1

公开(公告)日：2016-12-22

申请号：US14900290

申请日：2015-06-04

Applicant: LG Chem, Ltd.

Inventor： Ye Seul HWANG ,  Dong Hyun KO ,  Kyong Yong CHA ,  Dae Heung CHOI ,  Myung Ji SUH ,  Jun Han KANG ,  Joo Hyuck LEE ,  Hyun Seok NAM ,  Jun Kyu HAN ,  Sang Jin HAN

IPC: C07C5/333 ,  B01J37/08 ,  B01J37/04 ,  B01J37/03 ,  B01J23/887 ,  B01J35/00

CPC classification number: C07C5/3332 ,  B01J23/002 ,  B01J23/881 ,  B01J23/8876 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/03 ,  B01J37/031 ,  B01J37/035 ,  B01J37/04 ,  B01J37/08 ,  B01J37/088 ,  B01J2523/00 ,  C07C5/48 ,  C07C2523/31 ,  C07C2523/887 ,  B01J2523/13 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  C07C11/167

Abstract: Provided are a method of preparing a multicomponent bismuth-molybdenum composite metal oxide catalyst, and a multicomponent bismuth-molybdenum composite metal oxide catalyst prepared thereby. According to the preparation method, since the almost same structure as that of a typical quaternary bismuth-molybdenum catalyst may be obtained by performing two-step co-precipitation, i.e., primary and secondary co-precipitation, of metal components constituting the catalyst, the reduction of catalytic activity due to the deformation of the structure of the catalyst may be suppressed. Also, since the multicomponent bismuth-molybdenum composite metal oxide catalyst may adjust the number of lattice oxygens consumed during a reaction to increase the catalytic activity, the multicomponent bismuth-molybdenum composite metal oxide catalyst may reduce the formation of by-products and may improve the conversion rate of reactant and the yield of desired product in a catalytic reaction process using the above catalyst, particularly, a catalytic reaction process under a relatively low temperature condition.

Abstract translation: 提供制备多组分铋 - 钼复合金属氧化物催化剂的方法和由其制备的多组分铋 - 钼复合金属氧化物催化剂。 根据制备方法，由于通过进行构成催化剂的金属组分的两步共沉淀（即一次和二次共沉淀）可以获得与典型的四价铋 - 钼催化剂几乎相同的结构， 可以抑制由于催化剂结构的变形引起的催化活性的降低。 此外，由于多组分铋钼复合金属氧化物催化剂可以调节反应期间消耗的晶格氧数以增加催化活性，所以多组分铋钼复合金属氧化物催化剂可以减少副产物的形成，并且可以改善 反应物的转化率和所需产物在使用上述催化剂的催化反应过程中的产率，特别是在较低温度条件下的催化反应过程。

公开(公告)号：US20180214854A1

公开(公告)日：2018-08-02

申请号：US15746758

申请日：2017-02-17

Applicant: LG CHEM, LTD.

Inventor： Dae Heung CHOI ,  Dong Hyun KO ,  Kyong Yong CHA ,  Myung Ji SUH ,  Ye Seul HWANG ,  Sun Hwan HWANG ,  Seong Min KIM ,  Jun Han KANG ,  Joo Hyuck LEE ,  Hyun Seok NAM ,  Sang Jin HAN ,  Jun Kyu HAN

IPC: B01J23/745 ,  B01J23/75 ,  B01J23/78 ,  B01J23/80 ,  B01J23/889 ,  B01J35/02 ,  B01J35/08 ,  B01J37/00 ,  B01J37/03 ,  B01J37/08

Abstract: The present invention relates to a ferrite-based catalyst composite, a method of preparing the same, and a method of preparing butadiene using the same. More particularly, the present invention provides a ferrite-based catalyst composite having a shape that allows effective dispersion of excess heat generated in a butadiene production process and prevention of catalyst damage and side reaction occurrence by reducing direct exposure of a catalyst to heat, a method of preparing the ferrite-based catalyst composite, and a method of preparing butadiene capable of lowering the temperature of a hot spot and reducing generation of Cox by allowing active sites of a catalyst to have a broad temperature gradient (profile) during oxidative dehydrogenation using the ferrite-based catalyst composite, and thus, providing improved process efficiency.

公开(公告)号：US20180186711A1

公开(公告)日：2018-07-05

申请号：US15561316

申请日：2017-03-30

Applicant: LG CHEM, LTD.

Inventor： Myung Ji SUH ,  Jun Han KANG ,  Dong Hyun KO ,  Seong Min KIM ,  Hyun Seok NAM ,  Joo Hyuck LEE ,  Kyong Yong CHA ,  Dae Heung CHOI ,  Sang Jin HAN ,  Jun Kyu HAN ,  Sun Hwan HWANG ,  Ye Seul HWANG

IPC: C07C5/48 ,  B01J35/04 ,  B01J23/80 ,  B01J37/02 ,  B01J37/08 ,  B01J37/03 ,  B01J35/02 ,  B01J37/00

CPC classification number: C07C5/48 ,  B01J23/74 ,  B01J23/78 ,  B01J23/80 ,  B01J23/84 ,  B01J35/023 ,  B01J35/04 ,  B01J37/00 ,  B01J37/009 ,  B01J37/02 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/08 ,  C07C7/20 ,  C07C11/08

Abstract: The present invention relates to a catalyst for coating a surface of a porous material and a method of treating the surface of the porous material. More particularly, when the catalyst for coating a surface of a porous material and the method of treating the surface of the porous material of the present invention are used for butadiene synthesis reaction under high gas space velocity and high pressure conditions, heat generation may be easily controlled and differential pressure may be effectively alleviated, thereby providing improved reactant conversion rate and product selectivity.

