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公开(公告)号:AU6986996A
公开(公告)日:1997-04-01
申请号:AU6986996
申请日:1996-09-04
Applicant: BASF AG
Inventor: SCHULZ MICHAEL , TELES JOAQUIM HENRIQUE , SUNDERMEYER JORG , WAHL GUNTER
IPC: B01J31/16 , B01J31/18 , B01J31/22 , C07B61/00 , C07D301/06 , C07D301/12 , C07D303/04
Abstract: PCT No. PCT/EP96/03888 Sec. 371 Date Mar. 11, 1998 Sec. 102(e) Date Mar. 11, 1998 PCT Filed Sep. 4, 1996 PCT Pub. No. WO97/10054 PCT Pub. Date Mar. 20, 1997Olefins can be epoxidized using catalysts I where M is a metal of the 4th to 7th transition group of the Periodic Table of the Elements, L1 is an amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligand of the formula II, III, VII or VIII, L2 is a customary auxiliary ligand or a further ligand L1 or a free coordination site, X is oxo oxygen or an imido ligand, m is 1 or 2, and n is 1, 2 or 3.
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公开(公告)号:CA2210696A1
公开(公告)日:1996-08-29
申请号:CA2210696
申请日:1996-02-10
Applicant: BASF AG
Inventor: SCHNURR WERNER , SCHULZ MICHAEL , TELES JOAQUIM HENRIQUE , RIEBER NORBERT , FISCHER ROLF
IPC: C07C45/41 , C07D301/14 , C07D303/04
Abstract: PCT No. PCT/EP96/00578 Sec. 371 Date Aug. 5, 1997 Sec. 102(e) Date Aug. 5, 1997 PCT Filed Feb. 10, 1996 PCT Pub. No. WO96/26198 PCT Pub. Date Aug. 29, 1996Preparation of epoxides from olefins by means of aromatic peroxycarboxylic acids comprises a step A of epoxidizing the olefin and removing the resulting aromatic carboxylic acid from the epoxide, a step B of catalytically hydrogenating the removed aromatic carboxylic acid to the corresponding aromatic aldehyde, and a step C of oxidizing this aldehyde with oxygen or an oxygen-containing gas mixture back to the aromatic peroxycarboxylic acid for re-use for epoxidizing an olefin.
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公开(公告)号:NO327885B1
公开(公告)日:2009-10-12
申请号:NO20020349
申请日:2002-01-23
Applicant: BASF AG
Inventor: AUER HEINZ , DAHLHAUS JUERGEN , FISCHER KARL , HAMMER HANS , KELLENBENZ JOCHEN , SCHULZ MICHAEL , THIEL JOACHIM , VICARI MAXIMILIAN
IPC: B01D3/00 , B01J3/00 , C07C67/36 , B01J3/02 , B01J19/00 , C07B61/00 , C07C29/80 , C07C31/04 , C07C69/06
Abstract: A description is given of a process for preparing methyl formate by reacting excess methanol with carbon monoxide under superatmospheric pressure and at elevated temperature in the presence of alkali metal methoxide or alkaline earth metal methoxide as catalyst in a pressure-rated reactor, in which the use of at least two reactor elements, preferably operated in countercurrent, at about 100° C. and a pressure of about 100 bar in combination with a solids-free desalting of the reaction product makes possible very economical, largely trouble-free production of methyl formate in any desired quality and with a very good production capacity. Furthermore, the process for solids-free desalting and apparatuses for carrying out this process are described.
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公开(公告)号:DE102004058887A1
公开(公告)日:2006-06-08
申请号:DE102004058887
申请日:2004-12-06
Applicant: BASF AG
Inventor: GRAFMANS HORST , MAAS STEFFEN , WECK ALEXANDER , RUETTER HEINZ , SCHULZ MICHAEL , ROS KARL-HEINZ
IPC: C07C231/02 , C07C233/05
Abstract: A process for preparing N,N-dimethylacetamide (DMAC) by continuously reacting methyl acetate (MeOAc) with dimethylamine (DMA) in the presence of a basic catalyst, wherein MeOAc is used in the form of a methanolic solution and in the range from 0.0002 to 0.09 mol of catalyst per mole of MeOAc, and performing the reaction at a temperature in the range from 90 to 140° C. and at an absolute pressure in the range from 10 to 30 bar.
