公开(公告)号：JPH1171313A

公开(公告)日：1999-03-16

申请号：JP17505598

申请日：1998-06-22

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  RIEBER NORBERT DR ,  BREUER KLAUS DR ,  RIEKER CHRISTOPHER WILLIAM DR ,  DEMUTH DIRK DR ,  HIBST HARTMUT ,  HAGEMEYER ALFRED DR

IPC: B01J23/06 ,  B01J37/02 ,  C07B61/00 ,  C07C41/06 ,  C07C41/08 ,  C07C41/54 ,  C07C43/15 ,  C07C43/303 ,  C07C67/04 ,  C07C69/145 ,  C07C69/16

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound at a low temperature, by adding a hydroxyl group-containing compound to an alkyne, etc., in the presence of an amorphous zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing 1-40 wt.% calculated as oxide of zinc or cadmium-containing X-ray amorphous zinc silicate or cadmium silicate as an active ingredient and obtained by setting a zinc salt or a cadmium salt of an acidic organic compound decomposable at a temperature lower than 400 deg.C on amorphous silicic acid and forming the catalyst at 50-500 deg.C in the presence of hydrogen and a hydroxyl group-containing compound such as a

公开(公告)号：JPH1171315A

公开(公告)日：1999-03-16

申请号：JP17620798

申请日：1998-06-23

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  RIEBER NORBERT DR ,  BREUER KLAUS DR ,  DEMUTH DIRK DR ,  HIBST HARTMUT

IPC: B01J23/06 ,  B01J37/02 ,  C07B61/00 ,  C07C41/06 ,  C07C41/08 ,  C07C41/54 ,  C07C43/15 ,  C07C43/16 ,  C07C43/303

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound at a low temperature, by adding a hydroxyl group-containing compound to an alkyne, etc., in the presence of an amorphous zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase at

公开(公告)号：JPH1171314A

公开(公告)日：1999-03-16

申请号：JP17505698

申请日：1998-06-22

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  RIEBER NORBERT DR ,  BREUER KLAUS DR ,  DEMUTH DIRK DR ,  HIBST HARTMUT ,  HAGEMEYER ALFRED DR

IPC: B01J23/08 ,  B01J21/16 ,  B01J23/06 ,  B01J37/03 ,  C01B33/20 ,  C07B41/00 ,  C07B61/00 ,  C07C41/06 ,  C07C41/08 ,  C07C41/54 ,  C07C43/15 ,  C07C43/16 ,  C07C43/303

Abstract: PROBLEM TO BE SOLVED: To safely obtain the subject compound, by adding a hydroxyl group- containing compound to an alkyne, etc., in the presence of a roentgenamorph zinc silicate catalyst, etc. SOLUTION: A compound of the formula R OH (R is H, an aliphatic or alicyclic group) is added to an acetylene or allene of formula I or formula II (R is H, an aliphatic or alicyclic group) in a gas phase by using a catalyst containing a zinc silicate as an active ingredient obtained by precipitation from an aqueous solution comprising a soluble silicon compound and zinc compound to give the objective compound of formula III or formula IV ((m) is 0 or 1). The zinc silicate is X-ray amorphous zinc silicate of the formula Zna Sic Oa+2c-0.5e (OH)e .fH2 O ((e) is a value from 0 to 2a+2c; a/c is 1-3.5 and f/a is 0 to 200) and/or a crystal zinc silicate having a hemimorphite structure of the formula Zn4 Si2 O7 ) (OH)2 .H2 O. Zinc exists in a deficient amount or an excessive amount of 25% in terms of stoichiometric composition.

公开(公告)号：JPH11152245A

公开(公告)日：1999-06-08

申请号：JP25520098

申请日：1998-09-09

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  RIEBER NORBERT DR ,  BREUER KLAUS DR ,  DEMUTH DIRK DR ,  HIBST HARTMUT ,  KAESHAMMER STEFAN DR ,  ETZRODT HEINZ DR ,  KAISER WULF DR

IPC: B01J23/06 ,  C07B61/00 ,  C07C41/08 ,  C07C41/28 ,  C07C45/51 ,  C07C49/203

Abstract: PROBLEM TO BE SOLVED: To obtain an unsaturated ketone which is an intermediate for synthesizing a useful flavor and a natural substance by reacting isopropenyl ether with a ketal of acetone with propene, etc., in the reaction between an allyl alcohol and isopropenyl ether. SOLUTION: An allyl alcohol of formula I (R to R are each H, an alkyl, an alkenyl or the like) or a propargyl alcohol of formula II is reacted with an isopropenyl ether of formula III (R is 1-4C alkyl) with forming a ketal of formula IV to give unsaturated ketones of formula V and formula VI. The isopropenyl ether of the formula III is obtained by reacting the ketal of formula IV with propyne or allylene or its mixture in a vapor phase at a raised temperature in the presence of a heterogeneous catalyst containing silicon or oxygen and zinc or cadmium. The ketal of the formula IV is resupplied for producing the isopropenyl ether of the formula III.

