ADHESIVE COMPOSITIONS COMPRISING A SILSESQUIOXANE POLYMER CROSSLINKER, ARTICLES AND METHODS

    公开(公告)号:US20170321088A1

    公开(公告)日:2017-11-09

    申请号:US15306200

    申请日:2015-06-08

    Abstract: Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10° C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The free-radically polymerizable solvent monomer, polymerized units of the solute (meth)acrylic polymer, or a combination thereof comprise a low Tg ethylenically unsaturated monomer. Also described are pressure sensitive adhesive articles and method of preparing adhesive articles.

    METHOD OF MAKING A NANOSTRUCTURE AND NANOSTRUCTURED ARTICLES
    32.
    发明申请
    METHOD OF MAKING A NANOSTRUCTURE AND NANOSTRUCTURED ARTICLES 审中-公开
    制备纳米结构和纳米结构的方法

    公开(公告)号:US20170067150A1

    公开(公告)日:2017-03-09

    申请号:US15354086

    申请日:2016-11-17

    Abstract: A method of making a nanostructure and nanostructured articles by depositing a layer to a major surface of a substrate by plasma chemical vapor deposition from a gaseous mixture while substantially simultaneously etching the surface with a reactive species. The method includes providing a substrate; mixing a first gaseous species capable of depositing a layer onto the substrate when formed into a plasma, with a second gaseous species capable of etching the substrate when formed into a plasma, thereby forming a gaseous mixture; forming the gaseous mixture into a plasma; and exposing a surface of the substrate to the plasma, wherein the surface is etched and a layer is deposited on at least a portion of the etched surface substantially simultaneously, thereby forming the nanostructure. The substrate can be a (co)polymeric material, an inorganic material, an alloy, a solid solution, or a combination thereof. The deposited layer can include the reaction product of plasma chemical vapor deposition using a reactant gas comprising a compound selected from the group consisting of organosilicon compounds, metal alkyl compounds, metal isopropoxide compounds, metal acetylacetonate compounds, metal halide compounds, and combinations thereof. Nanostructures of high aspect ratio and optionally with random dimensions in at least one dimension and preferably in three orthogonal dimensions can be prepared.

    Abstract translation: 一种通过从气体混合物的等离子体化学气相沉积而将基底沉积到基底的主表面上而形成纳米结构和纳米结构化制品的方法,同时基本上同时用反应性物质蚀刻该表面。 该方法包括提供基板; 当形成等离子体时,能够将能够沉积到衬底上的第一气态物质混合,当形成等离子体时,能够蚀刻衬底的第二气态物质,从而形成气态混合物; 将气态混合物形成等离子体; 以及将所述衬底的表面暴露于所述等离子体,其中所述表面被蚀刻并且基本上同时地在所述蚀刻表面的至少一部分上沉积层,从而形成所述纳米结构。 基底可以是(共)聚合物材料,无机材料,合金,固溶体或其组合。 沉积层可以包括使用包含选自有机硅化合物,金属烷基化合物,金属异丙醇化合物,金属乙酰丙酮化合物,金属卤化物化合物及其组合的化合物的反应气体的等离子体化学气相沉积的反应产物。 可以制备高纵横比的纳米结构,并且任选地在至少一个维度,优选三个正交尺寸的随机尺寸。

    MULTILAYER PRESSURE-SENSITIVE ADHESIVE FILMS WITH A (METH)ACRYLIC-BASED ELASTOMERIC MATERIAL
    33.
    发明申请
    MULTILAYER PRESSURE-SENSITIVE ADHESIVE FILMS WITH A (METH)ACRYLIC-BASED ELASTOMERIC MATERIAL 审中-公开
    具有(甲基)丙烯酸的弹性体材料的多层压敏粘合膜

    公开(公告)号:US20160326404A1

    公开(公告)日:2016-11-10

    申请号:US15214136

    申请日:2016-07-19

    Abstract: The present invention is directed to a multilayer pressure sensitive adhesive (PSA) film, having a first pressure sensitive adhesive layer and at least an opposing layer, wherein the first pressure sensitive adhesive layer comprises a pressure-sensitive adhesive composition with a (meth)acrylic-based elastomeric material comprising a reaction product of polymerizable material comprising: (a) a first monomer which is an alkyl (meth)acrylate ester of a primary alcohol R1—OH, the alkyl (meth)acrylate ester being of Formula (I) CH2═C(R2)—(CO)—OR1   (I) wherein R1 is an alkyl having 14 to 25 carbon atoms and the primary alcohol R1—OH has an iso index equal to at least 2 but no greater than 4; R2 is hydrogen or methyl; and (b) a second monomer having an ethylenically unsaturated group; wherein the at least one opposing layer comprises at least one filler material. The invention is also directed to a method for the manufacturing of such a multilayer PSA film and its use.

