公开(公告)号：DE4430478A1

公开(公告)日：1996-02-29

申请号：DE4430478

申请日：1994-08-27

Applicant: BASF AG

Inventor： MEISNER RUPRECHT ,  IRGANG MATTHIAS DR ,  EGER KNUT DR ,  WEIDLICH PETER DR ,  DREYER HEINZ DR

IPC: B01J2/22 ,  B01J2/28 ,  B01J19/30 ,  B01J21/18 ,  C04B35/52 ,  C04B35/532

Abstract: Blanks consist of up to 30-100 wt. % graphite, made from graphite powder contg. 5-100 wt. % rhombohedral crystallised graphite, and opt additives and binders. Prodn. of the blanks is also claimed.

公开(公告)号：DE4419514A1

公开(公告)日：1995-12-07

申请号：DE4419514

申请日：1994-06-03

Applicant: BASF AG

Inventor： SCHNURR WERNER DR ,  FISCHER ROLF DR ,  WULFF-DOERING JOACHIM DR ,  IRGANG MATTHIAS DR ,  NEUHAUSER HORST DR

IPC: C07D307/12 ,  B01J23/34 ,  C07D309/04 ,  C07D309/06 ,  C07D315/00 ,  C07D313/04 ,  C07B41/00 ,  C07B31/00 ,  B01J23/10

Abstract: Heterocyclic aldehydes having the formula (I), in which A, B stand for possibly substituted methylene groups; m, n = 1 to 5 and m+n > 2, are prepared by hydrogenating carboxylic acids having the formula (IIa) or their esters (IIb) derived from C1-C10 alcohols at 200 to 450 DEG C in the presence of a catalyst. The products thus obtained are useful as precursors of cyclohexenone type herbicides.

公开(公告)号：DE59001156D1

公开(公告)日：1993-05-13

申请号：DE59001156

申请日：1990-05-26

Applicant: BASF AG

Inventor： HUELLMANN MICHAEL DR ,  KUEKENHOEHNER THOMAS DR ,  BRENNER KARL ,  BECKER RAINER DR ,  IRGANG MATTHIAS DR ,  SCHOMMER CHARLES DR

IPC: B01J23/04 ,  B01J23/10 ,  B01J23/12 ,  B01J21/06 ,  C07B61/00 ,  C07C45/30 ,  C07C45/61 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/68 ,  C07C45/72 ,  C07C49/203 ,  C07C49/385

Abstract: The muscone of the formula I is prepared by bringing open-chain 2,15-diketones of the general formula II CH3-CO-X-CO-CH3 (II> in which X represents one of the radicals -(-CH2-)@(a> -CH=CH-(-CH2-)@CH=CH- (b> -CH2-CH=CH-(-CH2-)@CH=CH-CH2- (c> -CH2-CH2-CH=CH-(-CH2-)@CH=CH-CH2-CH2- (d) or -CH2-CH2-CH2-CH=CH-(-CH2-)@CH=CH-CH2-CH2-CH2- (e), into contact at temperatures of 300 to 400 DEG C in the presence of 5 to 15 % by weight of water, relative to the amount of catalyst, in the gas phase over a fixed-bed catalyst which contains TiO2, CeO2 or ThO2 as the catalytically active compound and hydrogenating catalytically the unsaturated cyclic ketone formed in this reaction by intramolecular aldol condensation. Furthermore, the open-chain unsaturated ketones of the formulae IIb, IIc and IId and advantageous processes for their preparation and their use as intermediates for a simple industrial muscone synthesis are claimed.

公开(公告)号：DE3935112A1

公开(公告)日：1991-04-25

申请号：DE3935112

申请日：1989-10-21

Applicant: BASF AG

Inventor： KOEHLER ULRICH DR ,  SIEGEL HARDO DR ,  JAEGER PETER DR ,  IRGANG MATTHIAS DR

IPC: C07D211/26 ,  B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/13 ,  C08G59/40 ,  C08G59/50

Abstract: Process for the preparation of amines of the formula … … in which R denotes an H2N-CH2- radical, R denotes a hydrogen atom or R together with R denotes the bridging member -CH2-, by reaction of 1,3,6-tricyanohexane at elevated temperatures and pressures with hydrogen on a catalyst containing, in addition to cobalt, an oxide of alkali metals, alkaline earth metals, rare earths or the metals scandium or yttrium.

公开(公告)号：DE3819437A1

公开(公告)日：1989-12-14

申请号：DE3819437

申请日：1988-06-08

Applicant: BASF AG

Inventor： AMBACH EBERHARD DR ,  SPRAGUE MICHAEL JOLYON DR ,  STEIGLEITER WERNER ,  MROSS WOLF DIETER DR ,  GRUENDLER KARL-HEINZ DR ,  IRGANG MATTHIAS DR

IPC: B01J23/86 ,  C01B3/16

Abstract: The application relates to the preparation of a sulphur-free iron-oxide- and chromium-oxide-containing high temperature conversion catalyst, an iron oxide being used which is prepared from iron carbonyl and which has a mean grain size below 10 mu m and a specific surface area of more than 10 m /g. The chromium oxide component is applied to the iron oxide by precipitation. The chromium component used is CrO3 and is precipitated as insoluble chromium(III) compounds by reducing agents.

