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31.
公开(公告)号:MY144948A
公开(公告)日:2011-11-30
申请号:MYPI20045072
申请日:2004-12-08
Applicant: BASF AG
Inventor: SCHLITTER STEPHAN DR , SCHUBERT OLGA DR , HESSE MICHAEL DR , BORCHERS SABINE , ROESCH MARKUS DR , PINKOS ROLF DR , WECK ALEXANDER , WINDECKER GUNTHER
IPC: B01J23/72 , B01J21/04 , B01J23/94 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/18 , B01J38/10 , B01J38/12 , C07C29/136 , C07C29/149 , C07D307/08 , C07D315/00
Abstract: CATALYST IN THE FORM OF AN EXTRUDATE WHICH COMPRISES FROM 5 TO 85% BY WEIGHT OF COPPER OXIDE AND IN WHICH THE SAME OXIDIC SUPPORT MATERIAL IS PRESENT IN THE ACTIVE COMPOSITION AND AS BINDER, AND THE USE OF THE CATALYST FOR THE HYDROGENATION OF CARBONYL COMPOUNDS.
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公开(公告)号:MY138593A
公开(公告)日:2009-07-31
申请号:MYPI20031962
申请日:2003-05-28
Applicant: BASF AG , UNIV MICHIGAN
Inventor: LOBREE LISA DR , MUELLER ULRICH DR , HESSE MICHAEL DR , YAGHI OMAR M PROF , EDDAOUDI MOHAMED DR
IPC: B01D39/00 , B01J31/22 , B01D39/14 , B01J20/00 , B01J20/22 , B01J20/28 , B01J20/282 , B01J37/00 , B01J39/16 , C02F1/28 , C02F1/42 , C07F3/06 , C07F9/00
Abstract: THE PRESENT INVENTION RELATES TO A NOVEL CLASS OF SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS. SAID METAL-ORGANIC FRAMEWORKS COMPRISE AT LEAST ONE METAL ION AND AT LEAST ONE AT LEAST BIDENTATE ORGANIC COMPOUND AND CONTAIN AT LEAST ONE TYPE OF MICRO- AND MESOPORES OR MICRO- OR MESOPORES. SAID SHAPED BODIES COMPRISE AT LEAST ONE METAL-ORGANIC FRAMEWORK MATERIAL AND MAY OPTIONALLY CONTAIN FURTHER SUBSTANCES, IN PARTICULAR AT LEAST ONE SUPPORTING MATERIAL.
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公开(公告)号:MY137707A
公开(公告)日:2009-02-27
申请号:MYPI20015608
申请日:2001-12-10
Applicant: BASF AG
Inventor: FISCHER ROLF-HARTMUTH DR , WECK ALEXANDER , STEIN FRANK DR , PINKOS ROLF DR , HESSE MICHAEL DR , SPRAGUE MICHAEL JOLYON DR , SCH MARKUS R XD DR , BORCHERT HOLGER DR , SCHLITTER STEPHAN DR , RAHN RALF-THOMAS DR
IPC: B01J23/72 , B01J23/80 , C07C27/06 , C07D307/08
Abstract: UNSUBSTITUTED OR ALKYL-SUBSTITUTED THF IS OBTAINED BY CATALYTIC HYDROGENATION IN THE GAS PHASE OF C4-DICARBOXYLIC ACIDS AND/OR THEIR DERIVATIVES USING A CATALYST COMPRISING 20BY WEIGHT, PREFERABLY >30BY WEIGHT IN PARTICULARLY FROM 35 TO 90BY WEIGHT, OF AN OXIDIC SUPPORT HAVING ACID CENTERS, AT A HOT SPOT TEMPERATURE OF FROM 240 TO 310°C, PREFERABLY FROM 240 TO 280°C, AND A WHSV OVER THE CATALYST OF FROM 0.01 TO 1.0, PREFERABLY FROM0.02 TO 1, IN PARTICULARLY FROM 0.05 TO 0.5, kg OF STARTING MATERIAL/L OF CATALYST x HOUR.
