公开(公告)号：AU1139897A

公开(公告)日：1997-07-03

申请号：AU1139897

申请日：1996-12-02

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  KISTENMACHER AXEL ,  WOLF GERHARD ,  KNEIP MICHAEL ,  GREIF NORBERT ,  OPPENLANDER KNUT

IPC: C08F216/38 ,  C08F222/00 ,  C14C3/22 ,  C14C3/28

公开(公告)号：DE59305647D1

公开(公告)日：1997-04-10

申请号：DE59305647

申请日：1993-04-08

Applicant: BASF AG

Inventor： WOLF GERHARD ,  OFTRING ALFRED ,  OETTER GUENTER ,  SCHMIDT RICHARD ,  KLOTZ WOLFGANG

IPC: C07H1/00 ,  C07H15/04 ,  C11D1/14 ,  C11D1/66 ,  C11D1/68 ,  C11D1/83

公开(公告)号：ES2093963T3

公开(公告)日：1997-01-01

申请号：ES93908869

申请日：1993-04-01

Applicant: BASF AG

Inventor： WOLF GERHARD ,  OFTRING ALFRED ,  SCHUH GEORG ,  WOLF HELMUT ,  ALT RUDOLF ,  BECHTOLSHEIMER HANS-HEINRICH

IPC: C07H15/04

Abstract: PCT No. PCT/EP93/00791 Sec. 371 Date Sep. 15, 1994 Sec. 102(e) Date Sep. 15, 1994 PCT Filed Apr. 1, 1993 PCT Pub. No. WO93/21196 PCT Pub. Date Oct. 28, 1993The preparation of alkyl glycosides by reaction of aqueous glycoses having a water content of 10-80% by weight with aliphatic primary alcohols having from 5 to 30 C atoms is described, in which (a) the alcohols and the glycoses are employed in a molar ratio of 2:1 to 10:1, (b) 0.1-5% by weight, based on the amount of the glycoses employed, of the acidic form of an anionic surfactant is used as the acidic catalyst having emulsifying properties, (c) 1-30% by weight, based on the amount of the glycoses employed, of alkyl glycosides is used as a further emulsifier, (d) the aqueous glycose is preheated to 50 DEG -90 DEG C. and the preheated aqueous solution of the glycose is metered with effective mixing into the reaction mixture of alcohol, acidic catalyst and emulsifier in such a manner that an emulsion is formed, (e) the reaction is carried out at from 100 DEG to 150 DEG C. and from 10 to 100 mbar, the water introduced into the reaction mixture and the water formed by the reaction being continuously removed by distillation, (f) after the reaction has ended, the acidic catalyst is neutralized by addition of a base such that the resulting mixture has a pH of 8-10, then (g) the excess alcohol is removed by distillation at from 0.01 to 10 mbar down to a residual content of less than 5% by weight, based on the amount of alkyl glycoside present, and (h) the reaction mixture is bleached at pH 8-10 after conversion into an aqueous paste having a content of from 30 to 70% by weight of alkyl glycoside using a compound eliminating active oxygen.

公开(公告)号：ES2080514T3

公开(公告)日：1996-02-01

申请号：ES92918765

申请日：1992-09-04

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  HARTMANN HEINRICH ,  WOLF GERHARD ,  BAUR RICHARD ,  DIESSEL PAUL ,  JAEGER HANS-ULRICH ,  SCHWENDEMANN VOLKER ,  PERNER JOHANNES

IPC: C08F16/14 ,  C08F216/14 ,  C11D3/37

Abstract: PCT No. PCT/EP92/02041 Sec. 371 Date Feb. 10, 1994 Sec. 102(e) Date Feb. 10, 1994 PCT Filed Sep. 4, 1992 PCT Pub. No. WO93/06142 PCT Pub. Date Apr. 1, 1993Copolymers of hydroxyalkyl vinyl ethers are obtainable by cationic or free radical copolymerization of (a) from 99 to 1% by weight of a hydroxyalkyl vinyl ether, (b) from 1 to 99% by weight of an adduct of a C2-C4-alkylene oxide with a hydroxyalkyl vinyl ether and (c) from 0 to 98% by weight of other copolymerizable monomers, and the stated copolymer and hydroxyalkyl vinyl ethers polymerized by cationic or free radical polymerization, which contain the monomers (a) or (b) as sole monomers or as a mixture with other copolymerizable monomers in the form of polymerized units, are used as additives for detergents and cleaning agents in amounts of from 0.1 to 50% by weight.

