公开(公告)号：DE19852282A1

公开(公告)日：2000-05-18

申请号：DE19852282

申请日：1998-11-13

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  SIMON JOACHIM ,  HOEHN ARTHUR ,  KRAMER ANDREAS ,  FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUEBLING CHRISTOPH

IPC: C07C209/68 ,  C07C213/08 ,  C07C217/08 ,  C07B55/00 ,  C07C209/00

Abstract: The racemization of optically active, optionally substituted aliphatic secondary amines (I) by contacting with hydrogen and a (de)hydrogenation catalyst is carried out in the gas phase. Racemization of optically active amines (I) involves contacting (I), in the gas phase, with hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperatures. R1 = H, alkyl, cycloalkyl, aralkyl, aryl, heteroaryl or heterocyclyl (all optionally substituted by alkyl, cycloalkyl, alkoxy, aryloxy, alkylamino or dialkylamino); with the proviso that R1 and R2 are different. R2, R3 = alkyl, cycloalkyl, aralkyl, aryl, heteroaryl or heterocyclyl (all optionally substituted by alkyl, cycloalkyl, alkoxy, aryloxy, alkylamino or dialkylamino);

公开(公告)号：NO324896B1

公开(公告)日：2007-12-27

申请号：NO20013912

申请日：2001-08-10

Applicant: BASF AG

Inventor： HOHN ARTHUR ,  RIECHERS HARTMUT ,  SIMON JOACHIM ,  KRAMER ANDREAS ,  FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUEBLING CHRISTOPH

IPC: B01J23/755 ,  C07C209/68 ,  C07B55/00 ,  C07B57/00 ,  C07B61/00 ,  C07C209/88 ,  C07C211/03 ,  C07C213/02 ,  C07C213/08 ,  C07C217/08

Abstract: A process for the preparation of racemic amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III and the amine of the formula R3NH2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.

公开(公告)号：DE50308078D1

公开(公告)日：2007-10-11

申请号：DE50308078

申请日：2003-08-06

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/54 ,  C07C209/84 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：AT371638T

公开(公告)日：2007-09-15

申请号：AT03790870

申请日：2003-08-06

Applicant: BASF AG

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/54 ,  C07C209/84 ,  C07B61/00 ,  C07C29/68 ,  C07C209/82 ,  C07C209/86 ,  C07C211/36

Abstract: Pure isophorone-diamine (IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 is obtained by (a) making crude IPDA with a CTR below 73/27, (b) purifying and separating into fractions with CTR of at least 73/27 (b1) and below 63/37 (b2), (c) isomerizing (b2) in presence of hydrogen, ammonia and catalyst to give IPDA with a CTR of 63/37-66/34 which is recycled to stage (a). A method (M1) for the production of substantially pure 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone-diamine; IPDA) with a cis/trans isomer ratio (CTR) of at least 73/27 involves: (a) preparation of crude IPDA with a CTR of less than 73/27, (b) purification and separation to give fractions (b1) with a CTR of at least 73/27 and (b2) with a CTR of less than 63/27 and (c) isomerization of (b2) in presence of hydrogen, ammonia and a hydrogenation catalyst to give IPDA with a CTR of 63/37-66/34 which is then recycled to stage (a). An Independent claim is also included for a method (M2) for the production of IPDA with a CTR in the range 63/37 to 66/34 by reacting IPDA with any CTR value with hydrogen and ammonia in presence of a hydrogenation catalyst.

公开(公告)号：DE50208807D1

公开(公告)日：2007-01-04

申请号：DE50208807

申请日：2002-11-08

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  BOEHLING RALF ,  FUNKE FRANK ,  HARDER WOLFGANG

IPC: B01J31/26 ,  C07C209/00 ,  B01J31/02 ,  C07B61/00 ,  C07C209/60 ,  C07C211/03 ,  C07C211/35 ,  C07C211/65 ,  C07F1/00 ,  C07F1/02 ,  C07F1/04 ,  C07F1/06

Abstract: A process for preparing dialkylamides of the alkali metals by reacting the corresponding dialkylamine with the corresponding alkali metal in the presence of an electron-donating substance selected from the group consisting of 1,3-butadiene, isoprene, naphthalene and styrene with formation of small amounts of butenyldialkylamine comprises suspending the corresponding alkali metal in a solvent and subsequently adding dialkylamine and electron-donating substance in such a way that the dialkylamine is present in an amount of up to 45% by weight, preferably up to 25% by, weight, in particular up to 15% by weight, and the butadiene is present in an amount of up to 5% by weight, preferably up to 3% by weight, in particular up to 1.5% by weight.

