公开(公告)号：AU3321302A

公开(公告)日：2002-06-11

申请号：AU3321302

申请日：2001-11-29

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  BENISCH CHRISTOPH ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  BASSLER PETER ,  MAIXNER STEFAN

IPC: C07C209/84 ,  C07C211/09 ,  C07C253/34 ,  C07C255/24

Abstract: A process is provided for reducing the content of a monounsaturated aliphatic amine (III) in a mixture (IV) containing an aminonitrile (I) or a diamine (II), or mixtures thereof, and the amine (III), whereina) the mixture (IV) is reacted with an anionic nucleophile (V),which contains a nucleophilic atom selected from the group comprising oxygen, nitrogen and sulfur,which is capable of taking up an H ion to form an acid with a pKa ranging from 7 to 11, measured in water at 25° C., andwhich has a relative nucleophilicity, measured in methyl perchlorate/methanol at 25° C.,ranging from 3.4 to 4.7 when oxygen is the nucleophilic atom,ranging from 4.5 to 5.8 when nitrogen is the nucleophilic atom, andranging from 5.5 to 6.8 when sulfur is the nucleophilic atom,in an amount ranging from 0.01 to 10 mol per mole of amine (III) in the mixture (IV), to give a mixture (VI), andb) the aminonitrile (I) or the diamine (II), or mixtures thereof, are distilled from the mixture (VI) at a temperature ranging from 50 to 170° C. and a pressure ranging from 0.5 to 100 kPa.

公开(公告)号：AU8193701A

公开(公告)日：2002-01-14

申请号：AU8193701

申请日：2001-07-02

Applicant: BASF AG

Inventor： STEINBRENNER ULRICH ,  NARBESHUBER THOMAS ,  HAUBNER MARTIN ,  SIGWART CHRISTOPH ,  LINDEN GERD ,  COX GERHARD ,  FISCHER ROLF-HARTMUTH ,  HESSE MICHAEL ,  BOHNER GERD ,  HIBST HARTMUT ,  SCHWAB EKKEHARD ,  TENTEN ANDREAS

IPC: C08G65/10 ,  B01J21/06 ,  B01J23/28 ,  B01J23/30 ,  B01J27/188 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  C08G65/20 ,  C08G65/26 ,  B01J23/20 ,  B01J23/24

Abstract: The invention relates to a catalyst which contains a catalytically active quantity of at least one oxygen-containing molybdenum and/or wolfram compound on an oxidic support material and which has been calcinated at temperatures of 400 to 900° C. after the precursor compound of the catalytically active compounds have been applied to the support material or to a support material precursor. The transport pores for this catalyst each have a diameter of >25 nm and a volume of at least 50 mm /g. The catalyst contains x mumol (wolfram and/or molybdenum)/m molybdenum and/or wolfram, with 10.1 /g. Catalysts of this type are characterized by an acidity of at least 70 mumol/g at pKs

公开(公告)号：AU7636501A

公开(公告)日：2002-01-02

申请号：AU7636501

申请日：2001-06-13

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  OHLBACH FRANK ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  BASSLER PETER ,  ANSMANN ANDREAS ,  ACHHAMMER GUNTHER

IPC: C07C209/48 ,  C07C253/34 ,  C07C255/03 ,  C07C255/24

Abstract: The invention relates to a method for removing, by distillation, 6-aminocapronitrile from mixtures that contain 6-aminocapronitrile, adipodinitrile and hexamethylenediamine, by a) removing the hexamethylenediamine from the mixture while obtaining a mixture (I) that has a hexamethylenediamine content of less than 1 wt. -%, b) removing completely or partially the 6-aminocapronitrile from mixture (I) while obtaining a mixture (II) whose content in substances that have a higher boiling point as 6-aminocapronitrile under distillation conditions and that cannot be formed by dimerization reactions when 6-aminocapronitrile is thermally treated is less than 1 wt. -%, and c) completely or partially removing from mixture (II) the hexamethylenediamine that might be present while obtaining a mixture (IV) whose hexamethylenediamine content is higher than that of mixture (II), and a mixture (V) whose hexamethylenediamine content is lower than that of mixture (II).

