公开(公告)号：DE59602419D1

公开(公告)日：1999-08-19

申请号：DE59602419

申请日：1996-04-24

Applicant: BASF AG

Inventor： ETTL ROLAND ,  KASEL WOLFGANG ,  FANKHAENEL MATTHIAS ,  REUTHER WOLFGANG

IPC: C07C45/89 ,  C07C49/88 ,  C07D305/12

公开(公告)号：AT180526T

公开(公告)日：1999-06-15

申请号：AT96908139

申请日：1996-03-26

Applicant: BASF AG

Inventor： ETTL ROLAND ,  LORENCAK PRIMOZ ,  REUTHER WOLFGANG ,  BONN JOHANN ,  DE CLERCQ ARNOLD

IPC: D21H17/03 ,  D21H17/17 ,  D21H17/28 ,  D21H17/29 ,  D21H21/16 ,  D21H17/72

公开(公告)号：AU6623098A

公开(公告)日：1998-10-12

申请号：AU6623098

申请日：1998-02-23

Applicant: BASF AG

Inventor： ETTL ROLAND ,  SCHUHMACHER RUDOLF ,  BONN JOHANN ,  REUTHER WOLFGANG ,  UTECHT JENS ,  JULIUS MANFRED

IPC: C08G73/02 ,  D21H17/16 ,  D21H17/17 ,  D21H17/54 ,  D21H21/16

公开(公告)号：CA2231541A1

公开(公告)日：1997-05-15

申请号：CA2231541

申请日：1996-10-25

Applicant: BASF AG

Inventor： REUTHER WOLFGANG ,  ETTL ROLAND ,  LORENCAK PRIMOZ ,  BONN JOHANN

IPC: C07C45/90 ,  C07C49/88 ,  C09K23/00 ,  D06M13/13 ,  D06M15/11 ,  D21H17/09 ,  D21H17/10 ,  D21H17/17 ,  D21H17/23 ,  D21H17/29 ,  D21H21/16 ,  D21H17/72

Abstract: The invention concerns aqueous alkyldiketene dispersions containing an alkyldiketene, cationic starch with an amylopectin content of at least 95 % by wt. and the following anionic dispersants: (a) 0.05 to 1.0 % by wt. of lignin sulphonic acid, condensation products of naphtalene sulphonic acid and formaldehyde, sulphonated polystyrene or salts or mixtures of such polymers and (b) 0.05 to 1.5 % by wt. of sulphuric acid half esters of alcohols with at least 10 C-atoms, mono- or diphosphoric acid half esters of alkoxylated alcohols with at least 10 C-atoms, sulphuric acid half esters of alkoxylated alcohols with at least 10 C-atoms, mono- or diphosphoric acid esters of alkoxylated alcohols with at least 10 C-atoms, C12-C30 alkyl sulphonic acids or salts or mixtures of such compounds. The invention also concerns the use of such alkyldiketene dispersions as bulk size in the manufacture of paper, paperboard and cardboard, as well as in making cellulose fibres waterrepellent.

公开(公告)号：CA2230827A1

公开(公告)日：1997-03-27

申请号：CA2230827

申请日：1996-09-13

Applicant: BASF AG

Inventor： GULBINS ERICH ,  RAU MARIA GYOPAR ,  WIRTH THOMAS ,  MELDER JOHANN-PETER ,  KOKEL NICOLAS ,  ETTL ROLAND ,  LARBIG HARALD

IPC: C08L75/04 ,  C08G18/08 ,  C08G18/12 ,  C08G18/38 ,  C08G18/40 ,  C08G18/50 ,  C08G18/83 ,  C09D175/04 ,  C14C11/00 ,  C08G18/65 ,  C09D11/10