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公开(公告)号:MY137357A
公开(公告)日:2009-01-30
申请号:MYPI20021995
申请日:2002-05-30
Applicant: BASF AG
Inventor: SCHLITTER STEPHAN DR , SIGWART CHRISTOPH DR , DORFLINGER WALTER , HESSE MICHAEL DR , FISCHER ROLF-HARTMUTH DR
Abstract: POLYTETRAHYDROFURAN, POLYTETRAHYDROFURAN COPOLYMERS, DIESTERS OR MONOESTERS OF THESE POLYMERS ARE PREPARED BY POLYMERIZATION OF TETRAHYDROFURAN IN THE PRESENCE OF AT LEAST ONE TELOGEN AND/OR COMONOMER, WHICH IS IN THE FORM OF SHAPED CATALYST BODIES OR CATALYST PARTICLES HAVING A VOLUME OF THE INDIVIDUAL SHAPE OF THE BODY OR PARTICLE OF AT LEAST 0.05 mm3, PREFERABLY AT LEAST 0.2 mm3, IN PARTICULAR 1 mm3, AND HAS AT LEAST ONE OF THE FEATURES a) AND b) : a)A PORE RADIUS DISTRIBUTION HAVING AT LEAST ONE MAXIMUM IN THE PORE RADIUS RANGE FROM 100 TO 5000 Å,b)A PORE VOLUME OF CATALYST PRES HAVING RADII OF 200 - 3000 Å OF GREATER THAN 0.05 cm3/g AND/OR A PORE VOLUME OF PORES HAVING RADII OF 200 - 5000 Å OF GREATER THAN 0.075 cm3/g AND/OR A PORE VOLUME OF PORES HAVING RADII OF > 200 Å OF GREATER THAN 0.1 cm3/g.
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公开(公告)号:DE59913138D1
公开(公告)日:2006-04-27
申请号:DE59913138
申请日:1999-08-21
Applicant: BASF AG
Inventor: MEYER GERALD DR , SCHWAB EKKEHARD DR , HESSE MICHAEL DR , TRUEBENBACH PETER DR , MUELLER HANS-JOACHIM DR
IPC: B01J21/04 , B01J23/38 , B01J23/40 , B01J23/44 , B01J23/50 , B01J23/66 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/02 , C07C5/02 , C07C5/03 , C07C5/05 , C07C5/09 , C10G45/10 , C10G45/34 , C10G45/40
Abstract: Unsaturated compounds in hydrocarbon streams are hydrogenated over a catalyst which, in the unused state, shows reflections which correspond to the following lattice plane spacings in the X-ray diffraction pattern [in 10-10m]: 4.52, 2.85, 2.73, 2.44, 2.31, 2.26, 2.02, 1.91, 1.80, 1.54, 1.51, 1.49, 1.45 and 1.39 and have specific relative intensities.
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36.
公开(公告)号:MY121082A
公开(公告)日:2005-12-30
申请号:MYPI9903705
申请日:1999-08-27
Applicant: BASF AG
Inventor: MEYER GERALD DR , SCHWAB EKKEHARD DR , HESSE MICHAEL DR , TRUEBENBACH PETER DR , XDCLLER HANS-JOACHIM M DR
IPC: B01J23/38 , B01J21/04 , C07C5/08 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/50 , B01J23/66 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/02 , C07C5/02 , C07C5/03 , C07C5/05 , C07C5/09 , C10G45/10 , C10G45/34
Abstract: UNSATURATED COMPOUNDS IN HYDROCARBON STREAMS ARE HYDROGENATEDOVER A CATALYST WHICH, IN THE UNUSED STATE, SHOWS REFLECTIONSWHICH CORRESPOND TO THE FOLLOWING LATTICE PLANE SPACINGS IN THEX-RAY DIFFRACTION PATTERN [IN 10-10 M]: 4.52, 2.85, 2.73, 2.44,2. 31, 2. 26, 2. 02, 1. 91 , 1. 80 , 1. 54, 1. 51 , 1. 4 9 , 1. 45 AND 1. 39 ANDHAVE SPECIFIC RELATIVE INTENSITIES.
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公开(公告)号:AT272605T
公开(公告)日:2004-08-15
申请号:AT00124609
申请日:2000-11-10
Applicant: BASF AG
Inventor: NOUWEN JAN DR , HOEHN ARTHUR DR , NEUHAUSER HORST DR , FUNKE FRANK DR , SCHUNK STEPHAN ANDREAS , MELDER JOHANN-PETER DR , EGER KNUT DR , HESSE MICHAEL DR , WULFF-DOERING JOACHIM DR
IPC: B01J23/755 , C07B61/00 , C07C209/26 , C07C211/27 , C07C211/35 , C07C211/38 , C07C211/42 , C07C213/02 , C07C217/58
Abstract: Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst, wherein the catalytically active mass of the catalyst contains, after its preparation and before the treatment with hydrogen,22 to 45% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2,1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO,5 to 50% by weight of oxygen-containing compounds of nickel, calculated as NiO, where the molar ratio of nickel to copper is greater than 1,5 to 50% by weight of oxygen-containing compounds of cobalt, calculated as CoO,0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum and/or manganese, calculated as Al2O3 or MnO2.
