公开(公告)号：EP1842240A4

公开(公告)日：2009-10-14

申请号：EP05826022

申请日：2005-12-02

Applicant: IBM

Inventor： CALLEGARI ALESSANDRO C ,  GRIBELYUK MICHAEL A ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  SAENGER KATHERINE L ,  ZAFAR SUFI

IPC: H01L21/28 ,  C23C14/06 ,  C23C14/34 ,  H01L29/49 ,  H01L29/51

CPC classification number: H01L29/4966 ,  C23C14/0036 ,  C23C14/0635 ,  H01L21/28088 ,  H01L29/513 ,  H01L29/517 ,  H01L29/665

公开(公告)号：EP1836732A4

公开(公告)日：2009-07-01

申请号：EP05826298

申请日：2005-12-02

Applicant: IBM

Inventor： CALLEGARI ALESSANDRO C ,  FRANK MARTIN M ,  JAMMY RAJARAO ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  ZAFAR SUFI

IPC: H01L27/088 ,  H01L21/28 ,  H01L29/49

CPC classification number: H01L29/4966 ,  H01L21/28088 ,  H01L29/513 ,  H01L29/517 ,  H01L29/665 ,  H01L29/6659

Abstract: A compound metal comprising HfSiN which is a n-type metal having a workfunction of about 4.0 to about 4.5, preferably about 4.3, eV which is thermally stable on a gate stack comprising a high k dielectric and an interfacial layer. Furthermore, after annealing the stack of HfSiN/high k dielectric/interfacial layer at a high temperature (on the order of about 1000°C), there is a reduction of the interfacial layer, thus the gate stack produces a very small equivalent oxide thickness (12 Å classical), which cannot be achieved using TaSiN.

公开(公告)号：WO2006076086A3

公开(公告)日：2009-04-16

申请号：PCT/US2005043552

申请日：2005-12-02

Applicant: IBM ,  CALLEGARI ALESSANDRO C ,  GRIBELYUK MICHAEL A ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  SAENGER KATHERINE L ,  ZAFAR SUFI

Inventor： CALLEGARI ALESSANDRO C ,  GRIBELYUK MICHAEL A ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  SAENGER KATHERINE L ,  ZAFAR SUFI

IPC: H01L29/94 ,  H01L29/76 ,  H01L31/062 ,  H01L31/113 ,  H01L31/119

CPC classification number: H01L29/4966 ,  C23C14/0036 ,  C23C14/0635 ,  H01L21/28088 ,  H01L29/513 ,  H01L29/517 ,  H01L29/665

Abstract: A compound metal comprising TiC which is a p-type metal having a workfunction of about 4.75 to about 5.3, preferably about 5, eV that is thermally stable on a gate stack comprising a high k dielectric and an interfacial layer is provided as well as a method of fabricating the TiC compound metal. Furthermore, the TiC metal compound of the present invention is a very efficient oxygen diffusion barrier at 1000°C allowing very aggressive equivalent oxide thickness (EOT) and inversion layer thickness scaling below 14 Å in a p-metal oxide semiconductor (pMOS) device.

Abstract translation: 提供了包含TiC的复合金属，其是在包括高k电介质和界面层的栅极堆叠上具有约4.75至约5.3，优选约5e的功函数的功函数的热电稳定的p型金属，以及 制造TiC复合金属的方法。 此外，本发明的TiC金属化合物在1000℃下是非常有效的氧扩散阻挡层，在p-金属氧化物半导体（pMOS）器件中允许非常有侵蚀性的等效氧化物厚度（EOT）和低于14的反型层厚度标度。

公开(公告)号：WO2006076087A2

公开(公告)日：2006-07-20

申请号：PCT/US2005043555

申请日：2005-12-02

Applicant: IBM ,  CALLEGARI ALESSANDRO C ,  FRANK MARTIN M ,  JAMMY RAJARAO ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  ZAFAR SUFI

Inventor： CALLEGARI ALESSANDRO C ,  FRANK MARTIN M ,  JAMMY RAJARAO ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  ZAFAR SUFI

IPC: H01L29/94

CPC classification number: H01L29/4966 ,  H01L21/28088 ,  H01L29/513 ,  H01L29/517 ,  H01L29/665 ,  H01L29/6659

Abstract: A compound metal comprising HfSiN which is a n-type metal having a workfunction of about 4.0 to about 4.5, preferably about 4.3, eV which is thermally stable on a gate stack comprising a high k dielectric and an interfacial layer. Furthermore, after annealing the stack of HfSiN/high k dielectric/interfacial layer at a high temperature (on the order of about 1000°C), there is a reduction of the interfacial layer, thus the gate stack produces a very small equivalent oxide thickness (12 Å classical), which cannot be achieved using TaSiN.

