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    43.
    发明专利
    未知

    公开(公告)号：DE59306412D1

    公开(公告)日：1997-06-12

    申请号：DE59306412

    申请日：1993-09-25

    Applicant: BASF AG

    Inventor： KRONER MATTHIAS ,  HARTMANN HEINRICH ,  PERNER JOHANNES ,  JAEGER HANS-ULRICH ,  DIESSEL PAUL ,  BAUR RICHARD ,  SCHWENDEMANN VOLKER

    IPC: C04B24/28 ,  C04B24/38 ,  C08B31/00 ,  C08G65/34 ,  C09K23/00 ,  C09K23/52 ,  C11D3/37

    Abstract: PCT No. PCT/EP93/02613 Sec. 371 Date Mar. 20, 1995 Sec. 102(e) Date Mar. 20, 1995 PCT Filed Sep. 25, 1993 PCT Pub. No. WO94/07939 PCT Pub. Date Apr. 14, 1994.Soluble polyacetals containing acetaldehyde acetal units are obtainable by cationically initiated addition polymerization of (a) compounds containing at least 3 hydroxyl groups, and (b) divinyl ethers containing terminal vinyl ether groups, or mixtures of such divinyl ethers and monovinyl ethers, in the presence or absence of (c) dihydroxy compounds and/or monohydroxy compounds, and are useful as admixture in phosphate-reduced and phosphate-free detergents and cleaners and as dispersant for finely divided minerals.

    44.
    发明专利
    未知

    公开(公告)号：ES2061885T3

    公开(公告)日：1994-12-16

    申请号：ES89120522

    申请日：1989-11-06

    Applicant: BASF AG

    Inventor： PERNER JOHANNES DR ,  DIESSEL PAUL ,  HARTMANN HEINRICH DR ,  DENZINGER WALTER ,  OFTRING ALFRED DR ,  SCHOENLEBEN WILLIBALD DR

    IPC: C11D3/32 ,  C11D3/37

    Abstract: The use of copolymers which contain as essential copolymerised units (a) 50 to 99 mol% of units of monoethylenically unsaturated (a) C3- to C8-monocarboxylic acids, monoethylenically unsaturated C4- to C8-dicarboxylic acids, hemiesters of monoethylenically unsaturated C4- to C8-dicarboxylic acids, esters of monoethylenically unsaturated C3- to C8-carboxylic acids, C2- to C30-olefins, styrene, C1- to C3-alkylstyrenes, C1- to C28-alkyl vinyl ethers, vinyl esters of saturated C1- to C8- carboxylic acids or mixtures of units of these monomers and (b) 50 to 1 mol% of units of amides of monoethylenically unsaturated C3- to C8-carboxylic acids with amide groups of the structure … … in which R = C8- to C28- alkyl, … … R , R = H, CH3, C2H5 R = C1- to C28-alkyl, n = 2 to 100 and R = H, R have K values of 8 to 200, or of salts of these copolymers, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and aqueous liquid detergent compositions which contain these copolymers.

    46.
    发明专利
    未知

    公开(公告)号：DE4239076A1

    公开(公告)日：1994-05-26

    申请号：DE4239076

    申请日：1992-11-20

    Applicant: BASF AG

    Inventor： PERNER JOHANNES DR ,  DIESSEL PAUL ,  GUEMBEL HELMUT DR ,  DENZINGER WALTER ,  HARTMANN HEINRICH DR ,  KRONER MATTHIAS DR

    IPC: C02F5/10 ,  C08L33/02 ,  C08L35/00 ,  C08L51/02 ,  C08L77/04 ,  H04L27/20 ,  C11D3/37 ,  H04B7/00 ,  H04J3/16 ,  H04J3/22 ,  H04J3/24 ,  H04J11/00 ,  H04J13/00 ,  H04J13/18 ,  H04L20060101 ,  H04L1/00 ,  H04L1/08 ,  H04L12/00 ,  H04L27/30 ,  H04L29/06 ,  H04Q7/38

    Abstract: The invention concerns mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids with a molecular weight of 200 to 5,000 and (II) (1) copolymers with a molecular weight of 10,000 to 150,000 consisting of (a) 10 to 70 % by wt. of monoethylenically unsaturated C4 to C8 dicarboxylic acids or salts thereof and (b) 30 to 90 % by wt. of monoethylenically unsaturated C3 to C10 monocarboxylic acids and/or salts thereof, (2) homopolymers and copolymers with a molecular weight of 1,000 to 500,00 consisting of monoethylenically unsaturated C3 to C10 monocarboxylic acids, (3) graft polymers with a molecular weight of 5,000 to 150,000 obtained by the radical-initiated graft polymerization of (A) monoethylenically unsaturated C3 to C10 carboxylic acids, their anhydrides and/or their salts in the presence of (B) mono-, oligo- or polysaccharides derivatives thereof, in the ratio by weight of A:B of (95 to 100):(5 to 80) and/or (4) polyaminocarboxylic acids and/or polymers containing aminocarboxylic groups, the mixtures containing components (I) and (II) in the ratio by weight of 10:0.5 to 0.5:10. The invention also concerns the use of such mixtures as additives in phosphate-free or phosphate-reduced textile-washing agents or as dispersants and deposit-prevention agents in cleaning agents for hard surfaces.

    49.
    发明专利
    未知

    公开(公告)号：ES2048810T3

    公开(公告)日：1994-04-01

    申请号：ES89119547

    申请日：1989-10-21

    Applicant: BASF AG

    Inventor： DIESSEL PAUL ,  PERNER JOHANNES DR ,  DENZINGER WALTER ,  HARTMANN HEINRICH DR ,  RAUBENHEIMER HANS-JURGEN

    IPC: C08F8/14 ,  C08L67/00 ,  C11D3/37

    Abstract: The use of partially esterified copolymers which can be obtained by copolymerisation of (a) at least one C4- to C28-olefin and (b) ethylenically unsaturated dicarboxylic anhydrides with 4 to 8 C atoms in the molar ratio 1:1 and subsequent partial esterification of the copolymers with reaction products of (A) C1- to C30-alcohols, C8- to C22-fatty acids, C1- to C12-alkylphenols or secondary C2- to C30-amines with (B) at least one C2- to C4-alkylene oxide or tetrahydrofuran in the molar ratio (A):(B) of 1:2 to 50 and hydrolysis of the anhydride groups of the copolymers to carboxyl groups, where the partial esterification of the copolymers is continued until more than 5 to 50% of the carboxyl groups in the copolymers are esterified, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and liquid detergent compositions which contain the partially esterified copolymers.

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