公开(公告)号：JPH10114705A

公开(公告)日：1998-05-06

申请号：JP24899897

申请日：1997-09-12

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR ,  RIEBER NORBERT DR ,  SCHULZ MICHAEL DR ,  TELES JOAQUIM HENRIQUE DR

IPC: B01J27/128 ,  B01J27/138 ,  B01J31/02 ,  B01J31/12 ,  C07B61/00 ,  C07C27/02 ,  C07C35/06 ,  C07C67/03 ,  C07C67/04 ,  C07C69/06

Abstract: PROBLEM TO BE SOLVED: To obtain the subject compound in a short time without generating a coupling product and effectively utilizing the starting substances by reacting a specific cyclopentene with formic acid in the presence of an acidic catalyst. SOLUTION: The objective cyclopentyl formate of the formula II is produced by reacting (A) 1mol of a cyclopentene compound of the formula I (R1 to R3 are each H or a 1-8C alkyl, preferably a 1-4C alkyl) with (B) 0.1-25mol of formic acid in the presence of (C) 0.0001-25mol of an acidic catalyst (e.g. a Lewis acid) at -80 to +200 deg.C, preferably 35-80 deg.C. The component A is available as a 5C stream from a cracking apparatus or an oil refinery plant. Cyclopentyl formate is useful as a production raw material for cyclopentanol.

公开(公告)号：EP0902001B1

公开(公告)日：2001-11-07

申请号：EP98116052

申请日：1998-08-26

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  RIEBER NORBERT DR ,  BREUER KLAUS DR ,  DEMUTH DIRK DR ,  HIBST HARTMUT PROF DR ,  KAESHAMMER STEFAN DR ,  ETZRODT HEINZ DR ,  KAISER WULF DR

IPC: B01J23/06 ,  C07B61/00 ,  C07C45/51 ,  C07C49/203 ,  C07C41/08 ,  C07C41/28

CPC classification number: C07C45/513 ,  Y02P20/582 ,  C07C49/203

公开(公告)号：ID27449A

公开(公告)日：2001-04-12

申请号：ID20010297

申请日：1999-08-09

Applicant: BASF AG

Inventor： BASSLER PETER DR ,  HARDER WOLFGANG DR ,  RESCH PETER DR ,  RIEBER NORBERT DR

IPC: C07D301/19 ,  B01J20060101 ,  B01J8/04 ,  C07B20060101 ,  C07B33/00 ,  C07B41/00 ,  C07B61/00 ,  C07D20060101 ,  C07D301/03 ,  C07D301/12 ,  C07D303/04

Abstract: A process for the reaction of an organic compound with a hydroperoxide comprises at least the steps (i) to (iii) below:(i) reaction of the hydroperoxide with the organic compound to give a mixture comprising the reacted organic compound and unreacted hydroperoxide,(ii) separation of the unreacted hydroperoxide from the mixture resulting from step (i),(iii) reaction of the hydroperoxide separated off in step (ii) with the organic compound.

公开(公告)号：DE19726666A1

公开(公告)日：1998-12-24

申请号：DE19726666

申请日：1997-06-23

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE DR ,  RIEBER NORBERT DR ,  BREUER KLAUS ,  RIEKER CHRISTOPHER WILLIAM DR ,  DEMUTH DIRK DR ,  HIBST HARTMUT DR ,  HAGEMEYER ALFRED DR

IPC: B01J23/06 ,  B01J37/02 ,  C07B61/00 ,  C07C41/06 ,  C07C41/08 ,  C07C41/54 ,  C07C43/15 ,  C07C43/303 ,  C07C67/04 ,  C07C69/145 ,  C07C69/16 ,  C07C43/14 ,  C07C43/16 ,  C07C43/162 ,  C07C43/166 ,  C07C69/007 ,  B01J21/16 ,  C01B33/20

Abstract: Preparation of protected aldehydes and ketones of formulae (I) and (II) comprises addition of alcohols of formula (III) to acetylenes or allenes of formulae (IV) and (V) in the gas phase at elevated temperatures in the presence of a heterogeneous, X-ray amorphic zinc or cadmium silicates. The content of zinc or cadmium, calculated as the oxide, is 1-40 wt.%. The catalyst is prepared by bringing a zinc or cadmium salt and an organic acid (which decomposes at below 400 degrees C) into contact with amorphic silica. Formation of the catalyst takes place at 50-500 degrees C in the presence of an OH-containing compound selected from water, 1-10C alkanols, 2-6C diols or triols or 1-6C carboxylic acids. R1OH (III) (R)2C=C=C(R)2 (V) R1 = H or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic group or acyl (all optionally containing inert substituents); R = H or aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic groups (which optionally join together to form rings); and m = 0 or 1.

公开(公告)号：DE19623611A1

公开(公告)日：1997-12-18

申请号：DE19623611

申请日：1996-06-13

Applicant: BASF AG

Inventor： GROSCH GEORG HEINRICH DR ,  MUELLER ULRICH DR ,  SCHULZ MICHAEL DR ,  RIEBER NORBERT DR ,  WUERZ HARALD

IPC: B01J29/04 ,  B01J29/89 ,  C07D301/12 ,  C07D303/04

Abstract: A process for producing epoxides from olefines and hydrogen peroxide or hydroperoxides using an oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure and in the absence of an anthrahydroquinone/anthroquinone redox system, in which the oxidation catalyst is formed by solidifying shaping processes.

公开(公告)号：DE59206398D1

公开(公告)日：1996-07-04

申请号：DE59206398

申请日：1992-03-21

Applicant: BASF AG

Inventor： KAESTNER RALF DR ,  RIEBER NORBERT DR ,  MERGER FRANZ DR

IPC: C07D231/10 ,  A01N43/56 ,  C07D231/12 ,  C07D231/16 ,  C07D521/00

Abstract: Process for the production of 1-carbamoylpyrazole and its derivatives by reacting pyrazole or its derivatives, characterised in that pyrazole or its derivatives are reacted with urea at temperatures above 30 DEG C.