公开(公告)号：DE102004003310A1

公开(公告)日：2005-08-11

申请号：DE102004003310

申请日：2004-01-22

Applicant: BASF AG

Inventor： BOSCH MARCO ,  BOTTKE NILS ,  BENFER REGINA ,  NARBESHUBER THOMAS

IPC: B01J29/18 ,  C07C2/66 ,  C07C15/107 ,  C07C303/06 ,  C07C309/31 ,  C07C2/58 ,  C07C6/04 ,  C07C7/12 ,  C07C309/30

Abstract: Producing slightly branched alkylaromatics by alkylating aromatics with olefins in the presence of an acid catalyst comprises reducing the hydroperoxide content of the olefin feed to less than 1 g per kg of catalyst per hour by treatment with an inorganic hydride. An independent claim is also included for producing alkylaryl sulfonates by contacting a C4 olefin mixture with a metathesis catalyst to produce an olefin mixture containing 2-pentene and/or 3-hexene; optionally separating the 2-pentene and/or 3-hexene; dimerizing the 2-pentene and/or 3-hexene, optionally together with C4 and/or C7 olefins, in the presence of a dimerization catalyst, to give a C8-C14 olefin mixture; optionally separating the C8-C14 olefins and separating 5-30 wt.% of low boilers; reducing the hydroperoxide content of the C8-C14 olefin mixture as above; optionally adding linear olefins in an amount of 0-60 wt.%; reacting the C8-C14 olefin mixture with aromatics in the presence of an acid catalyst to produce alkylaromatics; optionally adding linear alkylbenzenes in an amount of 0-60 wt.%; sulfonating the alkylaromatics and neutralizing the products to give alkylaryl sulfonates; and optionally mixing the alkylaryl sulfonates with 0-60 wt.% (words missing).

公开(公告)号：DE10350333A1

公开(公告)日：2005-05-25

申请号：DE10350333

申请日：2003-10-29

Applicant: BASF AG

Inventor： BOTTKE NILS ,  BENFER REGINA ,  BOSCH MARCO ,  NARBESHUBER THOMAS ,  STEINBRENNER ULRICH ,  STEPHAN JUERGEN

IPC: C07C2/66 ,  C11D1/22 ,  C07C15/107 ,  C07C2/00

Abstract: In a process for preparing alkylaryl compounds by reacting a C10-14-monoolefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds and if appropriate subsequently sulfonating and neutralizing the resulting alkylaryl compounds, in the C10-14-monoolefins, on average, more than 0% and up to 100% of methyl branches are present in the longest carbon chain and fewer than 50% of the methyl branches are in the 2-, 3- and 4-position, calculated starting from the chain ends of the longest carbon chain.

公开(公告)号：AU2003294692A8

公开(公告)日：2004-05-04

申请号：AU2003294692

申请日：2003-10-14

Applicant: BASF AG

Inventor： NARBESHUBER THOMAS ,  BOTTKE NILS ,  PRINZ MARTINA ,  STEPHAN JURGEN ,  STEINBRENNER ULRICH ,  BENFER REGINA ,  MAAS HEIKO ,  HEIDEMANN THOMAS ,  FUNKE FRANK ,  TROPSCH JURGEN

IPC: C07C29/17 ,  C07C303/06 ,  C07C303/08 ,  C07C309/31 ,  C07C9/16 ,  C07C15/107 ,  C07C31/125 ,  C11D1/24

公开(公告)号：CA2326888A1

公开(公告)日：1999-11-11

申请号：CA2326888

申请日：1999-04-22

Applicant: BASF AG

Inventor： PETERS JARREN ,  DOCKNER TONI ,  BENFER REGINA ,  BIRNBACH STEFAN ,  MOHR JURGEN ,  ZEHNER PETER ,  BIEG WALTER ,  WEINLE WERNER ,  RUGE BERND

IPC: C07D317/36 ,  C07D317/38

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2- ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first pa rt of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the seco nd part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout th e reactor.

公开(公告)号：DE19819586A1

公开(公告)日：1999-11-04

申请号：DE19819586

申请日：1998-04-30

Applicant: BASF AG

Inventor： BIRNBACH STEFAN ,  DOCKNER TONI ,  MOHR JUERGEN ,  BENFER REGINA ,  BIEG WALTER ,  PETERS JARREN ,  RUGE BERND ,  WEINLE WERNER ,  ZEHNER PETER

IPC: C07D317/36 ,  C07D317/38 ,  C07D317/44

Abstract: The invention relates to a method for continually producing 1,3-dioxolan-2-ones such as ethylene carbonate or propylene carbonate by reacting a corresponding oxirane with carbon dioxide in liquid phase in the presence of a catalyst. The reaction is carried out in a two-part reactor. In the first part of the reactor, the reaction is carried out with back-mixing until a conversion rate of oxirane II of at least 80 % has been reached. In the second part, the reaction is completed under conditions without back-mixing, the carbon dioxide being guided to the oxirane II in a counterflow throughout the reactor.

