33.
    发明专利
    未知

    公开(公告)号:DE3316593A1

    公开(公告)日:1984-11-08

    申请号:DE3316593

    申请日:1983-05-06

    Applicant: BASF AG

    Abstract: 1. A process for preparing an ester of acrylic or methacrylic acid with a hydroxyl-containing organic compound, which comprises esterifying a saturated polyester which contains no fewer than 2 free hydroxyl groups per molecule and may contain ether groups or a saturated polyether which contains no fewer than 2 free hydroxyl groups per molecule, this polyester or polyether having an average molecular weight ~Mn of from 400 to 4,000, with from 100 to 150 mol %, based on the OH groups of the polyester or polyether, of acrylic acid or methacrylic acid in the presence of an acidic esterification catalyst and one or more hydrocarbons forming an azeotropic mixture with water and a small amount of a polymerization inhibitor at elevated temperature with azeotropic removal of the resulting water, after the esterification removing the hydrocarbon by distillation and after neutralization of the esterification catalyst reacting the remaining acrylic or methacrylic acid with an amount, equivalent to the acid number, of an epoxy compound having no fewer than two epoxy groups per molecule until an acid number =

    35.
    发明专利
    未知

    公开(公告)号:ES2122726T3

    公开(公告)日:1998-12-16

    申请号:ES96100873

    申请日:1996-01-23

    Applicant: BASF AG

    Abstract: Prodn. of high mol. polymers involves: (a) polymerising water-soluble, mono-ethylenically unsatd. monomers and opt. crosslinkers contg. non-conjugated ethylenically unsatd. double bonds. in the molecule and opt. water-insol. monoethylenically unsatd. monomers in aq. soln. in the presence of polymerisation initiators in a tubular reactor; and (b) forcing the gelatinous reaction mixt. from the reactor with an inert gas. The reactor has: (i) a conical taper at one end, so the ratio of the dia. (D1) of the reactor to the dia. (D2) at the end of the cone is (2-25); and (ii) the angle between D1 at the beginning of the cone and the inner wall of the cone of more than 45 and less than 90 degrees .

    36.
    发明专利
    未知

    公开(公告)号:DE59500894D1

    公开(公告)日:1997-12-04

    申请号:DE59500894

    申请日:1995-07-05

    Applicant: BASF AG

    Abstract: A low viscosity mixt. contains (i) 40-97.5 wt.% of amphiphilic nonionic graft polymer contg.(a) at least 20 wt.% of polyalkylene oxide units or polyvinylpyrrolidone units as the hydrophilic part of the molecule and (b) at least 40% of vinyl ester and/or (meth)acrylic ester units as the hydrophobic part of the molecule, (ii) 2.5-60% of polyalkylene glycol,alkoxylated alcohol, alkylphenol or amine, or 2-10C cpd. with 1-4 OH gps., when Mn of the polymers is not above 2500, as viscosity reducer, and (iii) 0-40% of homogenising or phase stabilising additive comprising (1) water, (2) an 8-25C mono- or di-basic acid, fatty alcohol sulph(on)ate, alkylbenzene sulphonate, sulphonation and/or sulphation prod. of 8-22C alkoxylated alcohol or alkylphenol, alkyl(poly)glucoside with 1-20C in the alkyl gp., mono-, oligo- or poly-saccharide or derivs. obtd. by oxidn. or redn., or (c) mixts. of (1) and (2) in ratio by wt. of 100:1-20:80.

    37.
    发明专利
    未知

    公开(公告)号:AT159748T

    公开(公告)日:1997-11-15

    申请号:AT95110442

    申请日:1995-07-05

    Applicant: BASF AG

    Abstract: A low viscosity mixt. contains (i) 40-97.5 wt.% of amphiphilic nonionic graft polymer contg.(a) at least 20 wt.% of polyalkylene oxide units or polyvinylpyrrolidone units as the hydrophilic part of the molecule and (b) at least 40% of vinyl ester and/or (meth)acrylic ester units as the hydrophobic part of the molecule, (ii) 2.5-60% of polyalkylene glycol,alkoxylated alcohol, alkylphenol or amine, or 2-10C cpd. with 1-4 OH gps., when Mn of the polymers is not above 2500, as viscosity reducer, and (iii) 0-40% of homogenising or phase stabilising additive comprising (1) water, (2) an 8-25C mono- or di-basic acid, fatty alcohol sulph(on)ate, alkylbenzene sulphonate, sulphonation and/or sulphation prod. of 8-22C alkoxylated alcohol or alkylphenol, alkyl(poly)glucoside with 1-20C in the alkyl gp., mono-, oligo- or poly-saccharide or derivs. obtd. by oxidn. or redn., or (c) mixts. of (1) and (2) in ratio by wt. of 100:1-20:80.

    39.
    发明专利
    未知

    公开(公告)号:DE19511859A1

    公开(公告)日:1996-10-02

    申请号:DE19511859

    申请日:1995-03-31

    Applicant: BASF AG

    Abstract: The invention concerns a method of preparing mixtures of alkali-metal salts of polyaspartic acids and alkali-metal salts of acylated polyaspartic acids by a) hydrolytically cleaving peptide bonds of polyaspartimides and/or polyaspartic acids with aqueous alkali-metal bases, a molar excess of at least one alkali-metal base being used per mole of aspartimide and/or aspartic acid units and b) reacting, in aqueous solution at pH values of 6 and over, the hydrolysis products with carboxylic acid chlorides, diketenes, carboxylic acid esters or caboxylic acid anhydrides or polymers which contain polymerized anhydride and/or ester groups. The invention also concerns the use of such mixtures as additives to phosphate-free and phosphate-reduced washing and cleaning agents.

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