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公开(公告)号:DE102005018606A1
公开(公告)日:2006-11-09
申请号:DE102005018606
申请日:2005-04-21
Applicant: BASF AG
Inventor: HEIDEMANN THOMAS , STAECK BIANCA , EGGERSMANN MARKUS , ULONSKA ARMIN , GACKSTATTER RAINER
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公开(公告)号:DE102005009596A1
公开(公告)日:2006-08-31
申请号:DE102005009596
申请日:2005-02-28
Applicant: BASF AG
Inventor: SCHUBERT MARKUS , STEPHAN JUERGEN , POPLOW FRANK , HEIDEMANN THOMAS , DIEHLMANN UWE , MALTRY MICHAELA
Abstract: Preparation of non-aromatic carbon-carbon double/triple bond compound (A) or its mixtures from another non-aromatic carbon-carbon double/triple bond compound (B), comprises reacting pure (B) with an adsorption agent comprising an aluminum oxide (3 wt.%) and activating at 450-1000[deg]C; and contacting the pure compound (B) with a metathesis catalyst.
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公开(公告)号:DE102004038108A1
公开(公告)日:2006-03-16
申请号:DE102004038108
申请日:2004-08-05
Applicant: BASF AG
Inventor: BOTTKE NILS , TRILLER MICHAEL , MUELLER ULRICH , PINKOS ROLF , HEIDEMANN THOMAS
IPC: C07C2/66 , B01J21/16 , C07B37/02 , C07C15/02 , C07C303/06 , C07C309/31
Abstract: The present invention relates to a process for preparing alkylaromatics by reacting aromatic compounds with C1-C14-alkanes in the presence of a heterogeneous catalyst, which comprises using as the catalyst a crystalline, micro- and/or mesoporous solid comprising silicon and at least one father element selected from the group consisting of the transition metals and the main group elements gallium and tin, and activating said catalysts by a reducing pretreatment. Furthermore, the present invention relates to a process for preparing alkylarylsulfonates by sulfonating and neutralizing the alkyl aromatic compounds.
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公开(公告)号:DE50102599D1
公开(公告)日:2004-07-22
申请号:DE50102599
申请日:2001-03-22
Applicant: BASF AG
Inventor: SCHULTZ RALF , HEIDEMANN THOMAS , SCHWAB PETER , ZEHNER PETER
Abstract: A process for the production of essentially unsaturated oligomers of 4-6C alkenes from an alkene or alkene containing hydrocarbon stream at a nickel containing heterogeneous catalyst in an adiabatic reactor at 20-300 [deg]C and 1-100 bar comprises working up a first partial outlet stream to the oligomer and recycling a second partial stream together with fresh alkene to the reactor.
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公开(公告)号:AU2003294692A8
公开(公告)日:2004-05-04
申请号:AU2003294692
申请日:2003-10-14
Applicant: BASF AG
Inventor: NARBESHUBER THOMAS , BOTTKE NILS , PRINZ MARTINA , STEPHAN JURGEN , STEINBRENNER ULRICH , BENFER REGINA , MAAS HEIKO , HEIDEMANN THOMAS , FUNKE FRANK , TROPSCH JURGEN
IPC: C07C29/17 , C07C303/06 , C07C303/08 , C07C309/31 , C07C9/16 , C07C15/107 , C07C31/125 , C11D1/24
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公开(公告)号:DE10229763A1
公开(公告)日:2004-01-29
申请号:DE10229763
申请日:2002-07-03
Applicant: BASF AG
Inventor: HEIDEMANN THOMAS , SIEBENHAAR URSULA
Abstract: Process for oligomerizing an alkene stream over a solid catalyst comprising sulfur and nickel, in which the oligomerization is carried out in two or more successive catalyst zones and the molar ratio of sulfur to nickel in the first catalyst zone is less than 0.5 and that in the last catalyst zone is 0.5 or more and, in the case of further catalyst zones between the first and last catalyst zones, the molar ratio of sulfur to nickel in each catalyst zone is not less than that in the immediately preceding catalyst zone, based on the main flow direction of the feed stream.
