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    53.
    发明专利
    未知

    公开(公告)号：DE50200760D1

    公开(公告)日：2004-09-09

    申请号：DE50200760

    申请日：2002-03-06

    Applicant: BASF AG

    Inventor： WEIGL HAGEN ,  EBEL KLAUS ,  HUBER SYLVIA ,  KUSCHE ANDREAS ,  ELLER KARSTEN ,  HESSE MICHAEL ,  HOEHN ARTHUR

    IPC: B01J23/89 ,  B01J27/045 ,  B01J37/02 ,  B01J37/20 ,  C07B61/00 ,  C07C31/20 ,  C07D307/28 ,  C07D309/18 ,  C07D319/12

    Abstract: A method for producing unsaturated cyclic ethers of general formula (I) wherein Z represents (CHR )q- or (CHR )q-O-, q 0, 1, 2 or 3 and R , R , R , R represent hydrogen or C1-C4-alkyl, by reacting dioles of general formula (II), wherein Z, R , R and R have the above-mentioned meanings, in a liquid phase at temperatures of 150-300° C. in the presence of a support catalyst which is not activated prior to use by reduction and which contains cobalt and is doped with sulphur, containing cobalt, and an earth metal which is deposited by sol impregnation and is selected from the group containing platinum, palladium, rhodium, iridium, ruthenium, osmium, rhenium or mixtures thereof, on an inert support, characterized in that water is added.

    54.
    发明专利
    未知

    公开(公告)号：AT272444T

    公开(公告)日：2004-08-15

    申请号：AT02722181

    申请日：2002-03-06

    Applicant: BASF AG

    Inventor： WEIGL HAGEN ,  EBEL KLAUS ,  HUBER SYLVIA ,  KUSCHE ANDREAS ,  ELLER KARSTEN ,  HESSE MICHAEL ,  HOEHN ARTHUR

    IPC: B01J23/89 ,  B01J27/045 ,  B01J37/02 ,  B01J37/20 ,  C07B61/00 ,  C07C31/20 ,  C07D307/28 ,  C07D309/18 ,  C07D319/12

    Abstract: A method for producing unsaturated cyclic ethers of general formula (I) wherein Z represents (CHR )q- or (CHR )q-O-, q 0, 1, 2 or 3 and R , R , R , R represent hydrogen or C1-C4-alkyl, by reacting dioles of general formula (II), wherein Z, R , R and R have the above-mentioned meanings, in a liquid phase at temperatures of 150-300° C. in the presence of a support catalyst which is not activated prior to use by reduction and which contains cobalt and is doped with sulphur, containing cobalt, and an earth metal which is deposited by sol impregnation and is selected from the group containing platinum, palladium, rhodium, iridium, ruthenium, osmium, rhenium or mixtures thereof, on an inert support, characterized in that water is added.

    55.
    发明专利
    未知

    公开(公告)号：DE59611017D1

    公开(公告)日：2004-07-01

    申请号：DE59611017

    申请日：1996-07-02

    Applicant: BASF AG

    Inventor： KOENIG HARTMANN ,  GOETZ NORBERT ,  KLEIN ULRICH ,  ELLER KARSTEN

    IPC: C07D231/20 ,  C07D231/22 ,  C07D401/04

    Abstract: PCT No. PCT/EP96/02891 Sec. 371 Date Jan. 8, 1998 Sec. 102(e) Date Jan. 8, 1998 PCT Filed Jul. 2, 1996 PCT Pub. No. WO97/03969 PCT Pub. Date Feb. 6, 1997N-substituted 3-hydroxypyrazoles of the formula I where R1 is unsubstituted or substituted alkyl, aryl or heteroaryl and R2, R3 is hydrogen, cyano, halogen or unsubstituted or substituted alkyl, aryl or heteroaryl, are prepared by oxidation of a corresponding pyrazolidin-3-one with atmospheric oxygen in the presence of a metal salt in an essentially pH-neutral medium.

