公开(公告)号：DE19731745C1

公开(公告)日：1998-09-17

申请号：DE19731745

申请日：1997-07-23

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF DR ,  LEBKUECHER ROLF DR ,  NEUHAUSER HORST DR ,  HENNE ANDREAS DR ,  BECKER RAINER DR

IPC: C07D295/02 ,  B01J23/75 ,  C07B37/04 ,  C07B61/00 ,  C07C209/26 ,  C07D295/023 ,  C07B43/04 ,  C07C209/24

Abstract: In the production of alkylamines (I) from amines (II) and aliphatic aldehydes (III) in the presence of hydrogen (H2) by introducing (II) and (III) into a reactor in separate streams and mixing in the stationary catalyst bed, only the (II) stream or only the (III) stream is preheated.

公开(公告)号：DE19709488A1

公开(公告)日：1998-09-10

申请号：DE19709488

申请日：1997-03-07

Applicant: BASF AG

Inventor： SIMON JOACHIM DR ,  BECKER RAINER DR ,  LEBKUECHER ROLF DR ,  NEUHAUSER HORST DR

IPC: C07D295/02 ,  B01J23/72 ,  B01J23/78 ,  B01J23/86 ,  C07B61/00 ,  C07C209/16 ,  C07C211/03 ,  C07D295/023 ,  C07D295/03 ,  C07C211/08 ,  B01J23/76

Abstract: A method for the N-alkylation of amines by reacting alcohol with (di)alkylamine in the presence of hydrogen is carried out in the presence of a catalyst based on copper and magnesium silicate, which contains 0-2 wt.% each of barium oxide, chromium (III) oxide (Cr2O3) and/or zinc oxide. Also claimed is the use of this catalyst for N-alkylation of amines.

公开(公告)号：DE19650537A1

公开(公告)日：1998-06-10

申请号：DE19650537

申请日：1996-12-05

Applicant: BASF AG

Inventor： BAUR RICHARD DR ,  EHLE BEATE DR ,  BOECKH DIETER DR ,  SCHUERMANN GREGOR DR ,  PERNER JOHANNES DR ,  SCHNEIDER JUERGEN DR ,  KAHMEN MARTIN AUS DEM DR ,  BECKER RAINER DR

IPC: C11D1/52 ,  C07C233/18 ,  C07C67/08 ,  C07C69/28 ,  C07C231/02 ,  C07C305/10 ,  C11D1/72 ,  C11D1/74 ,  C11D3/386 ,  C12N9/96 ,  D06L1/12 ,  D06M13/419

Abstract: Enzyme stabilisers in washing or cleaning agents comprise end group capped fatty acid amide alkoxylates of formula (I): R -CO-NH-(CH2)n-O-(AO)x-R (I) R = 5-21C alk(en)yl ; R = 1-4C alkyl ; A = 2-4C alkylene ; n = 2-3 ; and x = 1-6. Also claimed are (i) detergents containing 0.1-50 wt.% (I) and 0.1-10 wt.% synthesised enzyme, (ii) mixtures comprising (A) compounds (I) and (B) fatty alcohol (poly)ether sulphates, fatty alcohol (poly)alkoxylates and/or fatty acid (poly)alkoxylates, (iii) the preparation of mixtures comprising (A) compounds (I) and (B`) fatty acid (poly)alkoxylates corresponding to (A) in which -NH- is replaced by O, (iv) the use of these mixtures in detergents, and (v) detergents containing 0.1-50 wt.% of these mixtures.

公开(公告)号：DE59501841D1

公开(公告)日：1998-05-14

申请号：DE59501841

申请日：1995-12-06

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF DR ,  BECKER RAINER DR ,  GEHRER EUGEN DR ,  SCHOSSIG JUERGEN DR ,  HENNE ANDREAS DR

IPC: B01J21/12 ,  B01J29/06 ,  C07B61/00 ,  C07C45/60 ,  C07C47/12

Abstract: Prodn. of glutaraldehyde (I) comprises reacting a 2-alkoxy-2,3-dihydro-4H-pyran of formula (II) with water at 0-150 degrees C and 0.01-50 bar in the presence of a microporous crystalline aluminosilicate with a pore dia. above 5.4 Angstroms. R = 1-20C alkoxy.

公开(公告)号：DE19640554A1

公开(公告)日：1998-04-02

申请号：DE19640554

申请日：1996-10-01

Applicant: BASF AG

Inventor： MASSONNE KLEMENS DR ,  BECKER RAINER DR ,  NEUHAUSER HORST DR ,  ZIMMERMANN HORST DR ,  REIF WOLFGANG DR ,  CRAMERS PETER ,  NARDIN DANIEL

IPC: C07D307/88 ,  B01J25/00

Abstract: The invention concerns a process for preparing phthalides of general formula (I), in which R , R , R and R , independently of one another, designate hydrogen, C1-C4 alkyl or C1-C4 alkoxy, by hydrogenating phthalic acid anhydrides of general formula (II), in which the groups R , R , R and R have the above meanings, with hydrogen in the presence of suspended Raney-type catalysts in a hydrogenating device by mixing a liquid phase containing the catalyst and the phthalic acid anhydride used and the resultant phthalide and a gaseous phase containing the hydrogenating hydrogen using a mixing device which has a mixing output of at least 50 W/l in the liquid phase

