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公开(公告)号:DE10133788A1
公开(公告)日:2003-02-06
申请号:DE10133788
申请日:2001-07-16
Applicant: BASF AG
Inventor: WALCZUCH KARL-HEINZ , POLT AXEL , POPLOW FRANK , LUYKEN HERMANN , MECKL STEFAN , AUER HEINZ
Abstract: The invention relates to a method for the separation of ammonia from a mixture which contains ammonia and whose boiling point in an ammonia-free state is more than 50 DEG C higher than the boiling point of pure ammonia, characterized in that said method comprises n stages, n being a natural number of at least 2, wherein a) said mixture is fed to stage 1; b) at each stage m, m being a natural number of 1 to n-1, part of the ammonia is separated from the educt mixture fed from stage 1 at a pressure Pm by means of evaporation in order to obtain a product mixture which has an ammonia content corresponding to pressure Pm and temperature tm, and gaseous ammonia, c) the product mixture obtained in stage m is used in step m+1 as an educt mixture, with the exception of stage n, according to step b), d) in step n, the ammonia is separated at a pressure Pn and temperature tn either partially or fully from the educt mixture fed from stage n-1 by means of evaporation in order to obtain a product and gaseous ammonia, each pressure Pm being greater than Pm+1.
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公开(公告)号:CA2670935A1
公开(公告)日:2008-06-05
申请号:CA2670935
申请日:2007-11-29
Applicant: BASF AG
Inventor: SIGL MARCUS , HEIMANN FRANK , POPLOW FRANK , VOLLAND MARTIN , BITTERLICH STEFAN , PAPP RAINER , MACKEWITZ THOMAS , CRONE SVEN , HEIDEMANN THOMAS , UEBLER CHRISTOPH , PACIELLO ROCCO , WIEBELHAUS DAG
Abstract: The present invention relates to a method for the production of hydroform ylation products from olefins having at least four carbon atoms. A high amou nt of the linear Ci-olefins with terminal double bonds that are present in t he inlet comprising olefins, and also of the linear Ci-olefins having intern al double bonds are converted to hydroformylation products. The invention fu rther relates to a method for the production of 2-propylheptanol, comprising said hydroformylation method.
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13.
公开(公告)号:MX2007010286A
公开(公告)日:2008-04-10
申请号:MX2007010286
申请日:2006-02-24
Applicant: BASF AG
Inventor: SIGL MARCUS , STEPHAN JURGEN , SCHUBERT MARKUS , POPLOW FRANK
Abstract: La invencion se relaciona con un metodo para producir un flujo de producto que consiste sustancialmente de eteno (flujo de C2=), un flujo de producto que consiste substancialmente de propeno (flujo C3=), un flujo de producto que consiste substancialmente de isobuteno y, opcionalmente de otras olefinas que tiene 4 atomos de carbono (flujo C4=) y un flujo de producto que consiste substancialmente de 2-metil-2-buteno y, opcionalmente de 2-buteno (flujo C5=), y opcionalmente otro flujo de producto que contiene otros hidrocarburos (flujo Cx), que consiste opcionalmente de varios flujos parciales individuales. El metodo inventivo comprende un paso de metatesis que consiste en llevar un flujo de hidrocarburo de C4 que contiene cuando menos 15% en peso de 2-buteno, por lo menos 5% en peso de isobuteno y cuando menos 5% en peso de 1-buteno (flujo de alimentacion) a contacto con eteno en presencia de un catalizador de metatesis usual, el flujo de hidrocarburo asi formado se separa en los flujos C2=, C3=, C4=, y opcionalmente Cx y el flujo C5= se recicla parcial o totalmente en la etapa de metatesis.
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公开(公告)号:BRPI0413792A
公开(公告)日:2006-11-07
申请号:BRPI0413792
申请日:2004-09-24
Applicant: BASF AG
Inventor: REUTEMANN WERNER , WAMBSGANSS ROLF , POPLOW FRANK , WEBER THEODOR , ROSS KARL-HEINZ , JULIUS MANFRED
IPC: C07C209/16 , C07C211/04
Abstract: The invention relates to a process for preparing methylamines by gas-phase reaction of methanol and ammonia as starting materials at a pressure in the range from 15 to 30 bar in the presence of heterogeneous catalyst. The starting materials are vaporized in one or more heat exchangers (1, 2, 3), superheated to produce a feed gas stream and subsequently fed into a reactor (4), with the mixing of the starting materials being able to be carried out in the feed stream to one of the heat exchangers (1, 2, 3) or at any desired position in a heat exchanger (1, 2, 3). A product gas stream comprising monomethylamine, dimethylamine and trimethylamine and also reaction by-products is taken off from the reactor (4). To control the reactor inlet temperature of the starting materials to a temperature in the range from 360° C. to 370° C., all or some of the feed gas stream or the product gas stream is passed through an adjustable valve (5) in order to vary the pressure and thus the condensation temperature.
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公开(公告)号:DE102004009804A1
公开(公告)日:2005-09-15
申请号:DE102004009804
申请日:2004-02-28
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , HESSE MICHAEL , STEPHAN JUERGEN , BOEHM VOLKER , BRODHAGEN ANDREAS , POPLOW FRANK , DIEHLMANN UWE , HELLMANN MATTHIAS , LOEWENMUTH GUENTHER
Abstract: Producing porous catalyst pellets comprising rhenium on a support comprises preparing a mixture comprising the support and a pore-forming material (I), forming pellets from the mixture and simultaneously or subsequently removing (I) by heat treatment. The rhenium is predeposited on the support and/or added to the mixture and/or deposited on the pellets after heat treatment. Independent claims are also included for: (1) porous catalyst pellets produced as above; (2) metathesis of olefinic or acetylenic compounds by contact with porous catalyst pellets as above at 50-500[deg]C.
