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公开(公告)号:DE4223807A1
公开(公告)日:1994-01-27
申请号:DE4223807
申请日:1992-07-20
Applicant: BASF AG
Inventor: BOECKH DIETER DR , FUNHOFF ANGELIKA DR , KRONER MATTHIAS DR , HARTMANN HEINRICH DR , BAUR RICHARD DR , KUD ALEXANDER DR , SCHWENDEMANN VOLKER DR
IPC: C07C229/22 , C07C235/10 , C07C235/12 , C07D317/34 , C08B31/04 , C08G16/00 , C08G63/91 , C08G69/00 , C08G69/50 , C08G73/02 , C11D3/16 , C11D3/37 , C08G73/00 , C08F8/16
Abstract: The invention concerns condensation products containing N,O-acetal- or carbonamide structures, the products being characterized in that they are obtained by the condensation of (a) compounds containing at least once the structural element (I) or (II) in which X=OH or NHR, R being C1 to C6 alkyl or -CH2-COOH, with (b) aldehydes, ketones or aldehydic or ketonic carboxylic acids to give acetal lactones and by subsequently splitting the acetal lactones with (c) aminocarboxylic acids, primary or secondary amines and/or polyethylenimines to give condensation products containing N,O-acetal- or carbonamide structures. The invention also concerns methods of preparing such products and their use as additives in washing and cleaning agents. The invention further concerns condensation products containing acetal lactone structures produced by reacting (a) hydroxycarboxylic acids or secondary aminoacids with polyhydroxy compounds and condensing with (b) aldehydes, ketones or aldehydic or ketonic carboxylic acids.
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公开(公告)号:DE4221875A1
公开(公告)日:1994-01-05
申请号:DE4221875
申请日:1992-07-03
Applicant: BASF AG
Inventor: KRONER MATTHIAS DR , HARTMANN HEINRICH DR , BOECKH DIETER DR , FUNHOFF ANGELIKA DR , BAUR RICHARD DR , KUD ALEXANDER DR , SCHWENDEMANN VOLKER DR , POTTHOFF-KARL BIRGIT DR , BUECHNER KARL-HEINZ
IPC: C02F5/12 , C08F222/00 , C08F267/00 , C08F283/04 , C08G69/10 , C08G73/10 , C11D3/37 , C13B25/00 , C13B30/02 , C08G69/36 , C08G69/44 , C02F5/10 , C13F1/00
Abstract: Modified polyaspartic acids are obtained by polycondensing (a) 1 to 99.9 mol % aspartic acid with (b) 99 to 0.1 mol % fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic polyhydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugar carboxylic acids and/or non-proteinogenic aminocarboxylic acids, or by polymerising monoethylenically unsaturated monomers in the presence of polyaspartic acids, in the manner of radically initiated graft copolymerisation. Also disclosed is a process for preparing these modified polyaspartic acids, as well as the use of these modified polyaspartic acids as additives to washing and cleaning agents, as water conditioning agents and as deposit inhibitors during the condensation of sugar juice.
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公开(公告)号:DE4217847A1
公开(公告)日:1993-12-02
申请号:DE4217847
申请日:1992-05-29
Applicant: BASF AG
Abstract: The invention concerns the use of condensation products of aspartic acid, as well as the alkali-metal salts and ammonium salts of such condensation products, as deposit-prevention agents in the concentration of sugar juices.
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公开(公告)号:DE4142130A1
公开(公告)日:1993-06-24
申请号:DE4142130
申请日:1991-12-20
Applicant: BASF AG
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公开(公告)号:ES2289025T3
公开(公告)日:2008-02-01
申请号:ES02009116
申请日:2002-04-24
Applicant: BASF AG
Inventor: KRONER MATTHIAS DR , BUCHNER KARL-HEINZ , BRODT GREGOR DR
IPC: C04B7/52 , C08G65/332 , C04B24/26 , C04B24/32 , C04B103/52 , C08F2/10 , C08F2/38 , C08F6/10 , C08F8/00 , C08F20/28 , C08F290/06 , C08L71/02
Abstract: Empleo de polímeros hidrosolubles de ésteres de ácido acrílico y alquilpolialquilenglicoles, que son obtenibles mediante esterificado azeótropo de una mezcla de ácido acrílico y alquilpolialquilenglicol en proporción molar de 2 a 3 : 1 en presencia de un disolvente orgánico, que forma un azeótropo con agua, en al menos un 85 % en peso, referido al alquilpolialquilenglicol, y su siguiente polimerización a través de radicales de la mezcla obtenida en el esterificado en medio acuoso, destilándose el disolvente orgánico de la mezcla de reacción por vía azeótropa durante la polimerización, y devolviéndose el agua destilada a la mezcla, o substituyéndose mediante alimentación de agua fresca, como agente auxiliar de molturado para sistemas de cemento.
