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公开(公告)号：EA003753B1
公开(公告)日：2003-08-28
申请号：EA200100522
申请日：1999-11-06
Applicant: BASF AG
Inventor： MAYWALD VOLKER , STEINMETZ ADRIAN , RACK MICHAEL , GOETZ ROLAND , HENKELMANN JOCHEM , BECKER HEIKE , AISCAR BAYETO JUAN JOSE , GOETZ NORBERT
IPC: C07D231/20
Abstract: Изобретениеотноситсяк способуполучения 1-замещенных 5- и/или 3-гидроксипиразоловформул I и IIгде Rозначает C-Салкил, C-Салкенил, C-Салкинил, C-СциклоалкилилиС-Салкокси, причемэтигруппымогутбытьзамещеныгалогеном, C-Салкокси, фенокси, C-Салкоксикарбонилом, C-Салкилтиокарбониломилициклическойсистемойс 3-14 атомамицикла, причемсложныйалкиловыйэфир 3-алкоксиакриловойкислотыформулы IIIгде R, Rнезависимодруготдругаозначают C-Салкилили C-Сциклоалкил, подвергаютвзаимодействиюс гидразиномформулы IVгде Rимеетвышеприведенноезначение,а) сполучениемпризначениирН, равном 6-11, 5-гидроксипиразоловформулы Iилиб) сполучениемпризначениирН, равном 11-14, 3-гидроксипиразоловформулы II.
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公开(公告)号：NZ511645A
公开(公告)日：2003-07-25
申请号：NZ51164599
申请日：1999-11-06
Applicant: BASF AG
Inventor： GOTZ NORBERT , GOTZ ROLAND , HENKELMANN JOCHEM , BECKER HEIKE , AISCAR BAYETO JUAN JOSE , MAYWALD VOLKER , STEINMETZ ADRIAN , RACK MICHAEL
IPC: C07D231/20
Abstract: A process for preparing a 1-substituted 5- and/or 3-hydroxypyrazole of the formulae I and II, respectively in which R1 is C1 -C6 -alkyl, C2 -C6 -alkenyl, C2 -C6 -alkynyl, C3 -C6 -cycloalkyl or C1 -C4 -alkoxy. These groups may be substituted by halogen, C1 -C4 -alkoxy, phenoxy, C1 -C6 -alkoxycarbonyl, C1 -C6 -alkylthiocarbonyl or by a cyclic ring system having 3-14 ring atoms. An alkyl vinyl of formula V, reacts with phosgene VIa, "diphosgene" VIb or "triphosgene" VIc, producing an acyl chloride of the formula VII. The alkyl vinyl R2 is C1 -C6 -alkyl or C3 -C6 -cycloalkyl. The acyl chloride is converted by the elimination of hydrogen chloride into 3-alkoxyacryloyl chloride of the formula VIII. Esterifying the 3-alkoxyacryloyl chloride with an alcohol of formula IX, in which R3 is C1 -C6 -alkyl or C3 -C6 -cycloalkyl. This results in the alkyl 3-alkoxyacrylate of the formula III, Reacting the alkyl 3-alkoxyacrylate with a hydrazine of the formula IV, where R1 is defined above a)at a pH of 6-11 to give 5-hydroxypyrazoles of the formula I or b) b) at a pH of 11-14 to give 3-hydroxypyrazoles of the formula II. A 1-substituted 5- and/or 3-hydroxypyrazole of the formulae I and II produced from the above stated process.
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公开(公告)号：ES2190243T3
公开(公告)日：2003-07-16
申请号：ES99941607
申请日：1999-08-13
Applicant: BASF AG
Inventor： KINDLER ALOIS , BRUNNER MELANIE , TRAGUT CHRISTIAN , HENKELMANN JOCHEM
IPC: C07B61/00 , C07C29/42 , C07C33/044
Abstract: The invention relates to a method for producing alkyne diols by reacting ketones with acetylenic hydrocarbons in an organic solvent in the presence of a base which contains potassium alcoholates of primary and/or secondary alcohols. The alkyne diols are produced while forming adducts which precipitate out of the reaction mixture and which are comprised of alkyne monoalcohols and/or alkyne diols and a base. The stoichiometries of the reaction partners are selected such that gelatinous adducts are formed which comprise a spherical surface, whereby the reaction mixture remains agitable during the entire reaction.
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公开(公告)号：DE10152117A1
公开(公告)日：2003-04-30
申请号：DE10152117
申请日：2001-10-23
Applicant: BASF AG
Inventor： ROHDE THORSTEN , STAMM ARMIN , HENKELMANN JOCHEM
IPC: C07B61/00 , C07C263/10 , C07C265/10 , B01J31/02 , C07F9/53
Abstract: The invention relates to a method for producing isocyanates by reacting the corresponding primary amines with phosgene in an inert solvent. According to said method, between 0.01 and 50 mol. % of a phosphine oxide is used, in relation to the total amount of primary amine and isocyanate formed in the reaction solution.
