Process for the removal of the catalyst from polyphenylene ethers

    公开(公告)号:DE3222289A1

    公开(公告)日:1983-12-22

    申请号:DE3222289

    申请日:1982-06-14

    Applicant: BASF AG

    Abstract: The invention relates to a process for the removal of the catalyst in the preparation of high-molecular-weight polyphenylene ethers from monohydric phenols by oxidative coupling reaction with oxygen at temperatures between 15 and 50 DEG C in the presence of a catalyst complex comprising a metal salt and an organic amine in the presence of a solvent, and removal of the metal ion component of the catalyst from the polyphenylene ether solution by means of complexing or chelate complexing compounds in aqueous medium, the complexing and removal of the metal ion component of the catalyst being carried out in the presence of from 0.1 to 5000 mg/kg of high-molecular-weight, at least partially water-soluble polymers of (meth)acrylic acid and/or of (meth)acrylamide.

    ELECTROPHOTOGRAPHIC RECORDING MATERIAL

    公开(公告)号:DE3266612D1

    公开(公告)日:1985-11-07

    申请号:DE3266612

    申请日:1982-03-12

    Applicant: BASF AG

    Abstract: An electrophotographic recording medium which consists essentially of an electrically conductive base and a photosemiconductive double layer which comprises a first layer containing charge carrier-producing dyes, and a second layer containing one or more compounds which are charge carrier-transporting when exposed to light, wherein the charge carrier-producing dyes are those of the general formula I I where R1, R2, R3 and R4 are each hydrogen or a non-ionic substituent, X and Y are each the radical of a methylene-active compound, or of an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic amine or hydrazine, and Z is hydrogen, methyl or phenyl, and the production of this recording medium.

    PROCESS FOR THE PREPARATION OF POLYAMIDES

    公开(公告)号:DE2860225D1

    公开(公告)日:1980-12-04

    申请号:DE2860225

    申请日:1978-06-14

    Applicant: BASF AG

    Abstract: A process for the manufacture of nylons by heating an aqueous solution of a salt of an alkanedicarboxylic acid of 6 to 12 carbon atoms and a diamine of the formula NH2RNH2, where R is alkylene of 6 to 12 carbon atoms or is a radical to a temperature at which a nylon is formed, under superatmospheric pressure and with removal of water. The solution used is an aqueous solution of from 75 to 90 percent strength by weight of a salt of a dicarboxylic acid and a diamine, which solution has been obtained by neutralizing a less concentrated salt solution, which contains an appropriate dissolved excess of the particular dicarboxylic acid, with the corresponding diamine. The nylons obtained are used for the manufacture of moldings.

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