公开(公告)号：BRPI0415901B1

公开(公告)日：2016-01-26

申请号：BRPI0415901

申请日：2004-10-29

Applicant: BASF AG

Inventor： STEPHAN JÜRGEN ,  BOSCH MARCO ,  BOTTKE NILS ,  BENFER REGINA ,  NARBESHUBER THOMAS ,  STEINBRENNER ULRICH

IPC: C07C2/66 ,  C11D1/22

Abstract: "processo para preparar compostos, composto, uso do mesmo, e, agente de lavagem ou de limpeza". em um processo para preparar compostos de alquilarila mediante a reação de uma mistura de monoolefina c~ 10-14~ com um hidrocarboneto aromático, na presença de um catalisador de alquilação, para formar compostos aromáticos de alquila e, se apropriado, subseqüentemente sulfonando-se e neutralizando-se os compostos de alquilarila resultantes, nas monoolefinas c~ 10-14~, em média, mais do que 0% e até 100% de ramificações metila se acham presentes na cadeia de carbono mais longa, e menos do que 50% das ramificações metila se acham nas posições 2, 3 e 4, calculado partindo-se das extremidades de cadeia da cadeia de carbono mais longa.

公开(公告)号：EA009786B1

公开(公告)日：2008-04-28

申请号：EA200601233

申请日：2004-12-30

Applicant: BASF AG

Inventor： JOHANN THORSTEN ,  SCHINDLER GOTZ-PETER ,  BRODHAGEN ANDREAS ,  CRONE SVEN ,  BENFER REGINA ,  HILL THOMAS ,  DUDA MARK

IPC: C07C5/333 ,  C07C5/48 ,  C07C11/167

Abstract: Изобретениеотноситсяк способуполучениябутадиенаизн-бутана, включающемутакиестадии: A) подготовкаисходногогазовогопотокаа, содержащегон-бутан; B) подачасодержащегон-бутангазовогопотокаа поменьшеймерев первуюзонудегидрированияи неокислительноекаталитическоедегидрированиен-бутанас получениемпотокагазообразныхпродуктов b, содержащегон-бутан, 1-бутен, 2-бутен, бутадиен, водород, низкокипящиепримесии, принеобходимости, водянойпар; C) подачапотокагазообразныхпродуктов b неокислительногокаталитическогодегидрированияи содержащегокислородгазапоменьшеймеревовторуюзонудегидрированияи окислительноедегидрирование 1-бутенаи 2-бутенас получениемпотокагазообразныхпродуктовс, содержащегон-бутан, 2-бутен, бутадиен, водород, низкокипящиепримесии водянойпар, приэтомв такомпотокегазообразныхпродуктовс содержаниебутадиенавыше, чемв потокегазообразныхпродуктов b; D) отделениеводорода, низкокипящихпримесейи водяногопарас получениемпотокаС-газообразныхпродуктов d, которыйв основномсостоитизн-бутана, 2-бутенаи бутадиена; E) разделениепотока C-газообразныхпродуктов d навозвратныйпотоке1, состоящий, восновном, изн-бутанаи 2-бутена, инапотоке2, состоящий, восновном, избутадиена, путемэкстрактивнойдистилляциии рециркуляциипотокае1 впервуюзонудегидрирования; F) вслучаенеобходимости, подачачастиколичестваиливсегопотокае2, состоящего, восновном, избутадиена, взонуселективногогидрированияи селективноегидрированиебутадиенадо 1- и/или 2-бутенас получениемпотока f, содержащего 1-бутени 2-бутена; G) вслучаенеобходимости, подачапотока f, содержащего 1-бутени 2-бутена, вдистилляционнуюзонуи

公开(公告)号：ZA200604943B

公开(公告)日：2007-12-27

申请号：ZA200604943

申请日：2006-06-15

Applicant: BASF AG

Inventor： BOTTKE NILS ,  TROPSCH JURGEN ,  NARBESHUBER THOMAS ,  STEPHAN JURGEN ,  ROPER MICHAEL ,  STEINBRENNER ULRICH ,  BENFER REGINA ,  HEIDEMANN THOMAS

IPC: C07C20090101 ,  C07C2/66 ,  C07C303/06 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).

公开(公告)号：DE102005053231A1

公开(公告)日：2007-05-10

申请号：DE102005053231

申请日：2005-11-06

Applicant: BASF AG

Inventor： NEUMANN DIRK ,  KOCH MICHAEL ,  SCHINDLER GOETZ-PETER ,  BENFER REGINA ,  KAIBEL GERD ,  WAGNER HANS-GUENTER ,  PAESLE PETER

IPC: C07C4/18 ,  B01J23/62 ,  C07C4/20 ,  C07C5/41 ,  C07C15/00

公开(公告)号：BRPI0417365A

公开(公告)日：2007-04-10

申请号：BRPI0417365

申请日：2004-12-17

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  HEIDEMANN THOMAS ,  ROEPER MICHAEL ,  STEPHAN JUERGEN ,  NARBESHUBER THOMAS ,  TROPSCH JUERGEN ,  BOTTKE NILS ,  BENFER REGINA

IPC: C07C303/00 ,  C07C2/66 ,  C07C303/06 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

Abstract: The preparation of alkylaryl compounds takes place by a) reaction of a C 4 /C 5 -olefin mixture over a metathesis catalyst to prepare a C 4-8 -olefin mixture comprising 2-pentene, and optional removal of the C 4-8 -olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C 4-8 -olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C 8-16 -olefins, removal of these C 8-16 -olefins and optional removal of a partial stream thereof, d) reaction of the c 8-16 -olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c 8-16 -olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).