-
公开(公告)号:JPH10218990A
公开(公告)日:1998-08-18
申请号:JP35439797
申请日:1997-12-24
Applicant: BASF AG
Inventor: KRATZ DETLEF DR , LIPPERT FERDINAND DR , SCHWAB PETER DR , BOECKH DIETER DR , PERNER JOHANNES DR
IPC: A61K8/84 , A61Q5/00 , A61Q19/00 , B01F17/00 , B01F17/52 , C08G59/50 , C08G67/02 , C08G73/02 , C08G73/06 , C08L63/00 , C09J179/02 , C09K3/00 , C09K15/30 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/28 , C10L10/18 , C10M149/02 , C10M149/14 , C11D3/37 , D06P1/52 , D06P5/08
Abstract: PROBLEM TO BE SOLVED: To provide polyamines having various different characteristics and relatively high amine values by as many methods as possible. SOLUTION: This polyamine polymer is obtd. by reacting a carbon monoxide-1-alkane (pref. ethylene) linear alternating copolymer with ammonia or an amine represented by R-NH2 (wherein R is NH2 , OH, 1-10C alkyl, 6-20C aryl, 7-20C aralkyl, 7-20C alkaryl, or a 3-30C organosilicon group) or with a reagent which releases ammonia or the above-mentioned amine and then hydrogenating the resultant product.
-
公开(公告)号:DE19650537A1
公开(公告)日:1998-06-10
申请号:DE19650537
申请日:1996-12-05
Applicant: BASF AG
Inventor: BAUR RICHARD DR , EHLE BEATE DR , BOECKH DIETER DR , SCHUERMANN GREGOR DR , PERNER JOHANNES DR , SCHNEIDER JUERGEN DR , KAHMEN MARTIN AUS DEM DR , BECKER RAINER DR
IPC: C11D1/52 , C07C233/18 , C07C67/08 , C07C69/28 , C07C231/02 , C07C305/10 , C11D1/72 , C11D1/74 , C11D3/386 , C12N9/96 , D06L1/12 , D06M13/419
Abstract: Enzyme stabilisers in washing or cleaning agents comprise end group capped fatty acid amide alkoxylates of formula (I): R -CO-NH-(CH2)n-O-(AO)x-R (I) R = 5-21C alk(en)yl ; R = 1-4C alkyl ; A = 2-4C alkylene ; n = 2-3 ; and x = 1-6. Also claimed are (i) detergents containing 0.1-50 wt.% (I) and 0.1-10 wt.% synthesised enzyme, (ii) mixtures comprising (A) compounds (I) and (B) fatty alcohol (poly)ether sulphates, fatty alcohol (poly)alkoxylates and/or fatty acid (poly)alkoxylates, (iii) the preparation of mixtures comprising (A) compounds (I) and (B`) fatty acid (poly)alkoxylates corresponding to (A) in which -NH- is replaced by O, (iv) the use of these mixtures in detergents, and (v) detergents containing 0.1-50 wt.% of these mixtures.
-
公开(公告)号:DE19518476A1
公开(公告)日:1996-11-21
申请号:DE19518476
申请日:1995-05-19
Applicant: BASF AG
Inventor: BAUR RICHARD DR , GUEMBEL HELMUT DR , BURKHART BERND DR , OFTRING ALFRED DR , WOLF GERHARD DR , PERNER JOHANNES DR
Abstract: Pivalic acid esters of alkoxylated aliphatic alcohols have formula (I), in which R stands for the residue of an aliphatic alcohol with 6 to 30 C atoms, A stands for the 1,2-propylene grouping, n stands for a mean value from 1 to 20 and m for a mean value from 0 to 6. The compounds (I) are useful as low foaming or anti-foaming surfactants.
-
4.