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公开(公告)号:DE10213492A1
公开(公告)日:2003-10-09
申请号:DE10213492
申请日:2002-03-26
Applicant: BASF AG
Inventor: STEINBRENNER ULRICH , HEIDEMANN THOMAS , SCHINDLER GOETZ-PETER , STEPHAN JUERGEN , MAAS HEIKO
IPC: C07C15/00 , C07C309/31 , C11D1/22 , C07C2/66 , C07C2/08 , C07C5/22 , C07C5/327 , C07C6/04 , C07C15/02 , C07C303/02 , C07C309/28
Abstract: Preparation of alkylaryl compounds comprises production of a 12C-olefin mixture and reaction of the 12C-olefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkylaromatic compounds whereby additional linear olefins are added before the reaction. A process for the preparation of alkylaryl compounds (I) comprises: (A) production of a 12C-olefin mixture by trimerization of butenes or dehydrogenation of 12C-alkanes, with optionally pre- or post isomerization, or by the production of a 12C-olefin mixture by oligomerization of ethene, followed by isomerization; and (B) reaction of the 12C-olefin mixture from (A) with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkylaromatic compounds whereby additional linear olefins are added before the reaction. Independent claims are included for: (1) a process for the production of alkylarylsulfonates (II) by sulfonation and neutralization of alkylaryl compounds (I); (2) the alkylaryl compounds (I); (3) the alkylarylsulfonates (II); and (4) washing- or cleaning agents containing the alkylarylsulfonates (II).
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公开(公告)号:DE50003148D1
公开(公告)日:2003-09-04
申请号:DE50003148
申请日:2000-11-16
Applicant: BASF AG
Inventor: WALTER MARC , HEIDEMANN THOMAS
IPC: B01J27/053 , B01J23/755 , B01J27/02 , B01J27/043 , B01J37/02 , B01J37/20 , C07B61/00 , C07C2/08 , C07C2/10 , C07C11/107
Abstract: An oligomerization catalyst for olefins having from 2 to 6 carbon atoms is produced by treating aluminum oxide with a nickel compound and a sulfur compound, either simultaneously or firstly with the nickel compound an then with the sulfur compound, and subsequently drying and calcining the resulting catalyst, wherein a molar ratio of sulfur to nickel in the finished catalyst of from 0.25:1 to 0.38:1 is set in this way. The catalyst and its use are also described.
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公开(公告)号:DE59905239D1
公开(公告)日:2003-05-28
申请号:DE59905239
申请日:1999-11-10
Applicant: BASF AG
Inventor: HEIDEMANN THOMAS , HIBST HARTMUT , BAUER STEFAN , DIETRICH ULF
IPC: C07D307/89 , B01J23/68 , B01J35/06 , B01J37/02 , C01G1/00 , C01G31/00 , C01G39/00 , C07B61/00 , C07C51/265 , C07C51/31
Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O, I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.
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公开(公告)号:CZ20023237A3
公开(公告)日:2003-01-15
申请号:CZ20023237
申请日:2001-03-23
Applicant: BASF AG
Inventor: ARNOLD HEIKO , FREIRE ERDBRUGGER CRISTINA , HEIDEMANN THOMAS , MEYER GERALD , UNVERRICHT SIGNE , FRENZEL ANDREA , WULFF-DORING JOACHIM , ANSMANN ANDREAS
IPC: B01J35/06 , B01J23/42 , B01J23/44 , B01J23/48 , B01J23/50 , B01J23/70 , B01J23/755 , B01J37/02 , C07B61/00 , C07C5/02 , C07C5/03 , C07C5/08 , C07C7/163 , C07C7/167 , C07C11/04 , C07C11/06 , C07C11/08 , B01J23/38
Abstract: In a coated catalyst having a core and at least one shell surrounding the core, the core is made up of an inert support material, the shell or shells is/are made up of a porous support substance, with the shell being attached physically to the core, and a catalytically active metal selected from the group consisting of the metals of the 10th and 11th groups of the Periodic Table of the Elements is present in finely divided form or a precursor of the catalytically active metal is present in uniformly distributed form in the shell or shells. The coated catalyst of the present invention is suitable for the reduction of unsaturated hydrocarbons. Here, better selectivities than in the case of previously known coated catalysts can be achieved. A process for producing the coated catalyst is also described.
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