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    제초활성을 갖는9-(5-이속사졸메톡시페닐)이미노-8-치아-1,6-디아자비시클로[4.3.0]노난-7-온 유도체
    82.
    发明授权
    제초활성을 갖는9-(5-이속사졸메톡시페닐)이미노-8-치아-1,6-디아자비시클로[4.3.0]노난-7-온 유도체 失效
    除草9-5-异恶唑甲氧基苯基亚氨基-8-硫杂-1,6-二氮杂双环[4.3.0]壬-7-酮衍生物

    公开(公告)号：KR100477892B1

    公开(公告)日：2005-03-18

    申请号：KR1020030026416

    申请日：2003-04-25

    Applicant: 한국화학연구원

    Inventor： 전동주 ,  김형래 ,  송종환 ,  박관용 ,  정순민 ,  황인택

    IPC: A01N43/90

    Abstract: 본 발명은 다음 화학식 1로 표시되는 신규의 9-(5-이속사졸메톡시페닐)이미노-8-치아-1,6-디아자비시클로[4.3.0]노난-7-온 유도체와 이들을 유효성분으로 포함하는 제초제에 관한 것이다.

    상기 화학식 1에서, R은 C
    1 ∼C
    5 의 알킬기, 페닐기 또는 치환된 페닐기이고, 이때 치환된 페닐기는 C
    1 ∼C
    3 의 알킬기, C
    1 ∼C
    3 의 알콕시기, 할로겐 원자, 시아노기, 니트로기, 카르복실기 및 카르복실산 에스테르기 중에서 선택된 치환기가 1 ∼ 3개 단일 혹은 복합적으로 치환된 페닐기이다.

    3-클로로-2-(4-클로로-2-플루오로-5-히드록시페닐)-4,5,6,7-테트라히드로-2Ｈ-인다졸의 제조방법
    83.
    发明授权
    3-클로로-2-(4-클로로-2-플루오로-5-히드록시페닐)-4,5,6,7-테트라히드로-2Ｈ-인다졸의 제조방법 失效
    3-클로로-2-（4-클로로-2-플루오로-5-록드록시페닐）-4,5,6,7-테트라히드로-2H-인다졸의제조방3-

    公开(公告)号：KR100454090B1

    公开(公告)日：2004-10-26

    申请号：KR1020020033207

    申请日：2002-06-14

    Applicant: 한국화학연구원

    Inventor： 유응걸 ,  전동주 ,  김형래 ,  송종환 ,  박관용

    IPC: C07D231/54

    Abstract: PURPOSE: A process for preparing 3-chloro-2- (4-chloro-2-fluoro-5-hydroxyphenyl)- 4,5,6,7-tetrahydro-2H-indazole is provided, thereby improving its preparation yield and converting by-products of the preparation into starting material. CONSTITUTION: A process for preparing 3-chloro-2- (4-chloro-2-fluoro-5-hydroxyphenyl)- 4,5,6,7-tetrahydro-2H-indazole of the formula 1 comprises the steps of: reacting 2- (2-fluoro-4-chloro-5-hydroxyphenyl)- 2,3a,4,5,6,7- hexahydroindazole-3-one of the formula 2 with phosgene; concentrating the phosgene reaction mixture under reduced pressure; dissolving the concentrate in an organic solvent; adding ammonia water or hydroxide solution to the organic solvent and filtering solids; and distilling the filtrated solution, wherein the organic solvent is ethylacetate; the addition of ammonia water or hydroxide solution is carried out at room temperature; the solids are mainly constituted of a compound of the formula 2, and the by-products of the reaction include a dimer represented by the formula 3a, 3b or 3c.