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公开(公告)号:DE102004009803A1
公开(公告)日:2005-09-15
申请号:DE102004009803
申请日:2004-02-28
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , STEPHAN JUERGEN , BOEHM VOLKER , BRODHAGEN ANDREAS , POPLOW FRANK
Abstract: Process for producing a supported catalyst which comprises at least 75% by weight of Al 2 O 3 , whose proportion of Al 2 O 3 in the delta or theta modification is, based on the proportion of Al 2 O 3 , at least 1% and which comprises a rhenium compound and, if appropriate, a promoter as active component (A), which comprises a) converting a customary support (S) which comprises at least 75% by weight of Al 2 O 3 and to which a promoter may, if appropriate, have been applied is converted into a modified support (S) whose proportion of Al 2 O 3 in the delta or theta modification is, based on the proportion of Al 2 O 3 , at least 1% by calcining the customary support (S) at a temperature of from 750 to 1100°C., b) producing a supported catalyst precursor from the modified support (S) by applying the active component (A) comprising the rhenium compound to the modified support (S) and c) calcining the supported catalyst precursor at a temperature of from 500 to 750° C.
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公开(公告)号:CA2584235C
公开(公告)日:2012-09-11
申请号:CA2584235
申请日:2005-10-13
Applicant: BASF AG
Inventor: STEPHAN JUERGEN , BRODHAGEN ANDREAS , SCHUBERT MARKUS , POPLOW FRANK , ROEPER MICHAEL , HILL THOMAS
IPC: C07C5/05 , C07C6/04 , C07C11/08 , C07C11/10 , C07C11/107
Abstract: The invention relates to a C4-olefin mixture having a 1,3-butadiene content of between 100 and 500 ppm and a 1,2-diene content of less than 10 ppm. The invention also relates to a method for producing said C4-olefin mixture, and to the use thereof in a metathesis reaction for producing 2-pentene and/or 3-hexene.
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公开(公告)号:MX2007010290A
公开(公告)日:2008-03-04
申请号:MX2007010290
申请日:2006-02-24
Applicant: BASF AG
Inventor: HEIDEMANN THOMAS , STEPHAN JURGEN , SCHUBERT MARKUS , POPLOW FRANK , DIEHLMANN UWE , MALTRY MICHAELA
Abstract: La invencion se refiere a un proceso para producir un compuesto o una mezcla de compuestos que tienen un doble enlace C-C o triple enlace C-C no aromatico (compuesto A) a partir de otro compuesto o una mezcla de otros compuestos que tienen un doble enlace C-C o triple enlace C-C no aromatico (compuesto B), que comprende I. una etapa (I) que consiste en liberar al compuesto (B) de impurezas poniendo en contacto dichas impurezas con un agente de adsorcion que comprende al menos 3% en peso de oxido de aluminio y activandolos a temperaturas de 450 a 1000 degree C (agente de adsorcion X) y II. una etapa (II), que consiste en eliminar las impurezas del compuesto (B) de acuerdo con la etapa (I) y poniendo dicho compuesto B en contacto con un catalizador de metatesis bajo condiciones usuales para una reaccion de metatesis.
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公开(公告)号:AT384112T
公开(公告)日:2008-02-15
申请号:AT05770210
申请日:2005-08-06
Applicant: BASF AG
Inventor: SIGL MARCUS , SCHUBERT MARKUS , STEPHAN JUERGEN , PAPP RAINER , POPLOW FRANK
Abstract: Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.
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公开(公告)号:DE102005009665A1
公开(公告)日:2006-08-31
申请号:DE102005009665
申请日:2005-02-28
Applicant: BASF AG
Inventor: SIGL MARCUS , SCHUBERT MARKUS , STEPHAN JUERGEN , POPLOW FRANK
Abstract: Preparation of an ethene stream (C 2), a propene stream (C 3), an isobutene and optionally a 4C-olefin stream (C 4), a 2-methyl-2-butene and optionally 2-butene stream (C 5), and optionally other hydrocarbons containing stream (C x), optionally several separate components containing streams, comprises contacting a C4-hydrocarbon stream with ethene in a metathesis step; and separating the streams. Preparation of an ethene stream (C 2), a propene stream (C 3), an isobutene and optionally 4C olefin stream (C 4), a 2-methyl-2-butene and optionally 2-butene stream (C 5), and optionally other hydrocarbons containing stream (C x), optionally several separate components containing streams, comprises: (A) a metathesis step, in which a C4-hydrocarbon stream, containing at least 2-butene (15 wt.%), at least isobutene (5 wt.%) and 1-butene (less than 5 wt.%) (feed stream), is contacted with ethene in the presence of usual metathesis catalysts; and (B) separation of the streams (C2, C3, C4 and optionally Cx) from the obtained hydrocarbon stream, with the stream (C5) completely or partially led back to the metathesis step. Independent claims are included for methods for preparing feed stream, comprising subjecting naphtha or other hydrocarbon compounds to steam cracking or fluid catalytic cracking (FCC)-process, or dehydrating butane containing hydrocarbon stream and followed by purifying the obtained C4-olefin-mixture containing isobutene, 2-butene, butadiene, optionally butyne and optionally 1-butene, and removing the obtained stream of C4-olefin-mixture; and removing butadiene and butyne by means of selective hydrogenation to butene or butane hydride, or butadiene and butyne by extractive distillation of the obtained C4-olefin-mixture (raffinate I), where the content of 1,3-butadiene is at a maximum of 1000 wt. ppm.
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