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    103.
    发明专利
    未知

    公开(公告)号：AT183527T

    公开(公告)日：1999-09-15

    申请号：AT95912244

    申请日：1995-03-11

    Applicant: BASF AG

    Inventor： HARTMANN HEINRICH ,  DENZINGER WALTER ,  NILZ CLAUDIA

    IPC: C05G3/00 ,  C08F263/00 ,  C08F265/00 ,  C08F271/00 ,  C09B67/00 ,  C09B67/46 ,  C09D17/00 ,  C09K17/20 ,  C09K23/00 ,  C09K23/52 ,  C11D3/37 ,  D21H17/34 ,  B01F17/00

    Abstract: PCT No. PCT/EP95/00912 Sec. 371 Date Oct. 24, 1996 Sec. 102(e) Date Oct. 24, 1996 PCT Filed Mar. 3, 1995 PCT Pub. No. WO95/25759 PCT Pub. Date Sep. 28, 1995Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae (I) (II) where R1 and R2 are each H or C1-C6-alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25 DEG C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.

    104.
    发明专利
    未知

    公开(公告)号：ES2123954T3

    公开(公告)日：1999-01-16

    申请号：ES95906950

    申请日：1995-01-16

    Applicant: BASF AG

    Inventor： BIRKHOFER HERMANN ,  KNEIP MICHAEL ,  DANISCH PETER ,  DENZINGER WALTER ,  KISTENMACHER AXEL ,  HARTMANN HEINRICH

    IPC: C08F220/18 ,  C14C9/00 ,  C08F222/06 ,  C08J3/03 ,  C09K23/22 ,  C09K23/42 ,  C14C9/02

    Abstract: PCT No. PCT/EP95/00144 Sec. 371 Date Jul. 25, 1996 Sec. 102(e) Date Jul. 25, 1996 PCT Filed Jan. 16, 1995 PCT Pub. No. WO95/20056 PCT Pub. Date Jul. 27, 1995Aqueous solution or aqueous dispersion of copolymers suitable for the fatliquoring and filling of leather and fur skins are obtained by free-radical copolymerization of A1) C6-C40-monoolefins or C6-C40-alkyl vinyl ethers or mixtures thereof with B1) monoethylenically unsaturated C4-C8-dicarboxylic anhydrides or by free-radical copolymerization of A2) C6-C40-alkyl acrylates or methacrylates or vinyl esters of C6-C40-carboxylic acids or mixtures thereof with B2) monoethylenically unsaturated C3-C12-carboxylic acids, monoethylenically unsaturated C4-C12-dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C4-C12-dicarboxylic acids, amides of monoethylenically unsaturated C3-C12-carboxylic acids or mixtures thereof to give copolymers with molecular weights of 500 to 30,000, where the carboxyl groups which are present in aqueous medium are at least partially neutralized, and some of the carboxylic groups can be in amidated form, containing 0.5-40% by weight, based on the amount of copolymer, of defined emulsifiers.

    105.
    发明专利
    未知

    公开(公告)号：DE59504442D1

    公开(公告)日：1999-01-14

    申请号：DE59504442

    申请日：1995-09-23

    Applicant: BASF AG

    Inventor： RUEBENACKER MARTIN ,  SCHNEIDER REINHARD ,  NIEBERLE JUERGEN ,  HARTMANN HEINRICH ,  DENZINGER WALTER ,  KISTENMACHER AXEL

    IPC: C08F2/32 ,  C08F6/18 ,  C08F6/22 ,  C08F220/04

    Abstract: Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers containing ammonium carboxylate groups are prepared by azeotropic removal of water from water-in-oil emulsions of the water-soluble or water-swellable polymers which contain ammonium carboxylate groups in the presence of from 0:1 to 40% by weight, based on the polymers, of polyalkylene glycols which have an agglomerating effect and which are obtainable by an addition reaction of C2-C4-alkylene-oxides with alcohols, phenols, amines or carboxylic acids and contain at least two polymerized alkylene oxide units and additionally of from 0.1 to 20% by weight, based on the polymers, of protective colloids which are obtainable by free radical copolymerization of C8-C40-monoolefins with monoethylenically unsaturated C4-C6-dicarboxylic anhydrides by a mass polymerization method at from 80 to 300° C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, and said agglomerated polymer particles are used as thickeners for textile pigment print pastes.

