EFFECTIVE NEAR NEUTRAL PH ETCHING SOLUTION FOR MOLYBDENUM OR TUNGSTEN

    公开(公告)号:CA2039029C

    公开(公告)日:1994-07-19

    申请号:CA2039029

    申请日:1991-03-25

    Applicant: IBM

    Inventor: DAVID LAWRENCE D

    Abstract: A neutral or near neutral pH etching solution for effectively etching molybdenum and tungsten including: an aqueous ferricyanide ion solution, a soluble molybdate or tungstate, and an essential compound such that upon combination of said soluble molybdate or tungstate and said essential compound, a heteropoly compound is formed in which said essential compound contributes at least one heteroatom to said heteropoly compound. The etching solution is most preferably used for etching molybdenum or tungsten which is adhered or proximate to a base-sensitive material.

    METHOD OF SYNTHESIZING AMORPHOUS GROUP IIIA-VA COMPOUNDS

    公开(公告)号:CA1280873C

    公开(公告)日:1991-03-05

    申请号:CA570930

    申请日:1988-06-30

    Applicant: IBM

    Inventor: DAVID LAWRENCE D

    Abstract: A METHOD OF SYNTHESIZING AMORPHOUS GROUP IIIA-GROUP VA COMPOUNDS A method of synthesizing amorphous Group IIIA-Group VA compounds. A first solution is prepared which consists of a tris(trialkylsilyl) derivative of either a Group IIIA or Group VA element dissolved in an organic solvent. A second solution is then prepared which consists of a halide of the other of the Group IIIA or Group VA element dissolved in an organic solvent. Then the first and second solutions are mixed such that a Group IIIA-Group VA compound is formed along with a trialkylhalosilane by-product. The final step of the method consists of removing the trialkylhalosilane by-product and organic solvent mixture to form the Group IIIA-Group VA condensed phase. FI 9-86-037

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