    57.
    发明专利
    未知

    公开(公告)号：ES2175681T3

    公开(公告)日：2002-11-16

    申请号：ES98907952

    申请日：1998-01-17

    Applicant: BASF AG

    Inventor： SIGWART CHRISTOPH ,  NARBESHUBER THOMAS ,  ELLER KARSTEN ,  BARL MANFRED ,  FISCHER ROLF ,  GEHRER EUGEN

    IPC: C08F4/02 ,  C08F4/20 ,  C08F4/24 ,  C08F10/08 ,  C08F10/10 ,  C08F110/10

    Abstract: A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 50 mol % and an average molecular weight Mn of 280-10000 dalton by the cationic polymerization in the liquid phase of isobutene or hydrocarbon mixtures comprising isobutene comprises polymerizing at from -30° C. to +40° C. in the presence of a heterogeneous polymerisation catalyst comprising one or more oxides of the elements of transition groups V and VI of the Periodic Table of the Elements or in the presence of a heterogeneous polymerization catalyst comprising one or more oxidic compounds of one or more elements of transition groups V and VI of the Periodic Table of the Elements supported on a non-zeolitic oxidic support material which is not an oxygen-containing zirconium compound, the catalyst not containing a technically effective amount of halogen.

    59.
    发明专利
    未知

    公开(公告)号：DE59803734D1

    公开(公告)日：2002-05-16

    申请号：DE59803734

    申请日：1998-01-17

    Applicant: BASF AG

    Inventor： SIGWART CHRISTOPH ,  NARBESHUBER THOMAS ,  ELLER KARSTEN ,  BARL MANFRED ,  FISCHER ROLF ,  GEHRER EUGEN

    IPC: C08F4/02 ,  C08F4/20 ,  C08F4/24 ,  C08F10/08 ,  C08F10/10 ,  C08F110/10

    Abstract: A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 50 mol % and an average molecular weight Mn of 280-10000 dalton by the cationic polymerization in the liquid phase of isobutene or hydrocarbon mixtures comprising isobutene comprises polymerizing at from -30° C. to +40° C. in the presence of a heterogeneous polymerisation catalyst comprising one or more oxides of the elements of transition groups V and VI of the Periodic Table of the Elements or in the presence of a heterogeneous polymerization catalyst comprising one or more oxidic compounds of one or more elements of transition groups V and VI of the Periodic Table of the Elements supported on a non-zeolitic oxidic support material which is not an oxygen-containing zirconium compound, the catalyst not containing a technically effective amount of halogen.

    60.
    发明专利
    未知

    公开(公告)号：DE59802631D1

    公开(公告)日：2002-02-21

    申请号：DE59802631

    申请日：1998-02-20

    Applicant: BASF AG

    Inventor： BECKER RAINER ,  ELLER KARSTEN ,  LANGENSIEPEN HANS-WERNER ,  HESSE MICHAEL

    IPC: C07C211/51 ,  A61K9/12 ,  B01J21/16 ,  C07B61/00 ,  C07C209/54 ,  C07C209/68 ,  C07C209/78 ,  C07C211/50 ,  C07C211/54

    Abstract: Production of aromatic polyamine mixtures contg. cpds. of formula: H2NACH2BNH2(I) (where, A and B = 1,4-phenylene residues which can have 1-4 substits. chosen from 1-20C alkyls and halogens) comprises converting a cpd. of formula: HANHCH2NHBH (IV) and/or a cpd. of formula HANHCH2BNH2 (V) (where, A and B = as above) at a temp. of 20-200[deg]C in the presence of a heterogeneous inorganic catalyst chosen from: (a) oxides of 3-10 group element which can be acid-activated; (b) a clay doped with an oxide of a 2-13 group element or lanthanide which an be acid-activated; and (c) opt. acid-activated layered silicates acidity of below pK3 = 0.5 of more than 0.05 mmol/g catalyst. -

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