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公开(公告)号:DE19633967A1
公开(公告)日:1998-02-26
申请号:DE19633967
申请日:1996-08-22
Applicant: BASF AG
Inventor: REHMER GERD DR , STANGER BERND DR , AUCHTER GERHARD DR , TUERK JOHANNES , AYDIN ORAL DR , FUESL RUEDIGER
IPC: C08F2/22 , C08F2/16 , C08F2/24 , C08F220/06 , C08F220/12 , C08F220/18 , C09J7/04 , C09J133/04 , C09J133/06
Abstract: Aqueous solutions of adhesive materials which can be easily filtered and deodorized, particularly for self-adhesive labels, with a solids content of over 65 % can be produced with good reproducibility of characteristics through copolymerization of esters of acrylic and/or methacrylic acid in the presence of less than 50 ppm inhibitor and preferably in the presence of 0.01 to 5 % by weight of reducing agents, according to a special emulsion process. The highly concentrated and steam-deodorized adhesive material dispersion is free of coagulants and specks.
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公开(公告)号:DE19617183A1
公开(公告)日:1997-10-30
申请号:DE19617183
申请日:1996-04-29
Applicant: BASF AG
Inventor: REHMER GERD DR , HOLTRUP WALTER , SCHWARZ KARLHEINZ
Abstract: A process for the final preparation of polymer dispersions, in which the dispersion is circulated from a vessel (7) fitted with a stirrer (6) through a line (3) with a mixer (2) by means of a pump (4) in line (3), and treated with solution(s) or dispersion(s) of finishing agent(s) (I) which is/are injected from storage tank(s) (5) via a feed line (9) before the dispersion enters the mixer (2).
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公开(公告)号:DE19537936A1
公开(公告)日:1997-04-17
申请号:DE19537936
申请日:1995-10-12
Applicant: BASF AG
Inventor: REHMER GERD DR
Abstract: The invention concerns a process for preparing aqueous polymer dispersions by the emulsion-polymerization of olefinically unsaturated compounds. The invention is characterized in that the water-soluble initiator used is added at least partially in the form of an aqueous initiator solution which comprises a surfactant and the initiator or, in the case of reduction-oxidation (redox) initiator system, at least one initiator component (emulsified initiator solution).
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公开(公告)号:DE19514266A1
公开(公告)日:1996-10-17
申请号:DE19514266
申请日:1995-04-15
Applicant: BASF AG
Inventor: RECK BERND DR , FRANZMANN GERNOT DR , BECHERT BERTOLD , BAECHER REINHARD DR , REHMER GERD DR
IPC: C04B41/48 , C04B41/63 , C08F20/38 , C08F20/58 , C08F220/06 , C08F220/38 , C08F220/54 , C08F246/00 , C08F265/04 , C08F265/10 , C08L33/14 , C08L33/26 , C08L51/00 , C09D133/06 , C09D133/14 , C09D133/26 , C09D151/00 , C04B41/83 , C09D133/24
Abstract: A process for preserving a mineral moulding by coating the surface of said casting with an aqueous composition containing an aqueous polymer dispersion in which the polymer P in dispersed distribution contains a polymerised ethylenically unsaturated acid of the 2-acrylamide-2-methyl propane sulphonic acid type incorporated in radically polymerised form.
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公开(公告)号:DE59009278D1
公开(公告)日:1995-07-27
申请号:DE59009278
申请日:1990-08-31
Applicant: BASF AG
Inventor: REHMER GERD DR , AUCHTER GERHARD DR , BOETTCHER ANDREAS DR , FRANZ LOTHAR DR , JAEGER HELMUT
IPC: C08F2/04 , C08F224/00 , C08F226/06 , C08F228/06 , C08F246/00 , C09J157/10
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公开(公告)号:ES2061862T3
公开(公告)日:1994-12-16
申请号:ES89117621
申请日:1989-09-23
Applicant: BASF AG
Inventor: BLUM RAINER , REHMER GERD DR , SCHUPP HANS DR
IPC: C08G73/06 , C08G73/10 , C08J3/28 , C08L79/04 , C08L79/08 , C09D179/00 , C09D179/04 , C09D179/08 , G03F7/038 , H01L31/09 , H05K3/28
Abstract: The invention relates to radiation-reactive mixtures of certain precursors and carbonyl compounds which contain aromatic radicals and, in the UV-excited state, are capable of hydrogen abstraction, which mixtures experience a solubility differentiation on irradiation with actinic light and are suitable for the preparation of polyimides, polyisoindoloquinazolinediones, polyoxazinediones, polyquinazolinediones or polyquinazolones. … They are suitable for the production of insulating layers and printed circuit boards.
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公开(公告)号:ES2057715T3
公开(公告)日:1994-10-16
申请号:ES91119041
申请日:1991-11-08
Applicant: BASF AG
Inventor: BARWICH JUERGEN DR , REHMER GERD DR , BOTT KASPAR DR
IPC: C07C231/06 , C07C235/20 , C07C235/78 , C07C235/84 , C08F20/60 , C08F220/60 , C08F246/00 , C09J7/02 , C09J133/24
Abstract: Unsaturated phenone derivatives of the general formula I I where R1 is C1-C4-alkyl, cyclopropyl, cyclopentyl, cyclohexyl, indanonyl, tetralonyl, phenyl or phenyl in which some or all of the hydrogen atoms have been replaced by a C1-C4-alkyl, C1-C4-alkoxy or C1-C4-thioalkyl group, or together with R2 or R6 forms an ethylene or propylene bridge, R2 to R6 are each hydrogen, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-thioalkyl, and R3, R4 and R5 may each additionally be hydroxyl, R2 or R6 may additionally together with R1 form an ethylene or propylene bridge and one or more, but not more than three, of the radicals R2 to R6 are a group of the general formula II II or III III where K is C1-C10-alkylene which may contain 1 or 2 oxygen or sulfur atoms, Y is straight-chain or branched C1-C10-alkylene or is C1-C10-alkylene which is substituted by carboxyl, a carboxylate anion, an alkyl C1-C4-carboxylate group or hydroxyl, X is -NH- or -(N-Alkyl)- of 1 to 4 carbon atoms and Z is hydrogen or C1-C4-alkyl.