公开(公告)号：US20190134612A1

公开(公告)日：2019-05-09

申请号：US16307317

申请日：2018-01-04

Applicant: LG CHEM, LTD.

Inventor： Sun Hwan HWANG ,  Dong Hyun KO ,  Jun Han KANG ,  Kyong Yong CHA ,  Joo Hyuck LEE ,  Hyun Seok NAM ,  Dae Heung CHOI ,  Myung Ji SUH ,  Ye Seul HWANG ,  Jun Kyu HAN ,  Sang Jin HAN ,  Seong Min KIM

IPC: B01J23/80 ,  B01J37/08 ,  B01J35/10 ,  C07C11/167 ,  C07C5/48

Abstract: A ferrite catalyst for oxidative dehydrogenation and a method of preparing the same. The ferrite catalyst is prepared using an epoxide-based sol-gel method, wherein a step of burning includes a first burning step, in which burning is performed at a temperature of 70 to 200° C.; and a second burning step, in which burning is performed after the temperature is raised from a temperature in the range of greater than 200° C. to 250° C. to a temperature in the range of 600 to 900° C.

公开(公告)号：US20160347685A1

公开(公告)日：2016-12-01

申请号：US15035430

申请日：2015-11-25

Applicant: LG CHEM, LTD.

Inventor： Dae Heung CHOI ,  Dong Hyun KO ,  Myung Ji SUH ,  Kyong Yong CHA ,  Ye Seul HWANG ,  Jun Han KANG ,  Hyun Seok NAM ,  Joo Hyuck LEE ,  Sang Jin HAN ,  Jun Kyu HAN

IPC: C07C5/48 ,  B01J23/887 ,  B01J23/00

CPC classification number: C07C5/48 ,  B01J23/00 ,  B01J23/002 ,  B01J23/8876 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  C07C2523/02 ,  C07C2523/887 ,  C07C11/167 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845

Abstract: The present invention relates to a method of preparing butadiene. More particularly, the present invention relates to a method of preparing butadiene by feeding butene and oxygen into a reactor containing a composite metal oxide catalyst and performing oxidative dehydrogenation, wherein a mole ratio of the oxygen to the butene is 1.8 to 2.2.In accordance with the present invention, a method of preparing butadiene to secure long-term operation stability by maintaining the intensity of a catalyst despite oxidative dehydrogenation and not to decrease selectivity due to less side reaction is provided.

Abstract translation: 根据本发明，提供一种制备丁二烯的方法，通过保持催化剂的强度，尽管氧化脱氢，并且由于较少的副反应而降低选择性，从而确保长期的操作稳定性。

公开(公告)号：US20150352534A1

公开(公告)日：2015-12-10

申请号：US14763104

申请日：2014-11-14

Applicant: LG CHEM, LTD.

Inventor： Dae Chul KIM ,  Dong Hyun KO ,  Sung June CHO ,  Ju Han KANG ,  Kyong Yong CHA ,  Joo Hyuck LEE ,  Hyun Seok NAM ,  Dae Heung CHOI ,  Myung Ji SUH ,  Ye Seul HWANG ,  Jun Kyu HAN ,  Sang Jin HAN

IPC: B01J27/236 ,  B01J37/03 ,  C01F7/00 ,  B01J37/00 ,  B01J37/08 ,  B01J37/04 ,  B01J37/02

CPC classification number: B01J27/236 ,  B01J23/002 ,  B01J23/007 ,  B01J23/31 ,  B01J23/8876 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  C01F7/005 ,  C07C5/48 ,  C07C2523/28 ,  C07C2523/31 ,  C07C11/167 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/22 ,  B01J2523/31

Abstract: Disclosed are a catalyst composition for oxidative dehydrogenation and a method of preparing the same. More particularly, disclosed is a catalyst composition comprising a multi-ingredient-based metal oxide catalyst and a mixed metal hydroxide. The catalyst composition and the method of preparing the same according to the present disclosure may prevent loss occurring in a filling process due to superior mechanical durability and wear according to long-term use, may inhibit polymer formation and carbon deposition during reaction, and may provide a superior conversion rate and superior selectivity.

Abstract translation: 公开了用于氧化脱氢的催化剂组合物及其制备方法。 更具体地，公开了包含多成分基金属氧化物催化剂和混合金属氢氧化物的催化剂组合物。 根据本公开的催化剂组合物及其制备方法可以防止由于优异的机械耐久性和根据长期使用的磨损而在填充过程中发生的损失，可能抑制反应期间的聚合物形成和碳沉积，并且可以提供 转化率高，选择性好。