BIODEGRADABLE POLYMERS, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN PRODUCING BIODEGRADABLE MOULDINGS

    公开(公告)号:HU222853B1

    公开(公告)日:2003-12-29

    申请号:HU9701858

    申请日:1995-06-27

    Applicant: BASF AG

    Abstract: The following are claimed: (A) biodegradable polyester P1, preparable by reaction of a mixt. comprising: (a1) a mixt. comprising: (a11) 35-95 mol.% of adipic acid and/or one or more ester-forming derivs. of this, (a12) 5-65 mol.% of terephthalic acid and/or one or more ester-forming derivs. of this, and (a13) 0-5 mol.% of a cpd. contg. sulphonate gps., the total of mol.% in (a11)-(a13) being 100 mol.%; and (a2) a dihydroxy cpd. selected from 2-6C alkane-diols and 5-10C cycloalkane-diols. The molar ratio of (a1) to (a2) is 0.4-1.5:1. In addn., 0.01-5 mol.% (based on the molar amt. of component (a1)) of a cpd. D, which comprises at least three gps. capable of forming ester gps., are also used for prodn. of polyester P1. Polyester P1 has (a) a mol.wt. (Mn) of 5000-50000 g/mol; (b) a viscosity no. of 30-350 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a P1 concn. of 0.5 wt.%); and (c) a m.pt. of 50-170 degrees C. (B) biodegradable polyester P2, preparable by reaction of a mixt. comprising: (b1) mixt. comprising: (b11) 20-95 mol.% of adipic acid and/or one or more ester-forming deriv. of this, (b12) 5-80 mol.% of terephthalic acid and/or one or more ester- forming deriv. of this, and (b13) 0-5 mol.% of a cpd. contg. sulphonate gps., the total of mol.% in (b11)-(b13) being 100 mol.%; (b2) a dihydroxy cpd. as (a2) above; (b3) 0.01-100 wt.% (based on the amt. of component (b1) of a hydroxycarboxylic acid B1 which is of formula (Ia) or (Ib); and (b4) 0-5 mol.% (based on the amt. of component (b1)) of a cpd. D. The molar ratio of (b1) to (b2) is 0.4-1.25:1. Polyester P2 has (a) a mol.wt. (Mn) of 5000-80000 g/mol; (b) a viscosity no. of 30 - 450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a P2 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. p = a whole no. from 1-1500; r = a whole no. from 1-4; G = phenylene, (CH2)k, C(R)H and C(R)HCH2; k = 1-5; R = Me or Et. (C) biodegradable polyester Q1 which have: (a) a mol.wt. (Mn) of 5000-100000 g/mol; (b) a viscosity no. of 30-450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a Q1 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. Q1 are obtained by reaction of a mixt. comprising; (c1) polyester P1 and/or a polyester PWD; (c2) 0.01-50 wt.% (based on (c1)) of a hydroxycarboxylic acid B1; and (c3) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of P1 and/or PWD) of a cpd. D. Polyester PWD is obtainable by reaction of components (a1) and (a2) in a molar ratio of (a1) to (a2) of 0.4-1.5:1. Polyester PWD have: (a) a mol.wt. (Mn) of 5000 - 50000 g/mol; (b) a viscosity no. of 30 - 350 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a PWD concn. of 0.5 wt.%); and (c) a m.pt. of 50-170 degrees C. (D) biodegradable polyesters Q2 which have: (a) a mol.wt. (Mn) of 6000 - 60000 g/mol; (b) a viscosity no. of 30-350 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a Q2 concn. of 0.5 wt.%); and (c) a m.pt. of 50-170 degrees C. Q2 are obtained by reaction of a mixt. comprising: (d1) 95-99.9 wt.% of polyester P1 and/or PWD; and (d2) 0.1-50 wt.% of a diisocyanate C1; and (d3) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of P1 and/or PWD) of a cpd. D. (E) biodegradable polymers T1 which have: (a) a mol.wt. (Mn) of 10000 - 100000 g/mol; (b) a viscosity no. of 30-450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a T1 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. T1 are obtd. by reaction of polyester Q1 with (e1) 0.1-5 wt.% (based on the amt. of Q1) of diisocyanate C1 and (e2) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of Q1 via the polyester P1 and/or PWD) of a cpd. D. (F) biodegradable polymers T2 which have: (a) a mol.wt. (Mn) of 10000 - 100000 g/mol/. (b) a viscosity no. of 30-450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a T2 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. T2 are obtained by reaction of polyester Q2 with (f1) 0.01-50 wt.% (based on the amt. of Q2) of hydroxycarboxylic acid B1 and (f2) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of Q2 via the polyester P1 and/or PWD) of a cpd