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公开(公告)号:DE59006489D1
公开(公告)日:1994-08-25
申请号:DE59006489
申请日:1990-08-31
Applicant: BASF AG
Inventor: REHMER GERD DR , RAU MARIA GYOPAR DR , WISTUBA ECKEHARDT DR , BAECHER REINHARD DR , MATTHAEI LOTHAR
IPC: C08K3/00 , C08F2/22 , C08K5/07 , C08K5/132 , C08L31/02 , C08L31/04 , C08L33/04 , C08L33/06 , C09D131/02 , C09D131/04 , C09D133/06 , C09J131/02 , C09J131/04
Abstract: Aqueous synthetic resin formulations essentially contain A) from 3 to 75% by weight of one or more synthetic resins which are composed of a) from 50 to 99.9% by weight of one or more unsaturated carboxylic or vinyl esters, b) from 0.1 to 12% by weight of one or more alpha , beta -monoethylenically unsaturated monobasic or dibasic acids or their ahydrides, c) from 0 to 10% by weight of one or more monoethylenically unsaturated acetophenone or benzophenone derivatives, d) from 0 to 35% by weight of one or more other copolymerizable monoethylenically unsaturated monomers, in polymerized form, B) one or more metal cations having a charge of from 2 to 4, in water-soluble form, C) from 0 to 10% by weight, based on the synthetic resin A, or benezophenones or acetophenones which are not monoethylenically unsaturated, D) effective amounts of emulsifiers or protective colloids or a mixture of these active ingredients, E) not less than 5% by weight of water and F) from 0 to 85% by weight of finely divided fillers, and the total amount of the cations B is such that it is capable of neutralizing from 0.2 to 6 times the amount, corresponding to the amount of acid functions incorporated in the form of the monomers b in the synthetic resin A, of their conjugated bases. These synthetic resin formulations are suitable for coating, adhesive bonding, sealing or impregnating.
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公开(公告)号:DE58906989D1
公开(公告)日:1994-03-24
申请号:DE58906989
申请日:1989-11-06
Applicant: BASF AG
Inventor: HORN PETER DR , REHMER GERD DR , LUTTER HEINZ-DIETER DR , RAMLOW GERHARD DR , HINZ WERNER DR , SCHMIDT HANS ULRICH
IPC: C08F216/14 , C08F218/10 , C08F220/28 , C08F220/58 , C08F222/20 , C08F226/00 , C08F226/06 , C08F290/06 , C08F299/02 , C08G18/40 , C08G18/62 , C08L75/04 , C09K23/52
Abstract: The novel copolymers having K values of from 5 to 80 are prepared by free-radical polymerisation of A) 20 to 80% by weight, based on the total weight of (A) and (B), of at least one olefinically unsaturated polyoxyalkylene alcohol or polyester alcohol adduct, (B) 80 to 20% by weight, based on the total weight of (A) and (B), of at least one vinyl monomer from the group comprising N-vinylformamide, -2-pyrrolidone, -2-piperidone, -2-caprolactam, -imidazole, -2-ethyleneurea and -2-propyleneurea, C) 0.05 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate, D) 0 to 10 parts by weight of at least one alpha , beta -monoolefinically unsaturated acid and E) 0 to 30 parts by weight of at least one olefinically unsaturated carboxamide and/or carboxylate and/or styrene, the parts by weight of (C), (D) and (E) in each case being based on 100 parts by weight of the monomers (A) and (B). The copolymers are used as assistants and/or additives, for example as dispersion and/or emulsification assistants, or as additives for improving the mechanical properties, in formulations for the preparation of polyisocyanate polyaddition products.
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公开(公告)号:DE58904789D1
公开(公告)日:1993-07-29
申请号:DE58904789
申请日:1989-10-21
Applicant: BASF AG
Inventor: REHMER GERD DR , BOETTCHER ANDREAS DR , PFOEHLER PETER DR , AYDIN ORAL DR , NESTLER GERHARD DR
IPC: C08J5/18 , C08F220/18 , C08L23/00 , C08L33/04 , C08L33/06 , C09J133/06
Abstract: Compositions which can be crosslinked under an atmospheric oxygen atmosphere by means of ultraviolet irradiation and are based on (meth)acrylate copolymers having a K value of from 10 to 100, obtained by free-radical polymerisation in solid phase or solution of a) 5 to 97.4% by weight of i-amyl acrylate and/or i-amyl methacrylate and b) 0 to 89.9% by weight of (meth)acrylates whose hompolymers have a glass transition temperature of below -30 DEG C, c) 2.5 to 30% by weight of alpha , beta -monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature of above - 30 DEG C, d) 0 to 10% by weight of monoolefinically unsaturated acids and/or anhydrides thereof, e) 0 to 20% by weight of further olefinically unsaturated monomers containing at least one of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary or tertiary amine and ether, and f) 0.1 to 5% by weight of a copolymerisable benzophenone or acetophenone derivative, the sum of the percentages by weight x = a + b + c + d + f in each case being 100.
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