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    PRE-POLYMERIZED CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    31.
    发明申请
    PRE-POLYMERIZED CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开

    公开(公告)号：WO2022214328A1

    公开(公告)日：2022-10-13

    申请号：PCT/EP2022/057811

    申请日：2022-03-24

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： LIGUORI, Dario ,  DALL'OCCO, Tiziano ,  MORINI, Giampiero ,  VITALE, Gianni

    IPC: C08F4/64 ,  C08F10/02 ,  C08F2/34

    Abstract: A pre-polymerized catalyst component for the polymerization of olefins, characterized by comprising (a) a solid catalyst component, comprising Ti, Mg and a halogen and a bidentate electron donor compound (BE) in an amount such that the molar ratio (BE)/Ti ranges from 0 to 0.3, and (b) an amount of an ethylene (co)polymer ranging from 0.1 up to less than 30g per g of said solid catalyst component and being characterized by an intrinsic viscosity, measured in tetraline at 135°C, of at least 3.0 dL/g; said prepolymerized catalyst component also showing a porosity measured by mercury method in the range 0.1 to 1 cm3/g. The pre-polymerized catalyst has a high morphological stability and produces a low amount of fines.

    HETEROPHASIC PROPYLENE COPOLYMERS
    32.
    发明申请
    HETEROPHASIC PROPYLENE COPOLYMERS 审中-公开

    公开(公告)号：WO2021052737A1

    公开(公告)日：2021-03-25

    申请号：PCT/EP2020/074185

    申请日：2020-08-31

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： PIEMONTESI, Fabrizio ,  MIGNOGNA, Alessandro ,  LIGUORI, Dario ,  MORINI, Giampiero ,  VITALE, Gianni

    IPC: C08L23/12 ,  C08F2/00

    Abstract: A polypropylene composition comprising (percentages being referred to the total A+B): A) from 60 to 90wt%, of a fraction insoluble in xylene at 25 °C, comprising more than 90 %wt of propylene units, and B) from 10 to 40wt%; of a fraction soluble in xylene at 25 °C comprising a copolymer of propylene and ethylene containing an average content of ethylene derived units from 30.0 wt% to 50.0wt%, said fraction being characterized by the fact that when subjected to GPC fractionation and continuous IR analysis for determining the ethylene content of the eluted fractions (GPC-IR analysis), it shows that the content of ethylene increases along with the Mw for fractions having Mw higher than the average.

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    35.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开

    公开(公告)号：WO2018091375A1

    公开(公告)日：2018-05-24

    申请号：PCT/EP2017/078934

    申请日：2017-11-10

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F110/06 ,  C08F4/651 ,  C08F4/654

    Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where the R 1 and R 7 groups, equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups, R 2 group is selected from C 1 -C 10 hydrocarbon groups, R 3 to R 6 groups, independently, are selected from hydrogen or C 1 -C 15 hydrocarbon groups which can be fused together to form one or more cycles. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.

    PROCESS FOR THE PREPARATION OF CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    36.
    发明申请
    PROCESS FOR THE PREPARATION OF CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    制备烯烃聚合催化剂组分的方法

    公开(公告)号：WO2017042058A1

    公开(公告)日：2017-03-16

    申请号：PCT/EP2016/070440

    申请日：2016-08-31

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： VITALE, Gianni ,  LIGUORI, Dario ,  MORINI, Giampiero

    IPC: C08F110/06 ,  C08F4/657 ,  C08F4/651

    CPC classification number: C08F4/657 ,  C08F110/06 ,  C08F4/6574 ,  C08F4/6465 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/12

    Abstract: A process for the preparation of a solid catalyst component comprising a Ti compound, a Bi compound and optionally an electron donor on a Mg chloride based support, said process comprising one or more steps (a) carried out at a temperature ranging from 0 to 150°C in which a Mg based compound of formula (M g Cl m X 2-m )*nLB, in which m ranges from 0 to 2, n ranges from 0 to 6, X is, independently R 1 , OR 1 , -OCOR 1 or 0-C(0)-OR 1 group in which R 1 is a C 1 -C 20 hydrocarbon group and LB is a Lewis base, is reacted with a liquid medium comprising a Ti compound having at least a Ti-Cl bond in an amount such that the Ti/Mg molar ratio is higher than 3; said process being characterized by the fact that in at least one of said steps (a) a Bi compound is dissolved or dispersed in said liquid medium comprising the titanium compound.

