121.
    发明专利
    未知

    公开(公告)号:FI964647A

    公开(公告)日:1997-01-22

    申请号:FI964647

    申请日:1996-11-21

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/01818 Sec. 371 Date Nov. 21, 1996 Sec. 102(e) Date Nov. 21, 1996 PCT Filed May 13, 1995 PCT Pub. No. WO95/32227 PCT Pub. Date Nov. 30, 1995A process for the preparation of a stable water-in-oil emulsion of a hydrolyzed polymer of an N-vinyl amide of the formula (I) in which R and R1 denote H or C1-C6 alkyl, by the polymerization of a compound of the formula I alone or in admixture with another ethylenically unsaturated monomer in the presence of a polymerization initiator and emulsifier in the form of a water-in-oil emulsion, to form a water-in-oil polymeric emulsion, followed by hydrolysis of the polymer in the form of the water-in-oil polymeric emulsion in the presence of an acid or base and from 1 to 30 wt %, based on the polymer, of an emulsifier, the emulsifier used being a mixture of (a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B)m, (A)-B or (B)-A, in which in each case (a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B)m, (A)nB or (B)nA, in which in each case A is a hydrophobic homopolymer or copolymer having a degree of polymerization of at least 3, B is a hydrophilic homopolymer or copolymer having a degree of polymerization of at least 3, m is equal to or greater than 1, and n is equal to or greater than 2, and (b) from 5 to 95 wt % of another water-in-oil emulsifier having a molar mass below 1000 g/mol.

    124.
    发明专利
    未知

    公开(公告)号:FI963807A0

    公开(公告)日:1996-09-24

    申请号:FI963807

    申请日:1996-09-24

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00907 Sec. 371 Date Dec. 2, 1996 Sec. 102(e) Date Dec. 2, 1996 PCT Filed Mar. 11, 1995 PCT Pub. No. WO95/25756 PCT Pub. Date Sep. 28, 1995Modified copolymers which are suitable as paraffin dispersants and are obtainable by reacting a copolymer of an ethylenically unsaturated dicarboxylic acid and/or a dicarboxylic acid derivative and a diketene of the general formula I I where R1 and R2, independently of one another, are each hydrogen or C1-C30-alkyl, with an amine of the general formula II II where m may be from 0 to 100, n from 0 to 5 and x from 0 to 5, R3, R4 and R5, independently of one another, are each hydrogen or C1-C5-alkyl and A is NR6R7 or C2-C30-alkoxy, and at least one of the substituents R6 or R7 is not hydrogen and is C1-C30-alkyl or alkenyl or a polyether radical where R8 and R9 are each hydrogen or C1-C5-alkyl and p is from 1 to 100, with the proviso that, when n is 0, A is NR6R7, their preparation and use, and mineral oil middle distillates which contain these modified copolymers.

    125.
    发明专利
    未知

    公开(公告)号:FI963778A0

    公开(公告)日:1996-09-23

    申请号:FI963778

    申请日:1996-09-23

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP95/00912 Sec. 371 Date Oct. 24, 1996 Sec. 102(e) Date Oct. 24, 1996 PCT Filed Mar. 3, 1995 PCT Pub. No. WO95/25759 PCT Pub. Date Sep. 28, 1995Graft polymers which contain N-vinyl units and in which the grafting base is a polymer which contains in each case at least 5% by weight of units of the formulae (I) (II) where R1 and R2 are each H or C1-C6-alkyl, monoethylenically unsaturated monomers are grafted onto the grafting base in a weight ratio of from 100:1 to 1:100, and which have K values of at least 7 (determined according to H. Fikentscher in 5% strength by weight aqueous solution at 25 DEG C. and pH 7), are prepared by polymerization of monoethylenically unsaturated monomers in the presence of polymers which in each case contain at least 5% by weight of units of the formulae I and/or II as the grafting base in a weight ratio of from 100:1 to 1:100, and are used as dispersants for pigments, as additives for detergents and cleaning agents, and strength agents for paper and as soil stabilizers and for fertilizer compaction.

    126.
    发明专利
    未知

    公开(公告)号:AT140637T

    公开(公告)日:1996-08-15

    申请号:AT94904174

    申请日:1993-12-22

    Applicant: BASF AG

    Abstract: The invention concerns the use, as dispersants for aqueous pigment suspensions, of partially esterified copolymers obtained by the copolymerization of (a) at least one C4 to C28 olefin and (b) ethylenically unsaturated dicarboxylic acid anhydrides with 4 to 8 C-Atoms in the molar ratio of 1:0.5 to 1:2 and the subsequent partial esterification of the copolymer with reaction products of (A) C1 to C30 alcohols, C8 to C22 fatty acids, C1 to C12 alkylphenols or secondary C2 to C30 amines and (B) at least one C2 to C4 alkylene oxide or tetrahydrofuran in the molar ratio (A):(B) of 1:2 to 1:200, and hydrolysis of the anhydride groups in the copolymer to give carboxyl groups, the partial esterification of the copolymer being carried out to an extent such that 1 to 50 % of the carboxyl groups in the copolymer are esterified. The invention also concerns pigment suspensions containing such partially esterified copolymers.

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