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公开(公告)号:AT202075T
公开(公告)日:2001-06-15
申请号:AT97119147
申请日:1997-11-03
Applicant: BASF AG
Inventor: SCHOENHERR MICHAEL DR , RAULS MATTHIAS DR , ASCHERL HERMANN , LETZELTER THOMAS , BAUMANN DIETER , POTTHOFF-KARL BIRGIT DR
IPC: C11D1/04 , C07C227/42 , C07C229/16 , C07C229/24
Abstract: A method for the preparation of a crystalline solid comprising a glycine-N,N-diacetic acid derivative of formula (I) with a very low hygroscopicity, comprises fixing the water content of the starting material containing (I) at 10-30 wt.% and then carrying out crystallisation: MOOC-CH(R)-N(CH2COOM)2 (I) R = 1-30C alkyl or 2-30C alkenyl (both optionally containing 1-5 OH, formyl, 1-4C alkoxy(carbonyl) or phenoxy groups and/or optionally containing up to 5 non-adjacent O atoms in the chain), alkoxylate groups of formula (II), phenyl-(1-20 C)-alkyl (optionally containing up to 3 1-4C alkyl, OH, carboxyl, sulpho or 1-4C alkoxycarbonyl ring substituents), 5- or 6-membered optionally benzalated heterocyclic ring containing up to 3 N, O or S atoms (optionally containing up to 3 1-4C alkyl, OH, carboxyl, sulpho or 1-4C alkoxycarbonyl substituents) or a group of formula (III): -(CH2)k-O-(A O)m-(A O)n-Y (II) -A-CH(COOM)-N(CH2COOM)2 (III) A , A = 2-4C 1,2-alkylene; Y = H, 1-12C alkyl, phenyl or 1-4C alkoxycarbonyl; k = 1-3; m, n = 0-50; A = 1-12C alkylene or single bond; and M = H, alkali(ne earth) metal or optionally substituted ammonium, with the provision that m+n = at least 4.
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公开(公告)号:DE19702734A1
公开(公告)日:1998-07-30
申请号:DE19702734
申请日:1997-01-27
Applicant: BASF AG
Inventor: BAUR RICHARD DR , POTTHOFF-KARL BIRGIT DR , BERTLEFF WERNER DR
Abstract: The invention relates to a detergent and cleaning agent formulation, containing, besides other usual components, a bleaching system based on hydrogen peroxide, peroxo compounds and/or peracids, as well as a mixture of (A) largely biodegradable aliphatic or alicyclic amine with 1-12 C-atoms, which can, in addition, carry hydroxyl groups, and (B) complexing agents having a complexing effect on heavy metals, whereby the weight ratio of A:B ranges from 20:1, in particular from 1:5 to 5:1. The above mixture of amines (A) and complexing agents (B) has a stabilizing effect on the bleaching system.
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公开(公告)号:DE19650102A1
公开(公告)日:1998-06-04
申请号:DE19650102
申请日:1996-12-03
Applicant: BASF AG
Inventor: SPERLING KARIN DR , POTTHOFF-KARL BIRGIT DR , GREINDL THOMAS DR
IPC: A61K8/44 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q9/04 , A61Q17/04 , A61Q19/00 , A61Q19/10 , C09K15/20 , A61K7/42 , A61K7/075 , A61K7/155 , A61K7/48 , A61K7/50 , C07C229/24
Abstract: Disclosed is an active substance composition, specially a cosmetic agent, a light-screening agent or a vitamin composition, containing one or several compounds of formula (I), specially an active substance composition, containing as a compound of formula (I) ethylene diaminosuccinate (EDDS), ethylene diaminoglutamate (EDDG) or (2-hydroxy propylene)-1,3-diaminosuccinate (HPDDS). The invention also relates to the use of bis(dicarboxylic acid) diaminoalkylene derivatives of the above formula (I) as complexing agents for earth alkaline metal ions and heavy metal ions in active substance compositions, specially cosmetic agents, screening agents, vitamin compositions and for stabilizing oxidation-sensitive active substances.
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公开(公告)号:DE19541012A1
公开(公告)日:1997-05-07
申请号:DE19541012
申请日:1995-11-03
Applicant: BASF AG
Inventor: WEHLAGE THOMAS DR , BOECKH DIETER DR , KAPPES ELISABETH DR , OFTRING ALFRED DR , POTTHOFF-KARL BIRGIT DR , BERTLEFF WERNER DR
Abstract: Proposed is the use of mono and bis oxime esters (I), in which L is an oxime group of formula (II) or (III), R and R being hydrogen or an organic group and Z being an alkyl group, L is a second oxime group L or an organic group linked by an O-atom or N-atom, A is a chemical bond or a bridging group and m is 0 or 1, as activators for inorganic per-compounds, in particular cold-bleach activators or optical brighteners in washing, cleaning and bleaching agents and in disinfectants.
