42.
    发明专利
    未知

    公开(公告)号:DE59303691D1

    公开(公告)日:1996-10-17

    申请号:DE59303691

    申请日:1993-01-14

    Applicant: BASF AG

    Abstract: Process for the preparation of 2,4,6-trimethylbenzoic acid, of the formula I, by reacting alpha -chloro-2,4,6-trimethylacetophenone with an alkali metal hydroxide solution and chlorine in the presence of a phase-transfer catalyst at temperatures from 0 to 150 DEG C and pressures from 0.01 to 50 bar, and a process for the preparation of the 2,4,6-trimethylbenzoic acid I, in which alpha -chloro-2,4,6-trimethylacetophenone, of the formula II, is prepared by reacting 1,3,5-trimethylbenzene with chloroacetyl chloride in the presence of a catalyst at temperatures from 0 to +150 DEG C and pressures from 0.01 to 50 bar, iron oxides being used as catalyst.

    46.
    发明专利
    未知

    公开(公告)号:DE4202567A1

    公开(公告)日:1993-08-05

    申请号:DE4202567

    申请日:1992-01-30

    Applicant: BASF AG

    Abstract: Process for the preparation of 2,4,6-trimethylbenzoic acid, of the formula I, by reacting alpha -chloro-2,4,6-trimethylacetophenone with an alkali metal hydroxide solution and chlorine in the presence of a phase-transfer catalyst at temperatures from 0 to 150 DEG C and pressures from 0.01 to 50 bar, and a process for the preparation of the 2,4,6-trimethylbenzoic acid I, in which alpha -chloro-2,4,6-trimethylacetophenone, of the formula II, is prepared by reacting 1,3,5-trimethylbenzene with chloroacetyl chloride in the presence of a catalyst at temperatures from 0 to +150 DEG C and pressures from 0.01 to 50 bar, iron oxides being used as catalyst.

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