    Abstract translation: 目的：提供一种制备3-氯-2-（4-氯-2-氟-5-羟基苯基）-4,5,6,7-四氢-2H-吲唑的方法，由此提高其制备产率和通过 - 将制剂的产物制成原料。 构成：制备式1的3-氯-2-（4-氯-2-氟-5-羟基苯基）-4,5,6,7-四氢-2H-吲唑的方法包括以下步骤：使2 - （2-氟-4-氯-5-羟基苯基）-2,3a，4,5,6,7-六氢吲唑-3-酮与光气的反应; 在减压下浓缩光气反应混合物; 将浓缩物溶解在有机溶剂中; 向有机溶剂中加入氨水或氢氧化物溶液并过滤固体; 蒸馏过滤后的溶液，其中有机溶剂为乙酸乙酯; 氨水或氢氧化钠溶液的加入在室温下进行; 固体主要由式2的化合物构成，并且反应的副产物包括由式3a，3b或3c表示的二聚体。

    제초활성을 갖는 5-벤질옥시메틸-1,2-이속사졸린 유도체화합물
    84.
    发明授权
    제초활성을 갖는 5-벤질옥시메틸-1,2-이속사졸린 유도체화합물 有权
    제초활성을갖는5- 5벤질옥시메틸-1,2-이속사졸린유도체화

    公开(公告)号：KR100392072B1

    公开(公告)日：2003-07-22

    申请号：KR1020000052917

    申请日：2000-09-07

    Applicant: 한국화학연구원

    Inventor： 유응걸 ,  김형래 ,  전동주 ,  송종환 ,  김경만 ,  이정노 ,  김형철 ,  홍경식

    IPC: A01N43/80

    CPC classification number: A01N43/80

    Abstract: The present invention provided with novel 5-benzyloxymethyl-1,2-isoxazoline derivatives of the formula (1), their preparation method and their use as herbicides. The 5-benzyloxymethyl-1,2-isoxazoline derivatives according to the present invention have sufficiently high herbicidal activity against the weeds in the paddy field rice even at low dose rates and excellent selectivity to transferred rice in particular. As thus, the compounds of the present invention are typically useful as herbicides for control of paddy weeds in rice.

    Abstract translation: 本发明提供了式（1）的新型5-苄氧基甲基-1,2-异恶唑啉衍生物及其制备方法和它们作为除草剂的用途。 即使在低剂量率下，本发明的5-苄氧基甲基-1,2-异恶唑啉衍生物对稻田杂草具有足够高的除草活性，特别是对转移的稻米具有优异的选择性。 因此，本发明的化合物通常可用作除草剂以控制稻中的稻田杂草。

    제초활성을 갖는 Ｎ-(5-이속사졸리닐메틸옥시페닐)-디메틸말레이미드 유도체
    85.
    发明公开
    제초활성을 갖는 Ｎ-(5-이속사졸리닐메틸옥시페닐)-디메틸말레이미드 유도체 失效
    衍生于除草活性的N-（5-异丙氧基苯基）乙酰基苯基）二甲基亚胺

    公开(公告)号：KR1020000059735A

    公开(公告)日：2000-10-05

    申请号：KR1019990007558

    申请日：1999-03-08

    Applicant: 한국화학연구원

    Inventor： 유응걸 ,  송종환 ,  김형래 ,  전동주 ,  정정애 ,  김경만 ,  김태준

    IPC: C07D413/12

    Abstract: PURPOSE: A N-(5-isoxazolinylmethyloxyphenyl)-dimethylmaleimide derivative is provided which has excellent stability against a rice plant and shows good herbicidal activity on weeds in a paddy like echor, scpju, moova, cypse, sagpy or so on. CONSTITUTION: The N-(5-isoxazolinylmethyloxyphenyl)-dimethylmaleimide derivative is shown in a chemical formula 1 wherein R is alkyl radical with 1-5 carbon number, phenyl radical or substituted phenyl radical, cyano radical, carboxylic acid or carboxylic ester, heterocyclic or substituted heterocyclic radical. The substituted phenyl radical or substituted heterocyclic radical is simply or mixedly substituted from 1-3 radicals among alkyl radical with 1-3 carbon number, alkoxy radial with 1-3 carbon number, halogen atom, cyano radical, nitro radical, carboxyl radical and carboxylic ester.

