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公开(公告)号:DE19503546A1
公开(公告)日:1996-08-08
申请号:DE19503546
申请日:1995-02-03
Applicant: BASF AG
Inventor: DENZINGER WALTER , KISTENMACHER AXEL DR , PERNER JOHANNES DR , FUNHOFF ANGELIKA DR , POTTHOFF-KARL BIRGIT DR , RAUBENHEIMER HANS-JUERGEN
IPC: C08F2/44 , C02F5/10 , C08F265/00 , C08F267/00 , C08F267/04 , C09K23/52 , C11D3/37 , C11D7/26 , B01F17/52
Abstract: Water-soluble or dispersible graft polymers (A) are prepd. by radical initiated polymerisation of 100 pts. wt. of at least one monoethylenically unsatd. monomer (I) onto 5-2000 pts. wt. polymers (II) of monoethylenically unsatd. dicarboxylic acid or their anhydrides with a mol mass of 200-5000. The prepn. of (A) by the above method is also claimed.
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公开(公告)号:DE19612768A1
公开(公告)日:1997-10-02
申请号:DE19612768
申请日:1996-03-29
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , KISTENMACHER AXEL DR , SCHORNICK GUNNAR DR , WEICKENMEIER MEIK , WENZ GERHARD PROF DR
IPC: A61K47/40 , A61K8/73 , A61Q19/00 , C08B37/16 , C11D3/22 , C11D3/37 , D06M15/03 , A01N35/02 , A61K7/48 , A61K31/70 , D06M15/21
Abstract: The invention concerns polymers which contain cyclodextrin groups and are obtained by: (a) deprotonation of cyclodextrins or modified cyclodextrins with bases, with the exclusion of water; and (b) reaction of the deprotonated cyclodextrins or cyclodextrin derivatives obtained in (a) with polymers containing reactive groups in the absence of water. The invention further concerns a process for preparing the polymers containing cyclodextrin groups and the use of the polymers containing cyclodextrin groups as gel-forming agents and thickeners for the molecular encapsulation of active substances in the field of pharmacy, cosmetics and plant protection, as well as detergent additives, softener additives and as textile and laundry after-treatment agents.
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公开(公告)号:DE4405621A1
公开(公告)日:1995-08-24
申请号:DE4405621
申请日:1994-02-22
Applicant: BASF AG
Inventor: BOECKH DIETER DR , KISTENMACHER AXEL DR , DENZINGER WALTER , RAU IRIS DR , FUNHOFF ANGELIKA DR , BAUR RICHARD DR , SCHWENDEMANN VOLKER DR , KUD ALEXANDER DR
IPC: C08F2/00 , C08F2/16 , C08F2/38 , C08F2/44 , C08F4/40 , C08F8/12 , C08F218/04 , C08F218/08 , C08F218/10 , C08F220/04 , C08F220/06 , C08F222/02 , C11D3/37
Abstract: The invention relates to a process for preparing copolymers from vinyl esters and monoethylenically unsaturated carboxylic acids by the radical copolymerisation of: (a) 20 to 80 mol % vinyl esters of aliphatic monocarboxylic acids having at least two carbon atoms, (b) 80 to 20 mol % monoethylenically unsaturated carboxylic acids and, optionally, (c) 0 to 30 mol % of other monoethylenically unsaturated monomers which can be copolymerised, and/or (d) 0 to 10 mol % monomers containing at least two ethylenically unsaturated non-conjugated double bonds in the molecule, in the presence of at least one sulphur, phosphorus and/or nitrogen compound having a reducing effect and of 0.05 to 30 wt %, relative to the monomers, of at least one surfactant in an aqueous medium and in the presence of initiators and, optionally, regulators. The invention further relates to the use of the copolymers or the copolymers comprising vinyl alcohol units obtained therefrom by hydrolysis and/or oxidation, as additives for washing and cleaning agents.
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公开(公告)号:DE19508655A1
公开(公告)日:1996-09-19
申请号:DE19508655
申请日:1995-03-13
Applicant: BASF AG
Inventor: DANISCH PETER , DIX JOHANNES PETER DR , DENZINGER WALTER , KISTENMACHER AXEL DR , KNEIP MICHAEL DR , MUELLER HANS-JOACHIM DR , ROESCH JOACHIM DR , SCHORNICK GUNNAR DR
IPC: C08F210/14 , C08F222/00 , C08F255/02 , C08F290/04 , C09B67/46 , C09D17/00 , C09K23/52 , C14C9/00 , C08F210/00 , B01F17/52 , C14C11/00
Abstract: The invention provides aqueous solutions or dispersions of copolymers obtained by copolymerising (a) 20 to 95 mol.% of at least one monoethylenically unsaturated C4-C12 dicarboxylic acid or its anhydride; (b) 5 to 80 mol.% of at least one branched chain oligomer or polymer with a vinyl, vinylidene or alkylvinylene end group made up of at least 9 C atoms; and (c) 0 to 50 mol.% of at least another monoethylenically unsaturated compound capable of being polymerised with monomers (a) and (b). These aqueous solutions or dispersions contain 0.5 to 70 % by weight of these copolymers in relation to their total weight. They are useful as leather auxiliary and pigment dispersing agents.
