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公开(公告)号:DE4344672C1
公开(公告)日:1995-06-14
申请号:DE4344672
申请日:1993-12-27
Applicant: BASF AG
Inventor: LUX MARTIN DR , SAIVE ROLAND DR , LANGHAUSER FRANZ DR , MICKLITZ WOLFGANG DR , GOERTZ HANS-HELMUT DR , LILGE DIETER DR
IPC: C08F2/06 , C08F2/14 , C08F4/606 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
Abstract: PCT No. PCT/EP94/04125 Sec. 371 Date Jun. 26, 1996 Sec. 102(e) Date Jun. 26, 1996 PCT Filed Dec. 13, 1994 PCT Pub. No. WO95/18160 PCT Pub. Date Jul. 6, 1995Homopolymers of ethylene or copolymers of ethylene with other olefins or mixtures thereof are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are those which contain, as active components, A) a finely divided carrier treated with trialkylaluminum, B) a metallocene complex, C) an open-chain or cyclic alumoxane compound and D) an alkali metal alkyl or alkaline earth metal alkyl or a mixture thereof.
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公开(公告)号:DE3867326D1
公开(公告)日:1992-02-13
申请号:DE3867326
申请日:1988-06-08
Applicant: BASF AG
Inventor: AUWETER HELMUT DR , HORN DIETER DR , LILGE DIETER DR , WORTMANN JUERGEN DR
Abstract: The optical fibre sensor measures the Doppler shift of dispersed laser light using a quasi-elastic light scattering principle, where the light is dispersed by incidence with moving particles. The exit face (7) for the laser light is provided at the end of a monomode or multi mode optical fibre (3) acting as an immersion probe, with an angle of between 0 and 15 degrees and pref between 1 and 6 degrees between the optical axis (8) of the optical fibre (3) and the normal (9) to the exit face (7). Pref. the dispersed light is fed back to the optical fibre (3) via the exit face (7) for coupling to a detector (12), pref. with an associated signal processing circuit.
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公开(公告)号:AT71226T
公开(公告)日:1992-01-15
申请号:AT88109082
申请日:1988-06-08
Applicant: BASF AG
Inventor: AUWETER HELMUT DR , HORN DIETER DR , LILGE DIETER DR , WORTMANN JUERGEN DR
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公开(公告)号:DE19726796A1
公开(公告)日:1999-01-07
申请号:DE19726796
申请日:1997-06-24
Applicant: BASF AG
Inventor: HUEFFER STEPHAN DR , ROESCH JOACHIM DR , LANGHAUSER FRANZ DR , LILGE DIETER DR , HINGMANN ROLAND DR
IPC: C08J5/18 , C08F4/02 , C08F4/646 , C08F6/04 , C08F10/00 , C08F10/06 , C08F210/16 , C08L23/10 , C08L23/12 , C08L23/14 , D01F6/06 , D01F6/30 , C08F210/06
Abstract: Propylene polymers (I) contain a matrix of propylene homopolymer and a copolymer of propylene and other alkenes. The novelty is that the polymers satisfy certain condition(s) when separated by tacticity and comonomer distribution of the polymer chain. They are first dissolved in boiling xylene, then the solution is cooled to 25 degrees C at a rate of 10 degrees C/hour. The polymers are separated, into fractions of different solubility at increasing temperature, whilst the matrix remains undissolved on heating the cooled solution to 80 degrees C. The conditions are that the amount of matrix remaining undissolved on further heating is (i) > 20 wt.% at 112 degrees C; (ii) > 8 wt.% at 117 degrees C and/or > 1 wt.% at 122 degrees C. Also claimed are (1) a method of producing (I); and (2) films, fibres or mouldings made from (I).