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公开(公告)号:DE4444349A1
公开(公告)日:1996-06-20
申请号:DE4444349
申请日:1994-12-14
Applicant: BASF AG
Inventor: GREINDL THOMAS DR , KARL ULRICH DR , KROMM ERICH DR , POTTHOFF-KARL BIRGIT DR
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公开(公告)号:DE59206206D1
公开(公告)日:1996-06-13
申请号:DE59206206
申请日:1992-02-03
Applicant: BASF AG
Inventor: HESSE ANTON DR , BUHL DIETER , POTTHOFF-KARL BIRGIT DR , SANNER AXEL DR
IPC: C08F299/04 , C08K3/00 , C08K3/22 , C08K5/01 , C08K5/09 , C08K5/10 , C08K5/14 , C08K7/02 , C08L31/04 , C08L67/06
Abstract: The invention relates to a curable, thickened polyester resin moulding composition which contains from 0.1 to 20 parts by weight of a thermoplastic vinyl polymer which is compatible with the resin and contains acid groups.
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公开(公告)号:DE4427287A1
公开(公告)日:1996-02-08
申请号:DE4427287
申请日:1994-08-02
Applicant: BASF AG
Inventor: KRONER MATTHIAS DR , SCHORNICK GUNNAR DR , BAUR RICHARD DR , POTTHOFF-KARL BIRGIT DR
Abstract: A process is disclosed for preparing aspartic acid polycondensates with improved biological degradability by thermal polycondensation of finely powdered aspartic acid in solid phase, at temperatures from 180 to 250 DEG C, until maximum 70 % by weight of the theoretically possible amount of water produced during polycondensation are removed from the reaction mixture. Also disclosed is the use of the thus produced polycondensates as additives for washing and cleaning agents and as scale inhibitors.
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公开(公告)号:DE4416438A1
公开(公告)日:1995-11-16
申请号:DE4416438
申请日:1994-05-10
Applicant: BASF AG
Inventor: MUELLER REINHARD DR , GREINDL THOMAS DR , OFTRING ALFRED DR , SCHERR GUENTER DR , GESNER THOMAS DR , TRIESELT WOLFGANG DR , POTTHOFF-KARL BIRGIT DR , WEHLAGE THOMAS DR
IPC: B01J31/16 , B01J31/18 , B01J31/22 , C07F1/00 , C07F3/00 , C07F13/00 , C07F15/06 , C11D3/39 , D06L3/02 , D06L4/12 , C07F19/00 , B01J31/06 , C07D257/00 , C07D403/04 , C07F9/547 , C07F9/6515 , C07F9/6524 , C07F9/655 , C11D3/395 , C11D7/54 , D21H21/32
Abstract: Single or multi-nuclear metal complexes [LnMmXp] Y, in which M is manganese in the oxidation number (II, III, IV, V and/or VI), copper in the oxidation number (I and/or II), cobalt in the oxidation number (II and/or III) or zinc in the oxidation number (II), X is a co-ordination or bridge group, Y is a counter-ion in the corresponding stoichiometric quantity for compensating a charge z, in which z may be positive, zero or negative as the charge of the metal complex, n and m are mutually independently whole numbers from 1 to 8, p is a whole number from 0 to 32 and L is certain nitrogen and/or oxygen atoms as co-ordination centres-containing organic molecules as ligands. The metal complexes (I) are suitable as bleaching and oxidation catalysts, especially in washing and cleaning agents and in textile and paper bleaching.
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公开(公告)号:DE4327494A1
公开(公告)日:1995-02-23
申请号:DE4327494
申请日:1993-08-16
Applicant: BASF AG
Inventor: KRONER MATTHIAS DR , SCHORNICK GUNNAR DR , BAUR RICHARD DR , KUD ALEXANDER DR , POTTHOFF-KARL BIRGIT DR , SCHWENDEMANN VOLKER DR
IPC: C02F5/12 , C08G73/10 , C11D3/37 , C07C229/14 , C07C235/28 , C08G69/10
Abstract: A process for the preparation of polyaspartimides (polyaspartic acid imides) by thermal condensation of aspartic acid, asparagine, monoamides or ammonium salts of maleic acid, fumaric acid or malic acid or mixtures thereof in polyalkylene glycols having a molecular weight of at least 150, polyalkylene glycols in which one or both of the end groups are masked and/or polytetrahydrofurans, and optionally hydrolysis of the polyaspartimides using a base, and the use of the resultant reaction mixtures as an additive to phosphate-free and reduced-phosphate detergents and cleaning agents.
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公开(公告)号:ES2056516T3
公开(公告)日:1994-10-01
申请号:ES91106394
申请日:1991-04-20
Applicant: BASF AG
Inventor: POTTHOFF-KARL BIRGIT DR , SPERLING-VIETMEIER KARIN DR , SANNER AXEL DR
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