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公开(公告)号:DE50210438D1
公开(公告)日:2007-08-23
申请号:DE50210438
申请日:2002-04-24
Applicant: BASF AG
Inventor: KRONER MATTHIAS DR , BUECHNER KARL-HEINZ , BRODT GREGOR DR
IPC: C04B7/52 , C08G65/332 , C04B24/26 , C04B24/32 , C04B103/52 , C08F2/10 , C08F2/38 , C08F6/10 , C08F8/00 , C08F20/28 , C08F290/06 , C08L71/02
Abstract: Water-soluble polymers (I) of esters of acrylic acid (II) and alkyl-polyalkylene glycols (III) are obtained by a method involving azeotropic esterification of (II) and (III) in presence of organic solvent followed by radical polymerisation of the mixture with removal of solvent by azeotropic distillation and replacement of the lost water. Water-soluble polymers (I) of esters of acrylic acid (II) and alkylpolyalkylene glycols (III), obtained by azeotropic esterification of a mixture of (II) and (III) in a mol ratio of (2-3):1 in presence of at least 85 wt% (based on III) of an organic solvent which forms an azeotrope with water, followed by radical polymerisation of the resulting mixture with azeotropic distillation to remove the solvent and with replacement of lost water by recycling or by the addition of fresh water. An Independent claim is also included for a method for the production of (I) as described above.
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公开(公告)号:DE19647609A1
公开(公告)日:1998-05-20
申请号:DE19647609
申请日:1996-11-18
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , JAEGER HANS-ULRICH DR , KAHMEN MARTIN AUS DEM DR , KRONER MATTHIAS DR , LUX JUERGEN ALFRED DR , OETTER GUENTER DR
Abstract: Use of 0.1-10 wt.% of at least trihydric alcohol and their reaction products with ethylene oxide (EO) and/or propylene oxide (PO) as additive to increase the rate of dissolution of particulate laundry detergent formulations in water.
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公开(公告)号:DE19631380A1
公开(公告)日:1998-02-05
申请号:DE19631380
申请日:1996-08-02
Applicant: BASF AG
Inventor: NGUYEN KIM SON DR , SANNER AXEL DR , HOESSEL PETER DR , KRONER MATTHIAS DR
IPC: A61K8/00 , A61K8/04 , A61K8/34 , A61K8/41 , A61K8/64 , A61K8/81 , A61K8/88 , A61K8/89 , A61K8/891 , A61Q5/00 , A61Q5/02 , A61Q5/12 , C08G73/10 , C08G69/48 , C08G69/10 , C08G73/14 , A61K7/06 , A61K7/11
Abstract: Water soluble and/or dispersible polyaspartic acid derivatives of formula (I) or their (poly)carboxylic acid salts or quat. derivatives are claimed. In (I), (x1 + x2) = 30-99.9; (y1 + y2) = 0.1-70; z = 0-20; A = at least one prim., sec. or tert. 2-6C alkyl amine, optionally with 1-3 substituents chosen from OH or alkoxy on the alkyl groups, at least one diamine of formula (R )(R )N(CH2)mN(R )(R ) (II) (where m = 2-6; R , R = H or alkyl; R , R = alkyl or they combine with the N atom to which they are bonded to form a 5-7 membered saturated heterocyclic ring of formula (III) (where n', o' = 1-5; X' = CH2, S, O, NR = H or alkyl)) or at least one cyclic diamine of formula (III) (where n, o = 1-5; X = NR (where R = H or alkyl)); B = at least one amine of formula R Y(CH2)pN(R )(R ) (IV) (where the group R -Y-(CH2)p contains 6-24C atoms; p = 1-23; Y = CH2, O, N, CONH (in which the CO group is bonded to R ) or N-COR ; R = H or (un)saturated fatty acid hydrocarbon; R , R = H, (hydroxy)alkyl or -ÄCH2-CH2-OÜrH (where r = 1-30; R = alkyl)); C = at least one derivative of a prim. or sec. amine (A) with an amino H atom removed; and D = at least one derivative of a prim. or sec. amine (B) with an amino H atom removed, with the provision that x1 + x2 + y1 + y2+ z = 100 and at least one amine (A) or (B) contains a tert. amino group. Also claimed are: (i) the preparation of (I) by reacting polyaspartic acid or polysuccinimide with at least one amine (A) and at least one amine (B) and (ii) hair treatment products containing at least one compound (I).
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公开(公告)号:DE19620364A1
公开(公告)日:1997-11-27
申请号:DE19620364
申请日:1996-05-22
Applicant: BASF AG
Inventor: HUFF JUERGEN DR , JAEGER HANS-ULRICH DR , KAHMEN MARTIN AUS DEM DR , KRONER MATTHIAS DR , LUX JUERGEN ALFRED DR , OETTER GUENTER DR
Abstract: The invention concerns the use of at least trivalent alcohols and their reaction products with ethylene oxide and/or propylene oxide as additives to particulate detergent formulations, in particular compact detergents, for increasing the speed of dissolution of the detergent formulations in water in amounts of between 0.1 and 5 wt %, relative to the detergent formulations.
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公开(公告)号:DE19532715A1
公开(公告)日:1997-03-06
申请号:DE19532715
申请日:1995-09-05
Applicant: BASF AG
Inventor: BOECKH DIETER DR , FUNHOFF ANGELIKA DR , JAEGER HANS-ULRICH DR , SCHADE CHRISTIAN DR , STEIN STEFAN DR , RAU IRIS DR , DENZINGER WALTER , KRONER MATTHIAS DR
Abstract: Washing agents based on surfactants, organic co-builders and polymeric dye transfer inhibitors, in which (a) the organic co-builder is a polymeric polycarboxylate with a Mw of up to 25,000 and (b) the dye transfer inhibitor is a water-soluble polymeric dye transfer inhibitor with a Mw of at least 30,000 and/or a water-insoluble crosslinked polymeric dye transfer inhibitor with a particle size of 0.1 - 500 mu m.
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