Abstract translation: 包含HfSiN的复合金属，其是具有约4.0至约4.5，优选约4.3的功函数的n型金属，其在包含高k电介质和界面层的栅极堆叠上是热稳定的。 此外，在高温（约1000℃）的高温下退火HfSiN /高k电介质/界面层之后，界面层的减少，因此栅叠层产生非常小的等效氧化物厚度 （12经典），使用TaSiN无法实现。

公开(公告)号：CA1283490C

公开(公告)日：1991-04-23

申请号：CA600747

申请日：1989-05-25

Applicant: IBM

Inventor： BUCHANAN DOUGLAS A ,  CALLEGARI ALESSANDRO C ,  HOH PETER D ,  LACEY DIANNE L

IPC: H01L21/318 ,  H01L29/78 ,  H01L21/70 ,  H01L27/04

Abstract: METHOD FOR PASSIVATING A COMPOUND SEMICONDUCTOR SURFACE AND DEVICE HAVING IMPROVED SEMICONDUCTOR-INSULATOR INTERFACE A method for passivating the surface of a compound semiconductor comprises annealing the substrate to form an anion rich surface layer containing cationic and anionic oxides and stripping the oxides to leave only a very thin anionic layer on the surface. The substrate is then subjected to an H2 plasma cleaning to remove chemisorbed oxygen. An N2 plasma cleaning is then performed to form an anionic nitride layer that is free of any cationic nitride. A layer of insulating material, such as, a native or other oxide, or a nitride, is deposited. The resulting structure has a very low interface state density such that the Fermi level may be swept through the entire band gap.

公开(公告)号：AT526684T

公开(公告)日：2011-10-15

申请号：AT05826298

申请日：2005-12-02

Applicant: IBM

Inventor： CALLEGARI ALESSANDRO C ,  FRANK MARTIN M ,  JAMMY RAJARAO ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  ZAFAR SUFI

IPC: H01L27/088 ,  H01L21/28 ,  H01L29/49

Abstract: A compound metal comprising HfSiN which is a n-type metal having a workfunction of about 4.0 to about 4.5, preferably about 4.3, eV which is thermally stable on a gate stack comprising a high k dielectric and an interfacial layer. Furthermore, after annealing the stack of HfSiN/high k dielectric/interfacial layer at a high temperature (on the order of about 1000° C.), there is a reduction of the interfacial layer, thus the gate stack produces a very small equivalent oxide thickness (12 Å classical), which cannot be achieved using TaSiN.

公开(公告)号：DE602005022493D1

公开(公告)日：2010-09-02

申请号：DE602005022493

申请日：2005-12-02

Applicant: IBM

Inventor： CALLEGARI ALESSANDRO C ,  GRIBELYUK MICHAEL A ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  SAENGER KATHERINE L ,  ZAFAR SUFI

IPC: H01L29/94 ,  C23C14/06 ,  C23C14/34 ,  H01L29/49 ,  H01L29/51

公开(公告)号：AT475195T

公开(公告)日：2010-08-15

申请号：AT05826022

申请日：2005-12-02

Applicant: IBM

Inventor： CALLEGARI ALESSANDRO C ,  GRIBELYUK MICHAEL A ,  LACEY DIANNE L ,  MCFEELY FENTON R ,  SAENGER KATHERINE L ,  ZAFAR SUFI

IPC: H01L21/28 ,  C23C14/06 ,  C23C14/34 ,  H01L29/49 ,  H01L29/51

Abstract: A compound metal comprising TiC which is a p-type metal having a workfunction of about 4.75 to about 5.3, preferably about 5, eV that is thermally stable on a gate stack comprising a high k dielectric and an interfacial layer is provided as well as a method of fabricating the TiC compound metal. Furthermore, the TiC metal compound of the present invention is a very efficient oxygen diffusion barrier at 1000° C. allowing very aggressive equivalent oxide thickness (EOT) and inversion layer thickness scaling below 14 Å in a p-metal oxide semiconductor (pMOS) device.