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公开(公告)号:DE19500811A1
公开(公告)日:1996-07-18
申请号:DE19500811
申请日:1995-01-13
Applicant: BASF AG
Inventor: WUENSCH JOSEF DR , FISCHER DAVID DR , LUX MARTIN DR , LILGE DIETER DR
Abstract: Polymers of vinylaromatic cpds. are prepd. at 0-150 deg C, in presence of a catalyst system comprising (A) at least 2 different metallocene complexes and (B) a cpd. forming metallocenium ions. Pref. the aromatic cpds. have formula (I) (where R = H (pref.) or 1-4C alkyl; R -R = H (pref.), 1-12C (1-4C) alkyl (pref.), or halogen (pref. Cl), or 2 adjacent gps. together form a 4-15C (4-12C) cyclic gp., or Ph, biphenyl, naphthalene or anthracene). The components are metallocene complexes formula (II) (where R -R = H, 1-10C alkyl, 5-7C cycloalkyl (opt. carrying 1-6C alkyl gps. as substits.), 6-15C aryl or arylalkyl, or 2 adjacent gps. form together 4-15C cyclic gps., or Si(R )3; R = 1-10C alkyl, 6-15C aryl or 3-10C cycloalkyl; M = metal or 3rd-6th sub-gps. or of the lanthanide series (pref. metal of 4th sub-gp.); Z -Z = H, halogen (Pref.), 1-10C alkyl (pref.), 1-10C alkoxy (pref.), 6-15C aryl or 1-15C aryloxy; z1-z5 = 0-5; z1+z2+z3+z4+z4+z5 = valency of (M - 1)). (B) The components are open-chain or cyclic alumoxan cpds. of formulae (R )(R )Al-(O-Al(R ))mR (III) or (IV) (where R = 1-4C alkyl; m = 5-30). The polymers are used to produce mouldings (claimed). Use is esp. in electrical and high temp. resistant applications. A simple process gives syndiotactic polymers with wide distribution of mol.wt. The polymers have mol.wt. 10000-10000000 (50000-1000000) and Mw/Mn of 5-100.
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公开(公告)号:DE4139261A1
公开(公告)日:1993-06-03
申请号:DE4139261
申请日:1991-11-29
Applicant: BASF AG
Inventor: RIEGER BERNHARD DR , LILGE DIETER DR , EVERTZ KASPAR DR , KONRAD RAINER DR
IPC: C08F4/622 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F210/02 , C08F210/16
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公开(公告)号:DE19723003A1
公开(公告)日:1998-12-03
申请号:DE19723003
申请日:1997-06-02
Applicant: BASF AG
Inventor: BAUER PETER , LUX MARTIN DR , LILGE DIETER DR
Abstract: The invention relates to polymer mixtures containing at least 85 wt pct ethylene/ alpha -olefin copolymers (A) produced by metallocene catalysis and 1 to 15 wt pct essentially linear ethylene/ alpha -olefin copolymers (B) produced with a different catalyst, in relation to the total mass of the polymer mixture.
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公开(公告)号:DE19533337A1
公开(公告)日:1997-03-13
申请号:DE19533337
申请日:1995-09-11
Applicant: BASF AG
Inventor: FISCHER DAVID DR , LANGHAUSER FRANZ DR , LILGE DIETER DR , HINGMANN ROLAND DR , SCHWEIER GUENTHER DR
IPC: C08J5/18 , B32B27/32 , C08F4/659 , C08F4/6592 , C08F210/06 , C08F210/08
Abstract: Propene/but-1-ene copolymers contain at least 80 % by moles propene units, have a melting point Tm below 145 DEG C and a molecular weight distribution lower than 2.5.
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公开(公告)号:DE4446385A1
公开(公告)日:1996-06-27
申请号:DE4446385
申请日:1994-12-23
Applicant: BASF AG
Inventor: WUENSCH JOSEF DR , FISCHER DAVID DR , LUX MARTIN DR , LILGE DIETER DR
Abstract: Polymers of vinylaromatic cpds. are prepd. at 0-150 deg C in presence of a catalyst system contg. as active components (A) at least 2 different metallocene complexes and (B) a cpd. forming metallocenium ions.
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