公开(公告)号：DE3819436A1

公开(公告)日：1989-12-14

申请号：DE3819436

申请日：1988-06-08

Applicant: BASF AG

Inventor： AMBACH EBERHARD DR ,  EBENHOECH FRANZ LUDWIG DR ,  GRUENDLER KARL-HEINZ DR ,  IRGANG MATTHIAS DR ,  ZIRKER GUENTER DR

IPC: B01J23/86 ,  B01J35/10 ,  C01B3/16 ,  C07C45/41

Abstract: The application relates to a process for the preparation of sulphur-free iron-oxide- and chromium-oxide-containing catalysts having BET surface areas of 20 to 100 m /g and in which more than 80% of the pore volume is in the pore radius range of 30 to 100 nm, an iron(III) oxide prepared from iron carbonyl having a mean grain size below 10 mu m and a BET surface area of greater than 50 m /g and chromium(III) oxide having a mean grain size below 40 mu m and a BET surface area of more than 30 m /g being mechanically mixed as powder or suspension and then tableted.

公开(公告)号：DE3715751A1

公开(公告)日：1988-11-24

申请号：DE3715751

申请日：1987-05-12

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  SAUERWALD MANFRED DR ,  KRUG HERBERT ,  IRGANG MATTHIAS DR

IPC: C07C1/30 ,  B01J23/745 ,  B01J27/043 ,  C07B35/06 ,  C07B61/00 ,  C07C1/00 ,  C07C1/26 ,  C07C11/06 ,  C07C15/04 ,  C07C17/00 ,  C07C17/23 ,  C07C17/354 ,  C07C67/00 ,  C07C9/08

公开(公告)号：DE3521766A1

公开(公告)日：1987-01-02

申请号：DE3521766

申请日：1985-06-19

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  BIFFAR WERNER DR ,  IRGANG MATTHIAS DR ,  MROSS WOLF DIETER DR ,  KROENER MICHAEL DR ,  AMBACH EBERHARD DR

IPC: B01J23/06 ,  B01J23/84 ,  B01J23/85 ,  B01J23/88 ,  B01J27/18 ,  B01J27/188 ,  B01J27/198 ,  B01J27/199 ,  B01J35/04 ,  C01B3/16 ,  C07B61/00 ,  C07C1/00 ,  C07C5/333 ,  C07C15/46 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C233/03 ,  B01J23/74 ,  B01J23/76 ,  B01J27/185

Abstract: A honeycomb catalyst consisting of from 30 to 95% by weight, calculated as Fe2O3, of an iron compound and from 0.1 to 60% by weight, calculated as Al2O3, CeO2 or Cr2O3, of an aluminum, cerium and/or chromium compound and/or from 1 to 50% by weight of an alkali metal compound, in particular potassium, calculated as K2O, and/or from 0.2 to 20% by weight, calculated as MeO3, of an element of sub-group 6, preferably MoO3 and WO3, and/or from 0.1 to 20% by weight, calculated as V2O5, of a compound of vanadium and/or from 0.1 to 20% by weight, calculated as P2O5, of a compound of phosphorus, a process for the preparation of the honeycomb catalyst, and the use of the catalyst for organic reactions.

公开(公告)号：DE2961143D1

公开(公告)日：1981-12-10

申请号：DE2961143

申请日：1979-08-21

Applicant: BASF AG

Inventor： HORNER MICHAEL DR ,  NISSEN AXEL DR ,  LAURER PETER RUDOLF DR ,  IRGANG MATTHIAS DR ,  PASEDACH HEINRICH DR

IPC: B01J31/00 ,  C07B31/00 ,  C07B35/02 ,  C07B61/00 ,  C07C45/00 ,  C07C45/62 ,  C07C47/02 ,  C07C47/21 ,  C07C49/04 ,  C07C67/00

Abstract: Carbonyl compounds R1-CHR2-CHR3-CR4O (I, R1=H or an organic radical; R2-R4=H or C1-C4-alkyl) are prepared by selective hydrogenation of the alpha , beta -unsaturated carbonyl compounds R1-CR2=CR3-CR4O (II) in the liquid phase by means of hydrogen in the presence of a palladium catalyst and of from 15 to 50% by weight, based on (II), of a tertiary amine.

公开(公告)号：DE59505505D1

公开(公告)日：1999-05-06

申请号：DE59505505

申请日：1995-12-07

Applicant: BASF AG

Inventor： IRGANG MATTHIAS DR ,  HESSE MICHAEL DR ,  SCHNURR WERNER DR ,  DR JOACHIM WULFF-DOERING FRANK

IPC: B01J21/06 ,  C01G25/02