    Biologically degradable polymers, and biologically degradable molding thermoplastic material as well as use thereof

    公开(公告)号:CZ292145B6

    公开(公告)日:2003-08-13

    申请号:CZ143797

    申请日:1995-06-27

    Applicant: BASF AG

    Abstract: In the present invention there are disclosed biologically degradable polyesters P1 obtainable by reaction of a mixture consisting essentially of: (a1) a mixture consisting essentially of from 45 to 80 mole percent of adipic acid or ester-forming derivatives thereof or mixtures thereof, from 20 to 55 mole percent of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and from 0 to 5 mole percent of a compound containing sulfonate group, whereby the sum of the individual mole percentages being 100 mole percent; and (a2) a dihydroxy compound selected from the group consisting of alkanediols having 2 to 6 carbon atoms and cycloalkane diols containing 5 to 10 carbon atoms. The molar ratio of (a1) to (a2) being chosen within the range from 0.4 : 1 to 1.5 : 1, with the proviso that the polyesters P1 have a molecular weight (Mn) within the range from 5000 to 50,000 g/mole, a viscosity number within the range from 30 to 350 g/ml (as measured in 50:50 w/w o-dichlorobenzene/phenol at a concentration of 0.5 percent by weight of polyester P1 at 25 degC) and a melting point within the range from 50 to 170 degC and with the further proviso that the polyesters P1 are prepared using from 0.01 to 5 mole percent, based on the molar quantity used of component (a1), of a compound D having at least three groups capable of ester formation. The invented biologically degradable polymers are used particularly for manufacture of compostable shaped bodies, further for the preparation of adhesives, biologically degradable mixtures containing polymer according to the present invention and starches as well as for the production of biologically degradable foams.

    73.
    发明专利
    未知

    公开(公告)号:DE19719689A1

    公开(公告)日:1998-11-12

    申请号:DE19719689

    申请日:1997-05-09

    Applicant: BASF AG

    Abstract: The invention relates to a copolymer from the monomers of constituents A to C as indicated below and optionally D, the total weight of which amounts to 100 mol %: a) 20 to 80 mol % of at least one ethylenically unsaturated dicarboxylic acid or an anhydride, ester and/or amide thereof as constituent A; b) 1 to 79 mol % of at least one diketene of general formula (I), wherein R and R independently means hydrogen or C1-30-alkyl as constituent B; c) 1 to 79 mol % of at least one vinyl ester, (meth)acrylic acid alkyl ester, (meth)acrylnitrile or mixtures thereof as constituent C and d) 0 to less than 0.5 mol %, or when at least 20 mol % of constituent C is provided, 0 to 20 mol % of at least one other olefinically unsaturated monomer as component D. The inventive copolymer is used as a flow enhancer in petroleum middle distillates.

    75.
    发明专利
    未知

    公开(公告)号:ES2108519T3

    公开(公告)日:1997-12-16

    申请号:ES95110442

    申请日:1995-07-05

    Applicant: BASF AG

    Abstract: A low viscosity mixt. contains (i) 40-97.5 wt.% of amphiphilic nonionic graft polymer contg.(a) at least 20 wt.% of polyalkylene oxide units or polyvinylpyrrolidone units as the hydrophilic part of the molecule and (b) at least 40% of vinyl ester and/or (meth)acrylic ester units as the hydrophobic part of the molecule, (ii) 2.5-60% of polyalkylene glycol,alkoxylated alcohol, alkylphenol or amine, or 2-10C cpd. with 1-4 OH gps., when Mn of the polymers is not above 2500, as viscosity reducer, and (iii) 0-40% of homogenising or phase stabilising additive comprising (1) water, (2) an 8-25C mono- or di-basic acid, fatty alcohol sulph(on)ate, alkylbenzene sulphonate, sulphonation and/or sulphation prod. of 8-22C alkoxylated alcohol or alkylphenol, alkyl(poly)glucoside with 1-20C in the alkyl gp., mono-, oligo- or poly-saccharide or derivs. obtd. by oxidn. or redn., or (c) mixts. of (1) and (2) in ratio by wt. of 100:1-20:80.