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公开(公告)号:DE59811573D1
公开(公告)日:2004-07-22
申请号:DE59811573
申请日:1998-11-26
Applicant: BASF AG
Inventor: GROENING CARSTEN DR , HESSE MICHAEL DR , HEINECKE DANIEL DR , KNEUPER HEINZ-JOSEF DR , FRITZ GERHARD DR
IPC: B01J23/89 , B01J27/043 , B01J27/045 , C07D307/28 , C07D309/18 , C07D507/02
Abstract: Unsaturated cyclic ethers are produced from diols in high yield and with low hydrogenated byproduct formation, by use of a supported cobalt-noble metal catalyst that has been doped with sulfur. A process for the production of unsaturated cyclic ethers (I) of formula (1) comprises reaction of a diol (II) of formula: OH-CH(R )-Y-CH(R )-CH(R )-OH (2), in the liquid phase at 150-300 degrees C, in the presence of a supported cobalt- containing catalyst (III) that has not been activated by reduction prior to use. The cobalt containing catalyst (III) is impregnated with a noble metal consisting of platinum, palladium, rhodium, iridium, ruthenium, osmium and/or rhenium on an inert carrier that is doped with sulfur. Y = -(CHR )q- or -(CHR )q-O-; R - R = H or 1-4C alkyl; q = 0-3. An Independent claim is also included for the supported cobalt catalyst (III).
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公开(公告)号:DE19632440A1
公开(公告)日:1998-02-19
申请号:DE19632440
申请日:1996-08-12
Applicant: BASF AG
Inventor: GEHRER EUGEN DR , HESSE MICHAEL DR , GROSCH GEORG HEINRICH DR , BURKHART BERND DR , OFTRING ALFRED DR , KAHMEN MARTIN AUS DEM DR
Abstract: - Mixed hydroxides of polycations, of formula (I) or (II), which are modified with various additives (III) and contain > 0 to 50 wt.% binder(s) (IV) based on aluminium and/or silicon compounds are claimed; in which M((I) = divalent metal ion(s); M(III) = trivalent metal ion(s); A = inorganic anion(s); L = an organic solvent or water; n = the valency of anion A or the average valency of several anions A; x = 0.1-0.5; m = 0-10. (III) are (a) (hetero)aromatic mono- or polycarboxylic acids or salts; (b) aliphatic mono- or polycarboxylic acids or salts with an isocyclic or heterocyclic ring in the side chain; (c) half esters of dicarboxylic acids or salts; (d) carboxylic anhydrides; (e) aliphatic or aromatic sulphonic acids or salts; (f) 8-18 carbon (C) alkyl sulphates; (g) long-chain paraffins; (h) polyether-(poly)ols; (j) alcohols or phenols; or (k) aliphatic 4-44 C dicarboxylic or aliphatic 7-34 C monocarboxylic acids. Also claimed are (a) a method for producing (I) and (II) modified with (III), in which these materials are moulded by consolidation; and (b) a method of preparing alkoxylation products (V) with improved filterability.
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公开(公告)号:DE19624283A1
公开(公告)日:1998-01-02
申请号:DE19624283
申请日:1996-06-18
Applicant: BASF AG
Inventor: SIMON JOACHIM DR , DOSTALEK ROMAN DR , LINGK HEINZ , BECKER RAINER DR , HENNE ANDREAS DR , LEBKUECHER ROLF DR , FREIRE ERDBRUEGGER CRISTINA DR , HESSE MICHAEL DR , KRATZ DETLEF DR
IPC: C07D295/02 , B01J23/72 , B01J37/02 , C07B61/00 , C07D295/03
Abstract: Preparation of N-substituted cyclic amines of formula (I) comprises reacting primary amines of formula R NH2 (II) with diols of formula HO-A-OH (III) in the presence of hydrogen and a catalyst containing copper obtained by impregnating an inert support with an aqueous solution of an ammine complex of a Cu compound (IV) that readily undergoes thermal decomposition, then drying and calcining to give a catalyst containing 5-50 wt.% Cu, calculated as oxide. A = alkylene or (CH2)n-ÄO-CH2)mÜr (optionally substituted by one or more R ); R , R = alkyl, alkoxyalkyl, optionally alkyl- or alkoxy-substituted cycloalkyl, cycloalkylalkyl, aryl or arylalkyl; n, m = 2-8; r = 1-3.
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