    Abstract translation: 一种制备固体催化剂组分的方法，所述固体催化剂组分包含在氯化镁基载体上的Ti化合物，Bi化合物和任选的电子给体，所述方法包括一个或多个步骤（a），其在0至150℃的温度下进行 ℃，其中m为0至2，m为0至6的式（MgClmX 2-m）* nLB的Mg基化合物，X独立地为R 1，OR 1，-OCOR 1或0-C（O ）-OR1基团，其中R1是C1-C20烃基，LB是路易斯碱，与包含至少具有Ti-Cl键的Ti化合物的液体介质反应，其量使得Ti / Mg摩尔比 高于3; 所述方法的特征在于在至少一个所述步骤（a）中Bi化合物溶解或分散在包含钛化合物的所述液体介质中。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    38.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2016184884A1

    公开(公告)日：2016-11-24

    申请号：PCT/EP2016/061078

    申请日：2016-05-18

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MIGNOGNA, Alessandro ,  KASHULIN, Igor ,  MORINI, Giampiero ,  NIFANT'EV, Ilya

    IPC: C08F4/651 ,  C08F10/00

    CPC classification number: C08F4/651 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15

    Abstract: A solid catalyst component for the polymerization of olefins comprising Mg, Ti and a an electron donor of formula (I) where independently, Z is a bridging group, the R 2 groups, equal to or different from each other, are hydrogen or a C 1 -C 20 hydrocarbon radicals, m is a number satisfying the valences of Z and n is an integer ranging from 1 to 10, R 1 and R 4 are selected from C 1 -C 15 hydrocarbon groups, optionally containing a heteroatom selected from halogen, P, S, N,O; and R 3 group, is hydrogen or R 4 groups. The catalyst system based on the solid catalyst component is endowed with high activity and stereospecificity.

    Abstract translation: 一种用于烯烃聚合的固体催化剂组分，其包含Mg，Ti和式（I）的电子给体，其中独立地Z为桥连基，R2基彼此相同或不同，为氢或C1- C20烃基，m是满足Z的化合价的数，n是1至10的整数，R 1和R 4选自C 1 -C 15烃基，任选地含有选自卤素，P，S，N， O; 和R 3基团，是氢或R 4基团。 基于固体催化剂组分的催化剂体系具有高活性和立体定向性。

    MULTILAYER FILM RANDOM PROPYLENE-ETHYLENE COPOLYMERS
    39.
    发明申请
    MULTILAYER FILM RANDOM PROPYLENE-ETHYLENE COPOLYMERS 审中-公开
    多层薄膜随机丙烯 - 乙烯共聚物

    公开(公告)号：WO2015169652A1

    公开(公告)日：2015-11-12

    申请号：PCT/EP2015/059246

    申请日：2015-04-28

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

    Inventor： MASSARI, Paola ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni ,  CATHELIN, Caroline ,  MORINI, Giampiero ,  CIARAFONI, Marco ,  CAVALIERI, Claudio ,  FELISATI, Andrea

    IPC: C08F110/06 ,  C08F210/06 ,  C08F4/657 ,  C08L23/12 ,  C08L23/14

    CPC classification number: C08F210/06 ,  C08L23/12 ,  C08L23/142 ,  C08L2203/16 ,  C08L2203/162

    Abstract: A multilayer film is characterized by having at least a skin layer comprising a propylene -- ethylene copolymers characterized by the following features: ethylene derived units content of between 1.0 wt% and 15.0% wt%; molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; - the content of xylene soluble fraction (XS) and the ethylene derived units content (C2) fulfill the following relation: XS 0.435C2 where XS is the percentage by weight of the fraction soluble in xylene at 25°C and C2 is the percentage by weight of ethylene units in the said copolymers determined via NMR.

    Abstract translation: 多层膜的特征在于至少具有包含丙烯 - 乙烯共聚物的表层，其特征在于以下特征：乙烯衍生单元含量在1.0wt％至15.0wt％之间; 分子量分布（MWD），以Mw / Mn表示，大于4.0; - 二甲苯可溶级分（XS）和乙烯衍生单元含量（C2）的含量满足下列关系：XS <1.0296⋅e0.435C2其中XS是可溶于二甲苯的馏分在25℃和C2的重量百分比 是通过NMR确定的所述共聚物中乙烯单元的重量百分比。

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