公开(公告)号：DE19624283A1

公开(公告)日：1998-01-02

申请号：DE19624283

申请日：1996-06-18

Applicant: BASF AG

Inventor： SIMON JOACHIM DR ,  DOSTALEK ROMAN DR ,  LINGK HEINZ ,  BECKER RAINER DR ,  HENNE ANDREAS DR ,  LEBKUECHER ROLF DR ,  FREIRE ERDBRUEGGER CRISTINA DR ,  HESSE MICHAEL DR ,  KRATZ DETLEF DR

IPC: C07D295/02 ,  B01J23/72 ,  B01J37/02 ,  C07B61/00 ,  C07D295/03

Abstract: Preparation of N-substituted cyclic amines of formula (I) comprises reacting primary amines of formula R NH2 (II) with diols of formula HO-A-OH (III) in the presence of hydrogen and a catalyst containing copper obtained by impregnating an inert support with an aqueous solution of an ammine complex of a Cu compound (IV) that readily undergoes thermal decomposition, then drying and calcining to give a catalyst containing 5-50 wt.% Cu, calculated as oxide. A = alkylene or (CH2)n-ÄO-CH2)mÜr (optionally substituted by one or more R ); R , R = alkyl, alkoxyalkyl, optionally alkyl- or alkoxy-substituted cycloalkyl, cycloalkylalkyl, aryl or arylalkyl; n, m = 2-8; r = 1-3.

公开(公告)号：AT158788T

公开(公告)日：1997-10-15

申请号：AT95111954

申请日：1995-07-29

Applicant: BASF AG

Inventor： REIF WOLFGANG DR ,  FRANZ LOTHAR DR ,  STOPS PETER ,  MENGER VOLKMAR DR ,  WINDERL SIEGFRIED DR ,  BECKER RAINER DR ,  KUMMER RUDOLF DR

IPC: B01J23/88 ,  B01J21/06 ,  B01J23/885 ,  B01J37/03 ,  C07C209/08 ,  C07C209/16 ,  C07C209/18 ,  C07C211/03

Abstract: Prodn. of amines (I) comprises reacting a primary or secondary alcohol (II) with ammonia or a primary or secondary amine (III) at 80-250 deg.C under 1-400 bar hydrogen pressure in the presence of a catalyst comprising: a) 20-85wt.% O2-contg. Zr cpds. calculated as ZrO2; b) 1-30 wt.% O2-contg. Cu cpds. calculated as CuO; c) 30-70 wt.% O2 contg. Ni cpds. calculated as NiO; d) 0-15 wt.% O2 contg. Mo cpds. calculated as MoO3; and opt. e) up to 10 wt.% O2-contg. Al and/or Mn cpds. calculated as Al2O3 or MnO2.

公开(公告)号：DE19527532A1

公开(公告)日：1997-01-30

申请号：DE19527532

申请日：1995-07-27

Applicant: BASF AG

Inventor： SIGWART CHRISTOPH DR ,  FISCHER ROLF DR ,  ELLER KARSTEN DR ,  BECKER RAINER DR ,  PLITZKO KLAUS-DIETER DR ,  HEILEN GERD DR

IPC: C08G18/48 ,  C08G18/67 ,  C08G63/66 ,  C08G65/10 ,  C08G65/20 ,  C08G65/26 ,  C08G65/28 ,  C08G69/40

Abstract: In the method proposed for the production of copolymers of tetrahydrofuran and 2-butine-1,4-diol by the catalytic polymerization of tetrahydrofuran, the polymerization is carried out over a heterogeneous acid catalyst having acid centres with a pKa-value of

公开(公告)号：DE19525507A1

公开(公告)日：1997-01-16

申请号：DE19525507

申请日：1995-07-13

Applicant: BASF AG

Inventor： BECKER RAINER DR ,  KERSTEN SIEGFRIED DR ,  STADLER KLAUS PETER DR ,  WACHE HARRO DR ,  WAMBACH LUDWIG DR ,  WEYER HANS-JUERGEN DR ,  ROS KARL-HEINZ DR

IPC: C07C209/12 ,  C07C211/63 ,  C07C209/08

公开(公告)号：DE19507522A1

公开(公告)日：1996-09-05

申请号：DE19507522

申请日：1995-03-03

Applicant: BASF AG

Inventor： WEHLAGE THOMAS DR ,  KAPPES ELISABETH DR ,  OFTRING ALFRED DR ,  SCHOENHERR MICHAEL DR ,  BECKER RAINER DR

IPC: C07D217/02 ,  C07D217/04

Abstract: Prodn. of 3,4-dihydro-isoquinoline cpds. of formula (I) comprises oxidising 1,2,3,4-tetrahydro-isoquinoline cpds. of formula (II) with NaOCl and/or KOCl in the absence of organic solvents. R2, R3 = R' or R"; R' = 1-20C alkyl, up to 20C cycloalkyl or aryl (all opt. substd. by aryl, NO2, CN, halogen, 1-20C alkyl, amino, 1-20 aminoalkyl, 1-20C thioalkyl, 1-20 sulphoalkyl, carboxylate ester, OH, 1-20C alkoxy, polyalkoxy or 1-40C quaternised di- or tri- alkylammonium or carboxyalkyl), H or heterocyclyl; R" = NO2, halo, CN, 1-20C alkoxy, phenoxy, benzyloxy, keto, COOH, 1-20C carboalkoxy, NH2 or mono- or di(1-6C alkyl)amino. Also claimed is a process as above where the prod. is quaternised with R1X to give a 3,4-dihydro-isoquinolinium salt of formula (III). R1 = R'; X = oxidn.-stable anion, pref. Cl, Br, sulphate, methylsulphate, sulphonate, p-toluenesulphonate, boron tetrafluoride, phosphorus pentafluoride, phosphate, cyanide or ethylsulphate.