公开(公告)号:DE19612031A1
公开(公告)日:1996-10-17
申请号:DE19612031
申请日:1996-03-27
Applicant: BASF AG
Inventor: WEIGUNY SABINE DR , PUETTER HERMANN DR , PERNER JOHANNES DR , TRIESELT WOLFGANG DR
IPC: C07C231/12 , C07C233/18 , C07C273/18 , C07C275/10 , C11D3/39 , C25B3/23 , C25B3/29 , C25B3/10 , C25B3/02 , C07C233/16 , D06L3/02 , C07D223/10 , C07D401/12 , C07D403/12 , C07D405/12
Abstract: Prepn. of N-acyloxyalkyl amides of formula (I) or (IV) by electrochemical oxidn. of amides (II) in the presence of carboxylic acids R4 - COOH (III) takes place in the presence of a conductive salt M(SO3R7)x (V) or M(OSO3R7)x (VI) R1 = H, (cyclo)alkyl, heteroaryl or NR5R6 ; R2 = H, (cyclo)alkyl or aryl, or it may form a 2-10C alkylene gp. with R1 ; R3 = H or 1-4C alkyl ; R4 - R6 = H, (cyclo)alkyl or (hetero)aryl ; R7 = (cyclo)alkyl or (hetero)aryl ; M = metal cation ; and x = charge on M. with the provision that (IV) are prepd. from (II) contg. a CH2R3 gp. as R2. The following cpds. are also claimed : N-acetoxymethyl-tri-N,N,N-methyl urea, N-decoyloxymethyl-N-methyl formamide or bis-(N-acetoxymethyl) formamide.
-
公开(公告)号:DE59203524D1
公开(公告)日:1995-10-12
申请号:DE59203524
申请日:1992-04-01
Applicant: BASF AG
Inventor: BAUR RICHARD DR , GUEMBEL HELMUT DR , OFTRING ALFRED DR , PERNER JOHANNES DR , WOLF GERHARD DR
Abstract: Alkanediol bisacetals useful as surface-active substances for industrial purposes, in particular in washing and cleaning agents, have the formula I I where R1 is alkyl or alkenyl of from 6 to 30 carbon atoms, A is 1,2-alkylene of from 2 to 4 carbon atoms, m is from 0 to 50, within each of the pairs R1, A and m the meanings being identical or different, and n is from 2 to 20.
-
公开(公告)号:DE58908529D1
公开(公告)日:1994-11-24
申请号:DE58908529
申请日:1989-11-06
Applicant: BASF AG
Inventor: PERNER JOHANNES DR , DIESSEL PAUL , HARTMANN HEINRICH DR , DENZINGER WALTER , OFTRING ALFRED DR , SCHOENLEBEN WILLIBALD DR
Abstract: The use of copolymers which contain as essential copolymerised units (a) 50 to 99 mol% of units of monoethylenically unsaturated (a) C3- to C8-monocarboxylic acids, monoethylenically unsaturated C4- to C8-dicarboxylic acids, hemiesters of monoethylenically unsaturated C4- to C8-dicarboxylic acids, esters of monoethylenically unsaturated C3- to C8-carboxylic acids, C2- to C30-olefins, styrene, C1- to C3-alkylstyrenes, C1- to C28-alkyl vinyl ethers, vinyl esters of saturated C1- to C8- carboxylic acids or mixtures of units of these monomers and (b) 50 to 1 mol% of units of amides of monoethylenically unsaturated C3- to C8-carboxylic acids with amide groups of the structure … … in which R = C8- to C28- alkyl, … … R , R = H, CH3, C2H5 R = C1- to C28-alkyl, n = 2 to 100 and R = H, R have K values of 8 to 200, or of salts of these copolymers, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and aqueous liquid detergent compositions which contain these copolymers.
-
公开(公告)号:DE58906888D1
公开(公告)日:1994-03-17
申请号:DE58906888
申请日:1989-10-21
Applicant: BASF AG
Inventor: DIESSEL PAUL , PERNER JOHANNES DR , DENZINGER WALTER , HARTMANN HEINRICH DR , RAUBENHEIMER HANS-JUERGEN
Abstract: The use of partially esterified copolymers which can be obtained by copolymerisation of (a) at least one C4- to C28-olefin and (b) ethylenically unsaturated dicarboxylic anhydrides with 4 to 8 C atoms in the molar ratio 1:1 and subsequent partial esterification of the copolymers with reaction products of (A) C1- to C30-alcohols, C8- to C22-fatty acids, C1- to C12-alkylphenols or secondary C2- to C30-amines with (B) at least one C2- to C4-alkylene oxide or tetrahydrofuran in the molar ratio (A):(B) of 1:2 to 50 and hydrolysis of the anhydride groups of the copolymers to carboxyl groups, where the partial esterification of the copolymers is continued until more than 5 to 50% of the carboxyl groups in the copolymers are esterified, as additive to liquid detergent compositions in an amount of 0.1 to 20% by weight and liquid detergent compositions which contain the partially esterified copolymers.