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公开(公告)号:ZA200306099B
公开(公告)日:2004-09-28
申请号:ZA200306099
申请日:2003-08-07
Applicant: BASF AG
Inventor: BASSET JEAN-MARIE , HOEHN ARTHUR , SCHULZ MICHAEL , SCHWAB EKKEHARD , TAOUFIK MOSTAPHA , THIVOLLE-CAZAT JEAN , VANOPPEN DOMINIC
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公开(公告)号:NO20033029L
公开(公告)日:2003-07-02
申请号:NO20033029
申请日:2003-07-02
Applicant: BASF AG
Inventor: VANOPPEN DOMINIC , SCHWAB EKKEHARD , BASSET JEAN-MARIE , THIVOLLE-CAZAT JEAN , TAOUFIK MOSTAPHA , SCHULZ MICHAEL , HOEHN ARTHUR
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公开(公告)号:DE59902990D1
公开(公告)日:2002-11-14
申请号:DE59902990
申请日:1999-02-10
Applicant: BASF AG
Inventor: SCHWAB PETER , BREITSCHEIDEL BORIS , OOST CARSTEN , SCHULZ RALF , SCHULZ MICHAEL
IPC: B01J23/36 , B01J23/46 , C07B61/00 , C07C2/10 , C07C4/10 , C07C6/04 , C07C11/06 , C07C11/08 , C08F2/00
Abstract: Preparation of propene and optionally 1-butene comprises converting butene isomers to propene isomers using metathesis catalyst and converting formed 2-pentene to propene and 1-butene, isolating and recycling the 2-butene fraction. Preparation of propene and optionally 1-butene comprises: (a) converting 1-butene and 2-butene in the presence of a metathesis catalyst containing group VIb, VIIb or VIII metals; (b) removing propene and 2-pentene formed; (c) converting the 2-pentene using ethene to propene and 1-butene in the presence of the metathesis catalyst in (a); (d) removing propene and 1-butene formed; and (e) discharging the 1-butene and partially isomerizing 1-butene to 2-butene in the presence of a catalyst and recycling the 1-butene and 2-butene with a part of the unreacted 4C-fraction from (a) to (a). An Independent claim is also included for the apparatus for carrying out the preparation of propene and 1-butene comprising a metathesis reactor (R01) connected to a distillation column (K101) for removing 2/3C low boiling, 4C middle boiling and 5C+ high boiling phases; column (K301) for removing ethene and propene; and reactor (R02) for reacting 2-pentene with ethene.
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公开(公告)号:DE59901942D1
公开(公告)日:2002-08-08
申请号:DE59901942
申请日:1999-04-01
Applicant: BASF AG
Inventor: QUEISSER JOACHIM , SLANY MICHAEL , SCHAEFER ANSGAR , SCHULZ MICHAEL
IPC: B01J31/24 , C07F9/50 , C07F9/6568 , C07F15/00 , C08G67/02 , C08L73/00 , C09D173/00 , D01F6/76 , D02G3/00
Abstract: Disclosed is a cis-bridged metal complex of the formula (I)where R5 is an electron-withdrawing radical, and catalyst systems based on these complexes for copolymerizing carbon monoxide and olefinically unsaturated compounds.
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公开(公告)号:DE59901120D1
公开(公告)日:2002-05-08
申请号:DE59901120
申请日:1999-05-03
Applicant: BASF AG
Inventor: SCHWAB PETER , SCHULZ MICHAEL , WOLF JUSTIN , STUER WOLFRAM , WERNER HELMUT
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公开(公告)号:DE59802654D1
公开(公告)日:2002-02-21
申请号:DE59802654
申请日:1998-08-20
Applicant: BASF AG
Inventor: SCHWAB PETER , SCHULZ MICHAEL , WOLF JUSTIN , STUER WOLFRAM , WERNER HELMUT
Abstract: Ruthenium complexes of the formula I or IVwhereX, Y are anionic ligands,R is hydrogen or a substituted or unsubstituted C1-C20-alkyl radical or C6-C20-aryl radical andL1 and L2 are, independently of one another, uncharged electron donor ligands, are prepared by(a) reaction of RuX3 with L1 and L2 in an inert solvent in the presence of a reducing agent and hydrogen and(b) reaction with compounds of the formula IIwhere R is as defined above, in the presence or absence of water, and, if desired after isolation of the intermediate, with HY, [HL1]Y or [HL2]Y.
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