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    81.
    发明专利
    未知

    公开(公告)号：BRPI0812054A2

    公开(公告)日：2014-11-18

    申请号：BRPI0812054

    申请日：2008-05-30

    Applicant: BASF SE

    Inventor： ZIERKE THOMAS ,  RHEINHEIMER JOACHIM ,  RACK MICHAEL ,  SMIDT SEBASTIAN PEER ,  ALTENHOFF ANSGAR GEREON ,  SCHMIDT-LEITHOFF JOACHIM ,  CHALLAND NINA

    IPC: C07D231/14

    Abstract: The present invention relates to a process for preparing N-substituted (3-dihalomethylpyrazol-4-yl)carboxamides of the formula (I) in which R1 is optionally substituted phenyl or C3-C7-cycloalkyl, R1a is hydrogen or fluorine, or R1a together with R1 is optionally substituted C3-C5-alkanediyl or C5-C7-cycloalkanediyl, R2 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl or C1-C4-alkoxy-C1-C2-alkyl, X is F or Cl and n is 0, 1, 2 or 3; which comprises A) providing a compound of the formula (II) in which X is F or Cl, Y is Cl or Br and R2 has one of the meanings given above and B) reacting a compound of the formula (II) with carbon monoxide and a compound of the formula (III) in which R1, R1a and n have one of the meanings given above; in the presence of a palladium catalyst; to intermediates used for the preparation according to the process according to the invention, and also to processes for their preparation.

    PROCESS FOR PREPARING DIFLUOROMETHYLPYRAZOLYL CARBOXYLATES
    82.
    发明专利
    PROCESS FOR PREPARING DIFLUOROMETHYLPYRAZOLYL CARBOXYLATES 未知

    公开(公告)号：CA2666746C

    公开(公告)日：2014-10-14

    申请号：CA2666746

    申请日：2007-11-02

    Applicant: BASF SE

    Inventor： RACK MICHAEL ,  SMIDT SEBASTIAN PEER ,  LOEHR SANDRA ,  KEIL MICHAEL ,  DIETZ JOCHEN ,  RHEINHEIMER JOACHIM ,  GROTE THOMAS ,  ZIERKE THOMAS ,  LOHMANN JAN KLAAS ,  SUKOPP MARTIN

    IPC: C07D237/04 ,  C07F7/04

    Abstract: The present invention relates to a process for preparing difluoromethyl-substituted pyrazol-4-yl carboxylates of the formula (I) in which R1 is C1-C8-alkyl, C3-C8-cycloalkyl, C1-C4-alkoxy-C1-C4-alkyl, etc.; and R2 is hydrogen, C1-C4-alkyl, benzyl or phenyl, wherein a) a compound of the general formula (II) in which X is fluorine, chlorine, or bromine, R1 has one of the definitions given above, and R4 is C1-C8-alkyl, C3-C8-cycloalkyl, C2-C8-alkenyl, benzyl or phenyl, is reacted with a silane compound of the general formula R3 nSiCl(4-n) in which n is 1, 2 or 3 and the substituents R3 are each independently selected from C1-C8-alkyl and phenyl, and with a metal which is selected from the metals of groups 1, 2, 3, 4 and 12 of the periodic table and has a redox potential of less than -0.7 V, based on a standard hydrogen electrode (at 25°C and 101.325 kPa); and b) the reaction mixture from step a) is reacted with a compound of the general formula (III) in which R2 has one of the definitions given above.

    СПОСОБ ПОЛУЧЕНИЯ ДИФТОРМЕТИЛПИРАЗОЛИЛКАРБОКСИЛАТОВ
    85.
    发明专利
    СПОСОБ ПОЛУЧЕНИЯ ДИФТОРМЕТИЛПИРАЗОЛИЛКАРБОКСИЛАТОВ 未知

    公开(公告)号：EA017900B1

    公开(公告)日：2013-04-30

    申请号：EA200900607

    申请日：2007-11-02

    Applicant: BASF SE

    Inventor： RACK MICHAEL ,  SMIDT SEBASTIAN PEER ,  LOEHR SANDRA ,  KEIL MICHAEL ,  DIETZ JOCHEN ,  RHEINHEIMER JOACHIM ,  GROTE THOMAS ,  ZIERKE THOMAS ,  LOHMANN JAN KLAAS ,  SUKOPP MARTIN

    IPC: C07D237/04 ,  C07F7/04

    Abstract: Настоящееизобретениеотноситсяк способуполучениядифторметилзамещенныхпиразол-4-илкарбоксилатовформулы (I)вкоторой Rозначает C-C-алкил, C-C-циклоалкил, C-C-алкокси-C-C-алкили т.д.; Rозначаетводород, C-C-алкил, бензилилифенил, причема) соединениеобщейформулы (II)вкоторой X означаетфтор, хлорилибром; Rимеетодноизприведенныхранеезначенийи Rозначает C-C-алкил, C-C-циклоалкил, C-C-алкенил, бензилилифенил, взаимодействуетс силановымсоединениемобщейформулы RSiCl, вкоторой n означает 1, 2 или 3 изаместители Rнезависимодруготдругавыбраныиз C-C-алкилаилифенила, ис металлом, которыйвыбранизметаллов 1, 2, 3, 4 и 12 группыПериодическойсистемыэлементови имеетокислительно-восстановительныйпотенциалменеечем -0,7 V, впересчетенанормальныйводородныйэлектрод (при 25°C и 101,325 кПа); иб) реакционнаясвязьизстадииа) взаимодействуетс соединениемобщейформулы (III)вкоторой Rимеетодноизприведенныхранеезначений.

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