-
公开(公告)号:DE3901613A1
公开(公告)日:1990-08-16
申请号:DE3901613
申请日:1989-01-20
Applicant: BASF AG
Inventor: OFTRING ALFRED DR , BIRNBACH STEFAN DR , FIKENTSCHER ROLF DR , BAUR RICHARD DR , KUD ALEXANDER DR , GOECKEL ULRICH DR , PERNER JOHANNES DR
IPC: C11D1/72 , C07C229/24 , C07C309/13 , C09K3/00 , C09K23/28 , C09K23/42 , C11D3/33
Abstract: Glycerol aminocarboxylates of the formula (I) where n is from 0 to 10 and R is where L is iminodiacetate, aspartate, glutamate, sarcosinate, glycinate, serinate, hydroxyaspartate, ethanolaminoacetate, diethanolamino, alanate or taurinate and X is hydrogen, an alkali metal, ammonium or substituted ammonium, are prepared by esterifying glycerol or polyglycerols which contain up to 10 glycerol units with maleic anhydride or itaconic anhydride and addition of compound L-H where L is as defined above to the double bonds of the esters, and are used as complexing agents.
-
公开(公告)号:DE3829829A1
公开(公告)日:1990-03-22
申请号:DE3829829
申请日:1988-09-02
Applicant: BASF AG
Inventor: WIDDER RUDI DR , GOUSETIS CHARALAMPOS DR , PERNER JOHANNES DR , WOLF HELMUT , BOCHNITSCHEK WERNER DR , OFTRING ALFRED DR
IPC: C07C227/12 , C07C229/22
Abstract: Preparation of the trisodium salt of isoserine-N,N-diacetic acid (I) by reaction of acrylonitrile with aqueous hydrogen peroxide to give glycidamide (II) and further reaction of II with the disodium salt of iminodiacetic acid (III) to give I, by carrying out the process continuously and, in it, successively a) reacting together acrylonitrile and aqueous hydrogen peroxide at pH 7-8 and 30-60 DEG C, b) removing unreacted acrylonitrile by distillation, c) passing the reaction mixture over a solid hydrogen peroxide-decomposing catalyst, d) reacting the aqueous solution of II, obtained in this way, with III at pH 7-9 and 40-90 DEG C, e) reacting the resulting solution with a basic sodium compound at pH 9-14 and 60-95 DEG C, f) removing the ammonia which is produced by distillation and g) if desired, working up the aqueous solution of I, obtained in this way, in a manner known per se to give solid I.
-
公开(公告)号:DE3570448D1
公开(公告)日:1989-06-29
申请号:DE3570448
申请日:1985-02-21
Applicant: BASF AG
Inventor: DENZINGER WALTER , HARTMANN HEINRICH DR , HETTCHE ALBERT DR , KALUZA ULRICH DR , PERNER JOHANNES DR , VAMVAKARIS CHRISTOS DR
IPC: C08F20/00 , C08F20/26 , C08F220/00 , C08F220/04 , C08F220/06 , C08F220/28 , C08F222/02 , C11D3/37
Abstract: The invention relates to copolymers as ingredients for detergents and cleaning agents, which contain monoethylenically unsaturated mono- and dicarboxylic acids, their hydroxyalkyl esters and, if appropriate, other ethylenically unsaturated compounds as monomer units, and are distinguished by a particular calicum-binding and magnesium-binding capacity, detergents and cleaning agents containing these copolymers, and their use in detergents and cleaning agents, in particular as sequestering agents and anti-redeposition agents.
-
-
-
-
-
-
-
-
-