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公开(公告)号:DE4416877A1
公开(公告)日:1995-11-16
申请号:DE4416877
申请日:1994-05-13
Applicant: BASF AG
Inventor: DENZINGER WALTER , KISTENMACHER AXEL DR , HARTMANN HEINRICH DR , BERNHARDT GUENTER , WOLF GERHARD DR
IPC: C08F289/00 , C14C3/22 , C08H1/00
Abstract: The use of water-soluble or water-dispersible graft polymers of proteins obtainable by the radically initiated polymerisation of: (A) a monomer or a monomer mixture of (a) 20 to 100 wt % acrylic acid or methacrylic acid or a mixture thereof or their alkaline metal, alkaline earth or ammonium salts, (b) 0 to 80 wt % other monoethylenically insaturated monomers which can be copolymerised with monomers (a), and (c) 0 to 50 wt % of at least two ethylenically unsaturated monomers having no conjugated double bonds in the molecule, in the presence of proteins (B) in the proportion by weight of A : B of (95 to 10) : (5 to 90), as tanning agents for the sole tanning, pre-tanning and co-tanning of smoothed hides and for the post-tanning of leather and hides.
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公开(公告)号:DE19612986A1
公开(公告)日:1997-10-02
申请号:DE19612986
申请日:1996-04-01
Applicant: BASF AG
Inventor: KNEIP MICHAEL DR , KISTENMACHER AXEL DR , DANISCH PETER , WOLF GERHARD DR
Abstract: The invention concerns the use of aqueous solutions or dispersions of copolymers which are obtained by the radical copolymerization of: (a) between 20 and 90 wt % of at least one monoethylenically unsaturated C4-C6 dicarboxylic acid or its anhydride as component A; (b) between 5 and 50 wt % of at least one C2-C6 olefin as component B; (c) between 5 and 50 wt % of at least one hydrophobic comonomer selected from the group comprising the long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, amides of long-chain amides with acrylic acid or methacrylic acid and the long-chain alkylvinyl ethers as component C; and (d) between 0 and 40 wt % of further comonomers which can be copolymerized with the above monomers as component D; the total of the amounts of components A, B, C and optionally D being 100 wt %. This copolymerization process is followed by at least partial esterification or hydrolysis and neutralizing and/or reaction with bases of the carboxyl groups which occur during hydrolysis. These solutions or dispersions are used for treating leather and/or furs.
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公开(公告)号:DE19606394A1
公开(公告)日:1997-08-28
申请号:DE19606394
申请日:1996-02-21
Applicant: BASF AG
Inventor: HUMMERICH RAINER DR , KISTENMACHER AXEL DR , DENZINGER WALTER , SCHORNICK GUNNAR DR , RECK BERND DR , WEBER MANFRED
IPC: D06N7/06 , C08F8/30 , C08K5/17 , C08K7/04 , C08L33/02 , C08L35/00 , D04H1/42 , D04H1/58 , D04H1/64 , D06M13/02 , D06M13/325 , D06M15/263 , D06N3/04 , C08K3/32 , E04D5/06 , E04B1/74 , E04F15/16
Abstract: Formaldehyde-free aqueous binders containing: A) a polymer consisting of 5 to 100 wt% of an ethylenically unsaturated acid anhydride or an ethylenically unsaturated bicarboxylic acid, the carboxylic acid groups of which can form an anhydride group, and B) an alkanol amine with at least two hydroxyl groups.
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公开(公告)号:DE19606392A1
公开(公告)日:1997-08-28
申请号:DE19606392
申请日:1996-02-21
Applicant: BASF AG
Inventor: RECK BERND DR , WISTUBA ECKEHARDT DR , BECKERLE WILHELM FRIEDRICH , KISTENMACHER AXEL DR , RUPANER ROBERT DR , HUMMERICH RAINER DR
IPC: B05D7/24 , B05D1/00 , C08F8/30 , C08J7/04 , C08K5/17 , C08L23/26 , C08L35/00 , C08L57/00 , C08L57/10 , C09D135/00 , C09D145/00 , C09D151/00 , C08J7/06 , E04B1/82
Abstract: Disclosed is the use of a formaldehyde-free aqueous binder as a coating material for mouldings, containing: A) a polymer obtained by radical polymerisation consisting to the extent of 5 to 100 wt% of an ethylenically unsaturated acid anhydride or bicarboxylic acid, the carboxylic acid groups of which can form an anhydride group, and B) an alkanol amine with at least two hydroxyl groups.
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公开(公告)号:DE19534847A1
公开(公告)日:1997-03-27
申请号:DE19534847
申请日:1995-09-20
Applicant: BASF AG
Inventor: BAUR RICHARD DR , GREIF NORBERT DR , KISTENMACHER AXEL DR , OPPENLAENDER KNUT DR
Abstract: The invention concerns the use of polycarboxylic acid half-amides obtained by reacting (a) polymers containing anhydride groups and having an average molecular mass Mw of between 200 and 100 000, and (b) aminocarboxylic acids comprising a primary or secondary amino group, taurine, C1-C18 alkyltaurines and/or aminophosphonic acid, as an encrustation-inhibiting additive to phosphate-free and phosphate-reduced washing and cleaning agents.
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公开(公告)号:DE19503116A1
公开(公告)日:1996-08-08
申请号:DE19503116
申请日:1995-02-01
Applicant: BASF AG
Inventor: POTTHOFF-KARL BIRGIT DR , DENZINGER WALTER , KISTENMACHER AXEL DR , GUEMBEL HELMUT DR
IPC: C08F251/00 , C11D3/37
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