    BIOLOGICALLY DEGRADABLE POLYMERS, PROCESS OF THEIR PREPARATION AND THEIR USE FOR PREPARING BIOLOGICALLY DEGRADABLE SHAPED BODIES

    公开(公告)号:CZ9701437A3

    公开(公告)日:1997-11-12

    申请号:CZ143797

    申请日:1995-06-27

    Applicant: BASF AG

    Abstract: The following are claimed: (A) biodegradable polyester P1, preparable by reaction of a mixt. comprising: (a1) a mixt. comprising: (a11) 35-95 mol.% of adipic acid and/or one or more ester-forming derivs. of this, (a12) 5-65 mol.% of terephthalic acid and/or one or more ester-forming derivs. of this, and (a13) 0-5 mol.% of a cpd. contg. sulphonate gps., the total of mol.% in (a11)-(a13) being 100 mol.%; and (a2) a dihydroxy cpd. selected from 2-6C alkane-diols and 5-10C cycloalkane-diols. The molar ratio of (a1) to (a2) is 0.4-1.5:1. In addn., 0.01-5 mol.% (based on the molar amt. of component (a1)) of a cpd. D, which comprises at least three gps. capable of forming ester gps., are also used for prodn. of polyester P1. Polyester P1 has (a) a mol.wt. (Mn) of 5000-50000 g/mol; (b) a viscosity no. of 30-350 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a P1 concn. of 0.5 wt.%); and (c) a m.pt. of 50-170 degrees C. (B) biodegradable polyester P2, preparable by reaction of a mixt. comprising: (b1) mixt. comprising: (b11) 20-95 mol.% of adipic acid and/or one or more ester-forming deriv. of this, (b12) 5-80 mol.% of terephthalic acid and/or one or more ester- forming deriv. of this, and (b13) 0-5 mol.% of a cpd. contg. sulphonate gps., the total of mol.% in (b11)-(b13) being 100 mol.%; (b2) a dihydroxy cpd. as (a2) above; (b3) 0.01-100 wt.% (based on the amt. of component (b1) of a hydroxycarboxylic acid B1 which is of formula (Ia) or (Ib); and (b4) 0-5 mol.% (based on the amt. of component (b1)) of a cpd. D. The molar ratio of (b1) to (b2) is 0.4-1.25:1. Polyester P2 has (a) a mol.wt. (Mn) of 5000-80000 g/mol; (b) a viscosity no. of 30 - 450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a P2 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. p = a whole no. from 1-1500; r = a whole no. from 1-4; G = phenylene, (CH2)k, C(R)H and C(R)HCH2; k = 1-5; R = Me or Et. (C) biodegradable polyester Q1 which have: (a) a mol.wt. (Mn) of 5000-100000 g/mol; (b) a viscosity no. of 30-450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a Q1 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. Q1 are obtained by reaction of a mixt. comprising; (c1) polyester P1 and/or a polyester PWD; (c2) 0.01-50 wt.% (based on (c1)) of a hydroxycarboxylic acid B1; and (c3) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of P1 and/or PWD) of a cpd. D. Polyester PWD is obtainable by reaction of components (a1) and (a2) in a molar ratio of (a1) to (a2) of 0.4-1.5:1. Polyester PWD have: (a) a mol.wt. (Mn) of 5000 - 50000 g/mol; (b) a viscosity no. of 30 - 350 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a PWD concn. of 0.5 wt.%); and (c) a m.pt. of 50-170 degrees C. (D) biodegradable polyesters Q2 which have: (a) a mol.wt. (Mn) of 6000 - 60000 g/mol; (b) a viscosity no. of 30-350 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a Q2 concn. of 0.5 wt.%); and (c) a m.pt. of 50-170 degrees C. Q2 are obtained by reaction of a mixt. comprising: (d1) 95-99.9 wt.% of polyester P1 and/or PWD; and (d2) 0.1-50 wt.% of a diisocyanate C1; and (d3) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of P1 and/or PWD) of a cpd. D. (E) biodegradable polymers T1 which have: (a) a mol.wt. (Mn) of 10000 - 100000 g/mol; (b) a viscosity no. of 30-450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a T1 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. T1 are obtd. by reaction of polyester Q1 with (e1) 0.1-5 wt.% (based on the amt. of Q1) of diisocyanate C1 and (e2) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of Q1 via the polyester P1 and/or PWD) of a cpd. D. (F) biodegradable polymers T2 which have: (a) a mol.wt. (Mn) of 10000 - 100000 g/mol/. (b) a viscosity no. of 30-450 g/ml (measured in o-dichlorobenzene/phenol (wt. ratio 50/50) at 25 degrees C and a T2 concn. of 0.5 wt.%); and (c) a m.pt. of 50-235 degrees C. T2 are obtained by reaction of polyester Q2 with (f1) 0.01-50 wt.% (based on the amt. of Q2) of hydroxycarboxylic acid B1 and (f2) 0-5 mol.% (based on the amt. of component (a1) used in prodn. of Q2 via the polyester P1 and/or PWD) of a cpd