Abstract: The invention concerns aqueous dispersions containing a polyurethane (A), containing structural units derived from compounds of formula (I), in which the substituents have the following meanings: R1, R2, R3 each designate hydrogen, C1-C24 alkyl or C6 - C24 alkenyl; R4 designates hydrogen; R5, R6 a) together designate C4-C10 alkane-diyl, b) each designate C2-C10 alkyl, C5-C8 cycloalkyl or C7-C20 aralkyl, c) each designate a hydroxyl-terminated poly(C2C4 alkylene oxide), or d) designate an R5 or R6 group with the meaning given in (a) to (c) and the other group designating hydrogen or a group of formula (II), in which X designates C2-C6 alkane-diyl; and R7 has the same meaning as R5 or R6 with the exception that R7 is not a group of formula II, R5 and R6 carrying a total of between 2 and 5 hydroxyl groups bonded to aliphatic carbon atoms; and R5 and/or R6 optionally carrying 1 or 2 aromatically bonded hydroxyl groups or 1 nitrile, tertiary amino, carboxylic acid or sulphonic acid group which are optionally present in the form of their salts.

公开(公告)号：NO933099L

公开(公告)日：1994-03-02

申请号：NO933099

申请日：1993-08-31

Applicant: BASF AG

Inventor： CLERCQ ARNOLD DE ,  ETTL ROLAND ,  GONCALVES CARLOS ALBERTO ,  HOEHR LOTHAR ,  HOHMANN ANDREAS ,  RIEBELING ULRICH

IPC: D21H17/17 ,  D21H17/29 ,  D21H21/16

Abstract: PCT No. PCT/EP93/02259 Sec. 371 Date Mar. 1, 1995 Sec. 102(e) Date Mar. 1, 1995 PCT Filed Aug. 23, 1993 PCT Pub. No. WO94/05855 PCT Pub. Date Mar. 17, 1994.Paper size mixtures which are prepared by mixing an aqueous suspension of a digested cationic starch with a finely divided, aqueous polymer dispersion which is the paper size and emulsifying the C14-C22-alkyldiketene in this mixture at not less than 70 DEG C. are used for engine and surface sizing of the paper.

公开(公告)号：AT380206T

公开(公告)日：2007-12-15

申请号：AT05750531

申请日：2005-06-03

Applicant: BASF AG

Inventor： KUKULA HILDEGARD ,  ETTL ROLAND ,  DYLLICK-BRENZINGER RAINER ,  STURM BERNHARD

IPC: C08F212/08 ,  C08F2/06 ,  C08F212/10 ,  C08F220/34 ,  C08F220/36 ,  C08F220/60 ,  C08F257/02 ,  C14C11/00 ,  D21H11/14 ,  D21H17/37 ,  D21H17/45 ,  D21H21/16

Abstract: Finely divided, amphoteric, aqueous polymer dispersions which are obtainable by a two-stage polymerization, a prepolymer being prepared in the first polymerization stage from a monomer mixture comprising (a) from 15 to 40% by weight of at least one (meth)acrylate and/or (meth)acrylamide having in each case a free amino group, protonated amino group and/or quaternized amino group, (b) from 40 to 70% by weight of at least one optionally substituted styrene, (c) from 0 to 25% by weight of acrylonitrile and/or methacrylonitrile, (d) from 0.5 to 5% by weight of at least one ethylenically unsaturated monomer comprising acid groups and (e) from 0 to 30% by weight of at least one nonionic, ethylenically unsaturated monomer differing from (b) and (c), the sum of (a)+(b)+(c)+(d)+(e) being 100% by weight, in a solution polymerization in a solvent partly to completely miscible with water, water then being added to the solution/dispersion of the prepolymer and then at least one nonionic, ethylenically unsaturated monomer being subjected to an emulsion polymerization in the aqueous solution of the prepolymer in a second polymerization stage, processes for the preparation of the polymer dispersions by two-stage polymerization and use of the polymer dispersions as sizes for paper, board and cardboard.