    109.
    发明专利
    未知

    公开(公告)号：DE59308127D1

    公开(公告)日：1998-03-12

    申请号：DE59308127

    申请日：1993-11-11

    Applicant: BASF AG

    Inventor： PERNER JOHANNES ,  DIESSEL PAUL ,  GUEMBEL HELMUT ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  KRONER MATTHIAS

    IPC: C02F5/10 ,  C08L33/02 ,  C08L35/00 ,  H04L27/20 ,  C08L51/02 ,  C08L77/04 ,  C11D3/37 ,  H04B7/00 ,  H04J3/16 ,  H04J3/22 ,  H04J3/24 ,  H04J11/00 ,  H04J13/00 ,  H04J13/18 ,  H04L20060101 ,  H04L1/00 ,  H04L1/08 ,  H04L12/00 ,  H04L27/30 ,  H04L29/06 ,  H04Q7/38

    Abstract: PCT No. PCT/EP93/03159 Sec. 371 Date May 22, 1995 Sec. 102(e) Date May 22, 1995 PCT Filed Nov. 11, 1993 PCT Pub. No. WO94/12571 PCT Pub. Date Jun. 9, 1994Mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and (II) (1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising (a) from 10 to 70% by weight of monoethylenically unsaturated C4-C8-dicarboxylic acids or the salts thereof and (b) from 30 to 90% by weight of monoethylenically unsaturated C3-C10-monocarboxylic acids and/or the salts thereof, (2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of (A) monoethylenically unsaturated C3-C10-carboxylic acids or the anhydrides and/or the salts thereof in the presence of (B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or (3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groups contain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.5 : 10 and are used as additives for phosphate-free or low-phosphate textile detergents or as dispersants or coating inhibitors in cleaners for hard surfaces.

    110.
    发明专利
    未知

    公开(公告)号：ES2108575T3

    公开(公告)日：1997-12-16

    申请号：ES95911239

    申请日：1995-02-17

    Applicant: BASF AG

    Inventor： BOECKH DIETER ,  KISTENMACHER AXEL ,  DENZINGER WALTER ,  RAU IRIS ,  FUNHOFF ANGELIKA ,  BAUR RICHARD

    IPC: C08F2/00 ,  C08F2/16 ,  C08F2/38 ,  C08F2/44 ,  C08F4/40 ,  C08F8/12 ,  C08F218/04 ,  C08F218/08 ,  C08F218/10 ,  C08F220/04 ,  C08F220/06 ,  C08F222/02 ,  C11D3/37

    Abstract: PCT No. PCT/EP95/00575 Sec. 371 Date Aug. 21, 1996 Sec. 102(e) Date Aug. 21, 1996 PCT Filed Feb. 17, 1995 PCT Pub. No. WO95/22569 PCT Pub. Date Aug. 24, 1995A process for preparing copolymers of vinyl esters and monoethylenically unsaturated carboxylic acids by free-radical copolymerization of (a) 20 to 80 mol % of vinyl esters of aliphatic monocarboxylic acids having at least 2 carbon atoms and (b) 80-20 mol % of monoethylenically unsaturated carboxylic acids, with or without (c) 0-30 mol % of other copolymerizable monoethylenically unsaturated monomers and/or (d) 0-10 mol % of monomers which contain at least two non-conjugated ethylenic double bonds in the molecule, in the presence of at least one sulfur, phosphorus and/or nitrogen compound with a reducing action and of 0.05-30% by weight, based on the monomers, of at least one surface-active agent in aqueous medium in the presence of initiators and in the presence or absence of regulators, and the use of the copolymers or of the copolymers which are obtainable therefrom by hydrolysis and/or oxidation and have vinyl alcohol units as additive to detergents and cleaners.

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