    78.
    发明专利
    未知

    公开(公告)号:DE19533269A1

    公开(公告)日:1997-03-13

    申请号:DE19533269

    申请日:1995-09-08

    Applicant: BASF AG

    Abstract: The invention relates to a method for the production of polymerisates from monomers insoluble in water and monomers optionally soluble in water by radical polymerisation of the monomers in water as the diluting agent, wherein the monomers insoluble in water are used in the form of complexes consisting of (a) cyclodextrins and/or compounds containing cyclodextrin structures, and (b) monomers which are insoluble in water or ethylenically unsaturated and soluble in water up to a maximum of 20 g/l at 20 DEG C, in the mol ratio (a):(b) of from 1:2 to 10:1, or the monomers are polymerised in the presence of up to 5 mol, in relation to 1 mol of the monomers (b), of cyclodextrins and/or compounds containing cyclodextrin structures. It also relates to the use of the polymerisates as sizing agents for the production of paper, as coating agents, as thickening agents for aqueous systems, as detergent additives and as thickening agents in cosmetic creams or lotions.

    80.
    发明专利
    未知

    公开(公告)号:DE19500754A1

    公开(公告)日:1996-07-18

    申请号:DE19500754

    申请日:1995-01-13

    Applicant: BASF AG

    Abstract: The invention concerns biologically degradable polyether ester amides Q1 with a molecular weight (Mn) in the range 6000-8000 g/mol, a viscosity number in the range 30-450 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyether ester amide Q1 at a temperature of 25 DEG C) and a melting point in the range 50-200 DEG C, obtainable through reaction of a mixture consisting essentially of the following: (a1) 95-99.9 wt.% polyether ester amide P1 with a molecular weight (Mn) in the range 6000-80,000 g/mol, a viscosity number in the range 30-450 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyether ester amide P1 at a temperature of 25 DEG C) and a melting point in the range 50-200 DEG C, obtainable through reaction of a mixture consisting essentially of: (b1) a mixture consisting essentially of: 20-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof; 5-80 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof; and 0-5 mol % a compound containing sulphonate groups (the sum of the molar percentages is 100); (b2) a mixture of dihydroxy compounds consisting essentially of: (b21) 15-99.3 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols; (b22) 0.2-85 mol % a dihydroxy compound containing ether functions, of formula I HO-[(CH2)n-O]m-H, wherein n is 2, 3 or 4 and m is an integer between 2 and 250, or mixtures thereof; (b23) 0.5-80 mol % an amino-C2-C12 alkanol or an amino C5-C10 cycloalkanol; and (b24) 0-50 mol % a diamino C1-C8 alkane; (b25) 0-50 mol % a 2,2`-bisoxazoline of general formula II, in which R is a single bond, a (CH2)q-alkylene group in which q = 2, 3 or 4, or a phenylene group (the sum of the individual molar percentages is 100 and the selected molar ratio of b1 to b2 is in the range 0.4:1 - 1.5:1; (a2) 0.1-5 wt.% a divinyl ether C1; and (a3) 0-5 mol % (in relation to components b1 from the production of P1) compound D. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same and the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles, foams and blends with starch obtainable from the polymers or moulding materials according to the invention.

Patent Agency Ranking