公开(公告)号：BRPI0414662A

公开(公告)日：2006-11-21

申请号：BRPI0414662

申请日：2004-09-24

Applicant: BASF AG

Inventor： SIEMENSMEYER KARL ,  GIBS STEFFEN ,  FUNKE FRANK ,  BASTIAN ANDREAS ,  GOTSCHE MICHAEL ,  HEISSLER HEINZ ,  CARNAHAN JAMES DAVID ,  SCHNEIDER TANJA ,  SCHOEPKE HOLGER ,  FRENZEL STEFAN

IPC: D06M15/356 ,  D06P1/52 ,  D06P3/60 ,  D06P3/62 ,  D06P3/66

公开(公告)号：DE10261194A1

公开(公告)日：2004-07-01

申请号：DE10261194

申请日：2002-12-20

Applicant: BASF AG

Inventor： GERLACH TILL ,  FUNKE FRANK ,  MELDER JOHANN-PETER

IPC: B01J23/755 ,  C07B31/00 ,  C07B35/02 ,  C07B41/02 ,  C07B43/04 ,  C07B61/00 ,  C07C5/03 ,  C07C5/08 ,  C07C9/02 ,  C07C27/04 ,  C07C29/14 ,  C07C29/143 ,  C07C31/02 ,  C07C209/26 ,  C07C209/44 ,  C07C209/48 ,  C07C211/01 ,  C07C211/04

公开(公告)号：AU2003294749A1

公开(公告)日：2004-06-23

申请号：AU2003294749

申请日：2003-11-28

Applicant: BASF AG

Inventor： BAUM PIA ,  KULZER NICOLA ULRIKE ,  FUNKE FRANK ,  BASTIAN ANDREAS ,  RINGELSBACHER MARKUS ,  HEISSLER HEINZ ,  REUTHER GERHARD ,  KONRAD ROUVEN ,  CARNAHAN JAMES DAVID ,  SIEMENSMEYER KARL ,  POTTHOFF-KARL BIRGIT ,  SCHNEIDER TANJA ,  MULLER JOHANN

IPC: D06P1/52 ,  D06P1/60 ,  D06P5/08 ,  D06P5/13 ,  D06P1/08

Abstract: The use of copolymers containing units derived from at least 2 monoethylenically unsaturated monomers B1 and B2 which each contain at least one nitrogenous heterocycle, as auxiliaries for textile dyeing and textile printing.

公开(公告)号：AU2003294692A8

公开(公告)日：2004-05-04

申请号：AU2003294692

申请日：2003-10-14

Applicant: BASF AG

Inventor： NARBESHUBER THOMAS ,  BOTTKE NILS ,  PRINZ MARTINA ,  STEPHAN JURGEN ,  STEINBRENNER ULRICH ,  BENFER REGINA ,  MAAS HEIKO ,  HEIDEMANN THOMAS ,  FUNKE FRANK ,  TROPSCH JURGEN

IPC: C07C29/17 ,  C07C303/06 ,  C07C303/08 ,  C07C309/31 ,  C07C9/16 ,  C07C15/107 ,  C07C31/125 ,  C11D1/24

公开(公告)号：AU769005B2

公开(公告)日：2004-01-15

申请号：AU4140899

申请日：1999-05-10

Applicant: BASF AG

Inventor： RIECHERS HARTMUT ,  SIMON JOACHIM ,  HOEHN ARTHUR ,  KRAMER ANDREAS ,  FUNKE FRANK ,  SIEGEL WOLFGANG ,  NUEBLING CHRISTOPH

IPC: B01J23/755 ,  C07B55/00 ,  C07B57/00 ,  C07B61/00 ,  C07C209/68 ,  C07C209/88 ,  C07C211/03 ,  C07C213/02 ,  C07C213/08 ,  C07C217/08

Abstract: A process for the preparation of racemic amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III and the amine of the formula R3NH2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.