公开(公告)号：DE102005030789A1

公开(公告)日：2007-01-11

申请号：DE102005030789

申请日：2005-06-29

Applicant: BASF AG

Inventor： BROCKMEYER ANDREAS ,  STEIN HILDEGARD ,  ETTL ROLAND

IPC: C08L33/02 ,  C08F2/28 ,  C08F2/44 ,  C08F212/08 ,  C08F220/10 ,  C08J3/05 ,  C08L3/02 ,  C09D4/02 ,  C09D5/02 ,  C09D103/02 ,  C09D133/02 ,  D21H17/20

Abstract: Finely divided, starch-containing polymer dispersions which are obtainable by free radical emulsion copolymerization of (a) from 25 to 50% by weight of at least one optionally substituted styrene, methyl methacrylate, acrylonitrile and/or methacrylonitrile, (b) from 1 to 49% by weight of at least one C1-C4-alkyl acrylate and/or one C2-C4-alkyl methacrylate, (c) from 1 to 49% by weight of at least one C5-C22-alkyl acrylate and/or one C5-C22-alkyl methacrylate and (d) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer and (e) from 15 to 40% by weight of a degradable starch which has a molar mass Mw of from 1000 to 65 000 the sum (a)+(b)+(c)+(d)+(e) being 100% and being based on the total solids content, in the presence of redox initiators and at least 0.01% by weight, based on the monomers used, of at least one polymerization regulator, processes for the preparation of the finely divided, starch-containing polymer dispersions by emulsion polymerization of the monomers (a), (b), (c) and (d) with redox initiators in the presence of (e) degraded starch and at least 0.01% by weight, based on the monomers used, of at least one polymerization regulator, and use of the finely divided, starch-containing polymer dispersions as sizes for paper, board and cardboard.

公开(公告)号：ES2257686T3

公开(公告)日：2006-08-01

申请号：ES03747101

申请日：2003-04-15

Applicant: BASF AG

Inventor： ETTL ROLAND ,  HAMERS CHRISTOPH ,  SCHMIDT-THUMMES JURGEN

IPC: C08F4/40 ,  C08F212/08 ,  C08F236/04 ,  C08F251/00 ,  C08F251/02 ,  C08L51/02 ,  C09D151/02 ,  D21H17/35 ,  D21H21/16

Abstract: Dispersiones poliméricas acuosas a base de copolímeros de compuestos aromáticos de vinilo y butadieno, caracterizadas porque pueden obtenerse mediante copolimerización iniciada por radicales de (a) del 0, 1 al 99, 9% en peso de estireno y/o metilestireno, (b) del 0, 1 ¿ 99, 9% en peso de butadieno-1, 3 y/o isopreno y (c) del 0 al 40% en peso de otros monómeros copolimerizables etilénicamente insaturados, ascendiendo la suma de los monómeros (a), (b) y (c) siempre a 100, en presencia de desde el 10 hasta el 40% en peso, con respecto a los monómeros utilizados, de al menos un almidón degradado con un peso Mn molecular de desde 500 hasta 40.000 y de catalizadores redox solubles en agua, utilizando como catalizador redox una combinación de peróxido de hidrógeno y de al menos una sal de metal pesado de la serie de las sales de cerio, de manganeso y de hierro (II).

公开(公告)号：DE50302436D1

公开(公告)日：2006-04-20

申请号：DE50302436

申请日：2003-04-15

Applicant: BASF AG

Inventor： ETTL ROLAND ,  HAMERS CHRISTOPH ,  SCHMIDT-THUEMMES JUERGEN

IPC: C08F4/40 ,  C08F251/00 ,  C08F212/08 ,  C08F236/04 ,  C08F251/02 ,  C08L51/02 ,  C09D151/02 ,  D21H17/35 ,  D21H21/16

Abstract: Aqueous polymer dispersions which are obtainable by free radical copolymerization of (a) from 0.1 to 99.9% by weight of styrene and/or methylstyrene, (b) 0.1-99.9% by weight of 1,3-butadiene and/or isoprene and (c) from 0 to 40% by weight of other ethylenically unsaturated copolymerizable monomers, the sum of the monomers (a), (b) and (c) always being 100, in the presence of from 10 to 40% by weight, based on the monomers used, of at least one degraded starch having a molecular weight Mn of from 500 to 40 000 and of water-soluble redox catalysts are prepared by free radical copolymerization of the monomers (a), (b) and, if required, (c) in an aqueous medium in the presence of a degraded starch having a molecular weight Mn of from 500 to 10 000 and redox initiators and are used as engine sizes and surface sizes for paper.