26.
    发明专利
    未知

    公开(公告)号:ES2093136T3

    公开(公告)日:1996-12-16

    申请号:ES92106987

    申请日:1992-04-24

    Applicant: BASF AG

    Abstract: The invention relates to a process for the preparation of CFC-free, soft and elastic, semi-rigid or rigid mouldings containing urethane groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one amorphous, microporous silica gel which preferably has a mean pore diameter with more than 40 % in range from 0.1 to 10 nm, a pore volume of from 0.15 to 1.8 ml/g and a BET surface area of from 200 to 900 m /g, and optionally further additives, and g) assistants, in a closed mould with compaction. t

    27.
    发明专利
    未知

    公开(公告)号:DK0545175T3

    公开(公告)日:1996-11-18

    申请号:DK92119790

    申请日:1992-11-20

    Applicant: BASF AG

    Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.

    28.
    发明专利
    未知

    公开(公告)号:ES2090463T3

    公开(公告)日:1996-10-16

    申请号:ES92119790

    申请日:1992-11-20

    Applicant: BASF AG

    Abstract: The invention relates to a process for the preparation of chlorofluorocarbon-free (CFC-free), elastomeric, semi-rigid or rigid mouldings containing urethane groups or urethane and urea groups and having a cellular core and a compacted peripheral zone with an essentially pore-free, smooth surface, by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms and optionally c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts, f) at least one microporous activated charcoal and/or a microporous carbon molecular sieve, which preferably has a mean pore diameter with more than 40% in the range from 0.3 to 3 nm, a pore volume of from 0.20 to 1.4 ml/g and a BET surface area of from 500 to 2500 m /g or greater, and optionally further additives and g) auxiliaries, in a closed mould with compaction.

    29.
    发明专利
    未知

    公开(公告)号:DE4435239A1

    公开(公告)日:1996-04-11

    申请号:DE4435239

    申请日:1994-10-04

    Applicant: BASF AG

    Abstract: A method is proposed of producing hydroxylamines from ammonia or the associated amines, hydrogen and oxygen. The method involves the reaction by heterogeneous catalysis of the initial materials; for this purpose, use is made of an oxidation catalyst based on titanium- or vanadium silicates with a zeolitic structure and comprising 0.01-20 wt.% platinum-group metals selected from the group ruthenium, rhodium, palladium, osmium, iridium and platinum, these metals being present in at least two different bonding energy states.

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