    Abstract translation: 目的：提供一种对水稻植株具有优异稳定性的N-（5-异恶唑啉基甲氧基苯基） - 二甲基马来酰亚胺衍生物，对水稻，scpju，moova，cypse，sagpy等中的杂草具有良好的除草活性。 组成：N-（5-异恶唑啉基甲氧基苯基） - 二甲基马来酰亚胺衍生物以化学式1表示，其中R是具有1-5个碳数的烷基，苯基或取代的苯基，氰基，羧酸或羧酸酯，杂环或 取代的杂环基。 取代的苯基或取代的杂环基团在具有1-3个碳原子的烷基，具有1-3个碳数的烷氧基，卤素原子，氰基，硝基，羧基和羧基的烷基中简单或混合取代1-3个基团 酯。

    2,3-디히드로-3-메틸렌-2-치환된 페닐-1H-이소인돌-1-온 유도체
    87.
    发明授权
    2,3-디히드로-3-메틸렌-2-치환된 페닐-1H-이소인돌-1-온 유도체 失效
    2.3-二氢-3-乙烯基-2-取代的苯基-1H-1衍生物

    公开(公告)号：KR100128544B1

    公开(公告)日：1998-04-04

    申请号：KR1019940016984

    申请日：1994-07-14

    Applicant: 한국화학연구원

    Inventor： 유응걸 ,  김재녕 ,  이수영 ,  황인택 ,  김형래 ,  김경만 ,  송종환

    IPC: C07D209/32 ,  C07D209/42

    Abstract: Title derivatives(I; R1, R2= same or not, H, fluro, chlorro, bromo, C1-3 alkyl, C1-3 alkoxy; R1 and R2 are formed a fused ring such as -CH=CH-CH=CH-; R3= H, C1-4 alkyl, C3-6 alkenyl, etc.), useful as herbicides were prepared. Thus, 3.03 g 4-fluorophenol was reacted with 1.9 ml ethyl chloride, followed by addition of 4.0 g anhydrous aluminium chloride at 180 deg.C for 30 minutes to give 2.71 g 2-hydroxy-5-fluoroacetophenone(III). III and 1.05 g ethyl carbamate were refluxed for 20- 30 hours in 50 ml n-propanol to give ethoxycarbonylhydrazone derivatives IV. 2.41 g IV was dissolved in 100 ml tetrahydrofuran, adding 4.44 g (CH3COO)4Pb as an oxidation agent at room temperature for 3- 5 hours to give ethyl 0-acetylarylcarboxylate derivatives(V). 2.1 g V and 0.83 g 4-chloro-2-fluoro-5-hydroxyaniline were refluxed for 20- 30 hours in a mixed solvent of 50 ml o-dichlorobenzene and acetic acid to give 2,3-dihydro-3-methylene- 2-(4-chloro-2-fluoro-3-hydroxyphenyl)-1H-isoindol-1-one(VII). VII was refluxed for 20 hours to give 2,3-dihydro-3-methylene-2- (3-propagyloxy-4-chloro-2-fluorophenyl)-1H-isoindol-1-one(I).

    Abstract translation: 标题衍生物（I; R1，R2 =相同或不同，H，氟，氯，溴，C1-3烷基，C1-3烷氧基; R1和R2形成稠环，例如-CH = CH-CH = CH- ; R3 = H，C1-4烷基，C3-6烯基等），可用作除草剂。 因此，将3.03g 4-氟苯酚与1.9ml氯乙烷反应，然后在180℃下加入4.0g无水氯化铝30分钟，得到2.71g 2-羟基-5-氟苯乙酮（III）。 III和1.05g氨基甲酸乙酯在50ml正丙醇中回流20-30小时，得到乙氧基羰基腙衍生物IV。 将2.41g IV溶解在100ml四氢呋喃中，在室温下加入4.44g（CH3COO）4Pb作为氧化剂，持续3-5小时，得到O-乙酰基芳基羧酸乙酯衍生物（V）。 将2.1g V和0.83g 4-氯-2-氟-5-羟基苯胺在50ml邻二氯苯和乙酸的混合溶剂中回流20-30小时，得到2,3-二氢-3-亚甲基-2 - （4-氯-2-氟-3-羟基苯基）-1H-异吲哚-1-酮（VII）。 VII的混合物回流20小时，得到2,3-二氢-3-亚甲基-2-（3-羰基氧基-4-氯-2-氟苯基）-1H-异吲哚-1-酮（I）。

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