公开(公告)号：CA2412928A1

公开(公告)日：2001-12-27

申请号：CA2412928

申请日：2001-06-13

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  MELDER JOHANN-PETER ,  FISCHER ROLF-HARTMUTH ,  LUYKEN HERMANN ,  BASSLER PETER ,  ANSMANN ANDREAS ,  ACHHAMMER GUNTHER

IPC: C07C209/48 ,  C07C253/34 ,  C07C255/03 ,  C07C255/24

Abstract: The invention relates to a method for removing, by distillation, 6- aminocapronitrile from mixtures that contain 6-aminocapronitrile, adipodinitrile and hexamethylenediamine, by a) removing the hexamethylenediamine from the mixture while obtaining a mixture (I) that has a hexamethylenediamine content of less than 1 wt.- %, b) removing completely o r partially the 6-aminocapronitrile from mixture (I) while obtaining a mixture (II) whose content in substances that have a higher boiling point as 6- aminocapronitrile under distillation conditions and that cannot be formed by dimerization reactions when 6-aminocapronitrile is thermally treated is less than 1 wt.- %, and c) completely or partially removing from mixture (II) the hexamethylenediamine that might be present while obtaining a mixture (IV) whose hexamethylenediamine content is higher than that of mixture (II), and a mixture (V) whose hexamethylenediamine content is lower than that of mixture (II).

公开(公告)号：DE59702349D1

公开(公告)日：2001-10-31

申请号：DE59702349

申请日：1997-04-03

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF-HARTMUTH

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A process for the coproduction of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) by treatment of adiponitrile (ADN) with hydrogen in the presence of a nickel-containing catalyst at temperatures not below room temperature and elevated hydrogen partial pressure in the presence or absence of a solvent comprises, after the conversion based on ADN and/or the selectivity based on ACN has or have dropped below a defined value (a) interrupting the treatment of ADN with hydrogen by stopping the feed of ADN and of the solvent, if used, (b) treating the catalyst at from 150 DEG to 400 DEG C. with hydrogen using a hydrogen pressure within the range from 0.1 to 30 MPa and a treatment time within the range from 2 to 48 h, and (c) then continuing the hydrogenation of ADN with the treated catalyst of stage (b).

公开(公告)号：CZ9803248A3

公开(公告)日：1999-02-17

申请号：CZ324898

申请日：1997-04-03

Applicant: BASF AG

Inventor： SCHNURR WERNER ,  VOIT GUIDO ,  FLICK KLEMENS ,  FISCHER ROLF-HARTMUTH

IPC: B01J23/78 ,  B01J23/94 ,  B01J27/187 ,  B01J27/28 ,  B01J38/10 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C253/00

CPC classification number: C07C209/48 ,  C07C253/30 ,  Y02P20/584

公开(公告)号：PL208093B1

公开(公告)日：2011-03-31

申请号：PL36682302

申请日：2002-04-24

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  ROESCH MARKUS ,  GOETZ NORBERT

IPC: B01J23/44 ,  C07B31/00 ,  B01J23/88 ,  B01J27/19 ,  C07B61/00 ,  C07C41/00 ,  C07C41/18 ,  C07C43/00 ,  C07C43/205

公开(公告)号：CA2463068C

公开(公告)日：2010-08-03

申请号：CA2463068

申请日：2002-10-18

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J23/745 ,  B01J37/18 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The iron-containing catalyst suitable for use as a catalyst contains a) iron or a mixture containing iron and an iron-based compound. The iron has an average crystallite size ranging from 1-35 nm measured by X-ray diffraction.

公开(公告)号：SK287042B6

公开(公告)日：2009-10-07

申请号：SK13202003

申请日：2002-04-24

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  ROSCH MARKUS ,  GOTZ NORBERT

IPC: B01J23/44 ,  C07B31/00 ,  B01J23/88 ,  B01J27/19 ,  C07B61/00 ,  C07C41/00 ,  C07C41/18 ,  C07C43/00 ,  C07C43/205

Abstract: The invention relates to a method for producing trimetoxytoluene of formula I, wherein the corresponding benzoic acids, benzoic acid esters or benzoic acid anhydrides react with hydrogen in the presence of catalyst.

公开(公告)号：DE502004002451D1

公开(公告)日：2007-02-08

申请号：DE502004002451

申请日：2004-02-26

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  GALL MARTIN ,  HUBER-DIRR SYLVIA ,  LIANG SHELUE ,  NOEBEL THOMAS ,  RUST HARALD ,  STEIN FRANK

IPC: C07C45/78 ,  B01J21/04 ,  B01J23/04 ,  C07C45/48 ,  C07C45/82 ,  C07C49/395