公开(公告)号：CA2124071A1

公开(公告)日：1993-10-28

申请号：CA2124071

申请日：1993-04-01

Applicant: BASF AG

Inventor： WOLF GERHARD ,  OFTRING ALFRED ,  SCHUH GEORG ,  WOLF HELMUT ,  ALT RUDOLF ,  BECHTOLSHEIMER HANS-HEINRICH ,  HERTEL DIETER

IPC: C07H15/04

Abstract: The preparation of alkyl glycosides by reaction of aqueous glycoses having a water content of 10 - 80% by weight with aliphatic primary alcohols having from 5 to 30 C atoms is described, in which (a) the alcohols and the glycoses are employed in a molar ratio of 2:1 to 10:1, (b) 0.1 - 5% by weight, based on the amount of the glycoses employed, of the acidic form of an anionic surfactant is used as the acidic catalyst having emulsifying properties, (c) 1 - 30% by weight, based on the amount of the glycoses employed, of alkyl glycosides is used as a further emulsifier, (d) the aqueous glycose is preheated to 50 - 90.degree.C and the preheated aqueous solution of the glycose is metered with effective mixing into the reaction mixture of alcohol, acidic catalyst and emulsifier in such a manner that an emulsion is formed, (e) the reaction is carried out at from 100 to 150.degree.C and from 10 to 100 mbar, the water introduced into the reaction mixture and the water formed by the reaction being continuously removed by distillation, (f) after the reaction has ended, the acidic catalyst is neutralized by addition of a base such that the resulting mixture has a pH of 8 - 10, then (g) the excess alcohol is removed by distillation at from 0.01 to 10 mbar down to a residual content of less than 5% by weight, based on the amount of alkyl glycoside present, and (h) the reaction mixture is bleached at pH 8 - 10 after conversion into an aqueous paste having a content of from 30 to 70% by weight of alkyl glycoside using a compound eliminating active oxygen.

公开(公告)号：BRPI0413268A

公开(公告)日：2006-10-10

申请号：BRPI0413268

申请日：2004-08-06

Applicant: BASF AG

Inventor： WOLF GERHARD ,  HUEFFER STEPHAN ,  DECKER JUERGEN ,  SCHERR GUENTER ,  REESE OLIVER

IPC: C08G59/10 ,  C14C11/00 ,  C14C3/22

Abstract: An epichlorohydrinamine polymer has a ratio of amine units to epichlorohydrin units of from 0.8:1.2 to 1.0:1.0, dimethylaminopropylamine and benzylamine preferably being used as amine and/or ammonium units. The novel epichlorohydrinamine polymer is used, for example, for the surface treatment of semifinished leather products and textile materials.

公开(公告)号：DE102004038217A1

公开(公告)日：2006-03-16

申请号：DE102004038217

申请日：2004-08-05

Applicant: BASF AG

Inventor： WOLF GERHARD ,  KLUEGLEIN MATTHIAS ,  HUEFFER STEPHAN ,  PETROVIC SUSANNE

IPC: C08F20/02 ,  C08F220/06 ,  C08F220/10 ,  C08F220/56 ,  C08F228/00 ,  C08F283/01 ,  C14C3/22

Abstract: The present invention relates to copolymers prepared by copolymerization in at least two stages, wherein, in one stage (A) at least one (co)polymer is prepared from a monomer or a mixture of comonomers comprising (a1) from 80 to 100% by weight of at least one ethylenically unsaturated carboxylic acid, (a2) from 0 to 20% by weight of at least one C 1 -C 22 -alkyl ester of at least one ethylenically unsaturated carboxylic acid, (a3) from 0 to 10% by weight of at least one further ethylenically unsaturated compound, data in % by weight being based on the total amount of comonomers of the relevant stage, and the (co)polymer thus obtained is reacted in a subsequent stage (B) with a further comonomer or a further mixture of comonomers comprising (b1) from 0 to 30% by weight of at least one ethylenically unsaturated carboxylic acid, (b2) from 70 to 100% by weight of at least one C 1 -C 22 -alkyl ester of at least one ethylenically unsaturated carboxylic acid, (b3) from 0 to 10% by weight of at least one further ethylenically unsaturated compound, data in % by weight being based on the total amount of comonomers of the relevant further stage.