    Adhesives comprising crosslinker with (meth)acrylate group and olefin group and methods
    34.
    发明授权
    Adhesives comprising crosslinker with (meth)acrylate group and olefin group and methods 有权
    包含交联剂与(甲基)丙烯酸酯基团和烯烃基团的粘合剂和方法

    公开(公告)号:US09475967B2

    公开(公告)日:2016-10-25

    申请号:US14767732

    申请日:2014-04-11

    Abstract: A pressure sensitive adhesive composition is described comprising at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one cross-linking monomers comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In yet other embodiments, methods of preparing adhesive compositions are described.

    Abstract translation: 描述了一种压敏粘合剂组合物,其包含至少50重量%的衍生自(甲基)丙烯酸烷基酯单体的聚合单元; 和0.2至15重量%的至少一种包含(甲基)丙烯酸酯基团和C 6 -C 20烯烃基团的交联单体,所述烯烃基团任选被取代。 在另一个实施方案中,描述了包含糖浆的粘合剂组合物,其包含i)可自由基聚合的溶剂单体; 和ii)包含衍生自一种或多种(甲基)丙烯酸烷基酯单体的聚合单元的溶质(甲基)丙烯酸聚合物; 其中所述糖浆包含至少一种交联单体或所述(甲基)丙烯酸溶质聚合物包含衍生自至少一种交联单体的聚合单元,所述交联单体包含(甲基)丙烯酸酯基团和C 6 -C 20烯烃基团,所述烯烃基团为 任选取代。 在其它实施方案中,描述了制备粘合剂组合物的方法。

    METHOD OF MAKING A NANOSTRUCTURE AND NANOSTRUCTURED ARTICLES
    36.
    发明申请
    METHOD OF MAKING A NANOSTRUCTURE AND NANOSTRUCTURED ARTICLES 审中-公开
    制备纳米结构和纳米结构的方法

    公开(公告)号:US20160141149A1

    公开(公告)日:2016-05-19

    申请号:US14895693

    申请日:2014-07-23

    CPC classification number: H01J37/32009 G09B19/00 H01J2237/332 H01J2237/334

    Abstract: A method and apparatus for enhancing a cognitive ability of a user may comprise: conducting, via a user interface display of a user computing device, a training session which may comprise: presenting a transportation routing network having a source of travelers and a respective unique destination for each traveler and a path from the source to the respective unique destination, each path comprising at least one direction modification element operable by the user to correctly direct the traveler from the source to the respective unique destination; displaying to the user a traveler moving along a path from the source to the at least one direction modification element; allowing the user to control the position of the at least one direction modification element so as to direct the traveler from the source to the respective unique destination.

    Abstract translation: 用于增强用户的认知能力的方法和装置可以包括:经由用户计算设备的用户界面显示进行训练会话,该训练会话可以包括:呈现具有旅行者来源的运输路由网络和相应的唯一目的地 对于每个旅行者以及从源到相应的唯一目的地的路径,每个路径包括至少一个方向修改单元,其可由用户操作以将旅行者从源正确地引导到相应的唯一目的地; 向用户显示沿着从源到至少一个方向修改元件的路径移动的旅行者; 允许用户控制至少一个方向修改元件的位置,以便将旅行者从源引导到相应的唯一目的地。

    SINGLE PANE GLAZING LAMINATES
    38.
    发明申请
    SINGLE PANE GLAZING LAMINATES 审中-公开
    单层玻璃层压板

    公开(公告)号:US20130062010A1

    公开(公告)日:2013-03-14

    申请号:US13668650

    申请日:2012-11-05

    Abstract: A single pane glazing unit includes a first glass substrate having a first inner surface and a first outer surface, a second glass substrate having a second inner surface and a second outer surface, and a pyrolytic Low-e coating disposed on the second outer surface, and a multilayer polymeric infrared light reflecting film laminated between the first inner surface and the second inner surface, forming a single pane glazing unit. Methods of forming the same are also disclosed.

    Abstract translation: 单层玻璃单元包括具有第一内表面和第一外表面的第一玻璃基板,具有第二内表面和第二外表面的第二玻璃基板和设置在第二外表面上的热解Low-e涂层, 以及层叠在第一内表面和第二内表面之间的多层聚合物红外光反射膜,形成单层玻璃窗单元。 还公开了其形成方法。

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