ACRYLATE POLYMERS BASED ON TERT-BUTYL ACRYLATE AND/OR TERT-BUTYL METHACRYLATE

    公开(公告)号:CA2428309C

    公开(公告)日:2010-01-12

    申请号:CA2428309

    申请日:2001-11-09

    Applicant: BASF AG

    Abstract: The invention relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 w t. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monome r A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monom er B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radical ly copolymerizable monomer mixture designated as monomer C, whereby at least on e of monomers C yields a homopolymer with a glass-transition temperature lower than 30 ~C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chai n length of C 14 to C 22. The invention also relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert - butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30 ~C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 10 to C 22 followed by a hydrogen peroxide treatment. The invention also relates to the use of these acrylate polymers as film formers as well as to their use in cosmetic preparations.

    23.
    发明专利
    未知

    公开(公告)号:DE10202253A1

    公开(公告)日:2003-08-07

    申请号:DE10202253

    申请日:2002-01-21

    Applicant: BASF AG

    Abstract: Hair-setting compositions comprising A) 0.5 to 20% by weight of a homopolymer of N-vinylcaprolactam or an anionic or nonionic copolymer of at least 70% by weight of N-vinylcaprolactam (polymer A), and B) 0.5 to 20% by weight of a terpolymer (polymer B) obtainable by copolymerization (a) of at least one C1-C4 N-alkylacrylamide or a C1-C4 N-alkylmethacrylamide and (b) at least one C1-C4 hydroxyalkyl ester or a C1-C4 alkyl ester of acrylic acid or methacrylic acid and (c) acrylic acid and/or methacrylic acid C) 0.5 to 20% by weight of a polymer chosen from the group consisting of copolymers of vinylpyrrolidone and a vinyl ester and of homopolymers of vinylpyrrolidone.

    FIXATIVE AGENTS FOR HAIR
    24.
    发明专利

    公开(公告)号:AU2003235706A1

    公开(公告)日:2003-07-30

    申请号:AU2003235706

    申请日:2003-01-20

    Applicant: BASF AG

    Abstract: Hair-setting compositions comprising A) 0.5 to 20% by weight of a homopolymer of N-vinylcaprolactam or an anionic or nonionic copolymer of at least 70% by weight of N-vinylcaprolactam (polymer A), and B) 0.5 to 20% by weight of a terpolymer (polymer B) obtainable by copolymerization (a) of at least one C1-C4 N-alkylacrylamide or a C1-C4 N-alkylmethacrylamide and (b) at least one C1-C4 hydroxyalkyl ester or a C1-C4 alkyl ester of acrylic acid or methacrylic acid and (c) acrylic acid and/or methacrylic acid C) 0.5 to 20% by weight of a polymer chosen from the group consisting of copolymers of vinylpyrrolidone and a vinyl ester and of homopolymers of vinylpyrrolidone.

    ACRYLATE POLYMERS BASED ON TERT-BUTYL ACRYLATE AND/OR TERT-BUTYL METHACRYLATE

    公开(公告)号:CA2428309A1

    公开(公告)日:2002-05-16

    申请号:CA2428309

    申请日:2001-11-09

    Applicant: BASF AG

    Abstract: The invention relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30 ~C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 14 to C 22. The invention also relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert- butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30 ~C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 10 to C 22 followed by a hydrogen peroxide treatment. The invention also relates to the use of these acrylate polymers as film formers as well as to their use in cosmetic preparations.

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