公开(公告)号：DE10140551A1

公开(公告)日：2003-02-27

申请号：DE10140551

申请日：2001-08-17

Applicant: BASF AG

Inventor： PABST GUNTHER ,  WOLF GERHARD ,  KAST JUERGEN ,  WERNER JUERGEN

IPC: C08G8/28 ,  C08L61/14 ,  C14C3/20 ,  C08G14/08

Abstract: The invention relates to a method for producing a solution of tanning agents containing sulphone. In said method, a) a component A is produced as follows: a1) phenol is reacted with concentrated sulphuric acid or with oleum with an SO3 content of between 20 and 65 wt. %, or with a mixture of sulphuric acid and oleum with an SO3 content of between 20 and 65 wt. %, whereby the molar ratio of total sulphuric acid, calculated in the form of SO3 to phenol is between 0.7: 1 and 1.5: 1, at a temperature of between 100 and 180 DEG C to obtain a mixture containing phenolsulphonic acid, dihydroxydiphenyl sulphone and sulphuric acid, or the individual components are blended to produce a corresponding mixture; a2) said mixture is subsequently condensed at between 40 and 90 DEG C per mol of phenol units present with between 0.25 and 4 mol of urea and between 0.5 and 4 mol of an aliphatic aldehyde comprising between 1 and 6 C atoms, a3) optionally a pH value of between 4 and 5 is set by adding a base; b) a component B is produced as follows: b1) dihydroxydiphenyl sulphone is reacted with between 0.5 and 5 mol of an aliphatic aldehyde comprising between 1 and 6 C atoms and between 0.4 and 2 mol of sodium sulphite per mol of dihydroxydiphenyl sulphone, at a temperature of between 90 and 180 DEG C; b2) optionally a pH value of between 3.5 and 5.5 is set by adding an acid. c) Between 10 and 90 wt. % of component A is mixed with between 90 and 10 wt. % of component B, (the sum of A and B amounting to 100 wt. %) and if not already accomplished in steps a3) and b2), the pH value of the mixture is set at between 3.5 and 5.5.

公开(公告)号：AU736657B2

公开(公告)日：2001-08-02

申请号：AU2292697

申请日：1997-03-27

Applicant: BASF AG

Inventor： KNEIP MICHAEL ,  KISTENMACHER AXEL ,  DANISCH PETER ,  WOLF GERHARD

IPC: C14C3/28 ,  C09D123/08 ,  C14C9/00 ,  C14C9/02

Abstract: Aqueous solutions or dispersions of copolymers obtainable by free-radical copolymerization of(a) from 20 to 90% by weight of at least one monoethylenically unsaturated C4-6-dicarboxylic acid or the anhydride thereof, as component A,(b) from 5 to 50% by weight of at least one olefin having 2 to 6 carbon atoms, as component B,(c) from 5 to 50% by weight of at least one hydrophobic comonomer from the group consisting of long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, long-chain amides of acrylic acid or methacrylic acid, and long-chain alkyl vinyl ethers, as component C,(d) from 0 to 40% by weight of further comonomers which can be copolymerized with the above monomers, as component D,where the sum of the amounts of components A, B, C and, if used, D is 100% by weight, followed by at least partial esterification or hydrolysis and neutralization and/or reaction of the carboxyl groups formed during the hydrolysis with bases, for treating leather and/or fur skins.

公开(公告)号：BR9909538A

公开(公告)日：2000-12-12

申请号：BR9909538

申请日：1999-03-29

Applicant: BASF AG

Inventor： NEGELE ANTON ,  WOLF GERHARD ,  KISTENMACHER AXEL ,  IGL GEORGE

IPC: C08F26/02 ,  C08F126/02 ,  C08F226/02 ,  C14C1/00 ,  C14C3/22 ,  C14C3/28

Abstract: N-Vinyl-containing polymers obtainable by free-radically initiated polymerization of a monomer or monomer mixture of(A) from 5 to 100% by weight of an N-vinylamide or N-vinylamine,(B) from 0 to 95% by weight of monoethylenically unsaturated carboxylic acids having from 3 to 8 carbon atoms or their derivatives,(C) from 0 to 95% by weight of other N-vinyl and/or C-vinyl compounds and(D) from 0 to less than 10% by weight of other copolymerizable monomers,are useful in the form of aqueous solutions or dispersions as tanning materials for self-tanning, pretanning and cotanning of leather pelts and fur pelts and for retanning leather and fur.