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公开(公告)号：DE10137480A1
公开(公告)日：2003-02-13
申请号：DE10137480
申请日：2001-08-03
Applicant: BASF AG
Inventor： RUST HARALD , BURKART KIRSTEN , FAUST TILLMANN , HENKELMANN JOCHEM , KINDLER ALOIS , KNOLL CHRISTIAN
IPC: C07D233/70 , C07D213/67 , C07D263/42 , C07D213/66
Abstract: Production of 5-alkoxy oxazoles (I) comprises heating an alkyl alpha -isocyanoalkanoate ester (II) at a temperature above 80 deg C in the presence of an auxiliary agent and simultaneously separating the product from the reaction mixture. Production of 5-alkoxy oxazoles of formula (I) comprises heating an alkyl alpha -isocyanoalkanoate ester of formula (II) at a temperature above 80 deg C in the presence of an auxiliary agent and simultaneously separating the product from the reaction mixture. R1 = optionally substituted 1-6C alkyl; R2 = H or optionally substituted 1-6C alkyl. An Independent claim is also included for a process for producing pyridoxine derivatives of formula (IX), comprising: (1) converting an amino acid of formula (III) to an ester of formula (IV); (2) converting (IV) to a formamido ester of formula (IV); (3) converting (IV) to (II), converting (II) to (I) as above; (4) reacting (I) with a protected diol of formula (VI) to form a Diels-Alder adduct of formula (VII); and (5) converting (VII) to (IX) by acid treatment and deprotection. R3, R4 = protecting groups or together form a protecting group.
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Patent Agency Ranking
公开(公告)号：MX212908B
公开(公告)日：2003-02-10
申请号：MXPA00008276
申请日：2000-08-24
Applicant: BASF AG
Inventor： BROECKER FRANZ JOSEF , RUETTER HEINZ , KAIBEL GERD , BOETTCHER ARND , HENKELMANN JOCHEM
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公开(公告)号：CA2450077A1
公开(公告)日：2002-12-19
申请号：CA2450077
申请日：2002-06-07
Applicant: BASF AG
Inventor： BOETTCHER ARND , VANOPPEN DOMINIC , KNOLL KONRAD , HENKELMANN JOCHEM , ARNDT JAN-DIRK
IPC: B01J21/08 , B01J23/46 , B01J37/18 , C07C5/10 , C07C29/141 , C07C29/17 , C07C29/19 , C07C29/20 , C07C51/36 , C07C209/48 , C07C209/72 , C07C211/03 , C07C211/11 , C07C211/35 , C07C211/36 , C07D295/023 , C08F8/04 , C07C29/136
Abstract: The invention relates to a method for hydrogenating at least one organic compound by bringing said organic compound into contact with a gas containin g hydrogen in the presence of a catalyst. Said catalyst comprises ruthenium as an active metal, either alone or combined with another metal of the subgroup s I, VII or VIII of the periodic table, deposited on an amorphous silicon dioxide-based support. Said catalyst is obtained by i): treating the amorpho us silicon dioxide-based support with a halogen-free aqueous solution of a low- molecular ruthenium compound, and subsequently drying the treated support at a temperature of less than 200 ~C, ii) reducing the solid matter obtained in i ) with hydrogen at a temperature ranging from 100 to 350 ~C, wherein step ii) is carried out directly after step i).
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公开(公告)号：CZ20020851A3
公开(公告)日：2002-10-16
申请号：CZ20020851
申请日：2000-08-31
Applicant: BASF AG
Inventor： BUSCH RALPH , KNEUPER HEINZ-JOSEF , WEBER THEODOR , MULLER WINFRIED , STAMM ARMIN , HENKELMANN JOCHEM
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公开(公告)号：BR0016214A
公开(公告)日：2002-09-17
申请号：BR0016214
申请日：2000-11-27
Applicant: BASF AG
Inventor： STAMM ARMIN , TZ ROLAND G , TZ NORBERT G , HENKELMANN JOCHEM , KNEUPER HEINZ-JOSEF , WOLF BERND
Abstract: The invention relates to a method for producing o-choromethyl benzenecarbonyl chlorides of formula (I), wherein R -R can be the same or different and stand for hydrogen, C1-C4-alkyl, halogen or trifluoromnethyl, by converting benzocondensed lactones of formula (II), wherein R -R have the aforementioned meaning, with gaseous or liquid phosgene and the dimers or trimers thereof. The inventive method is characterized in that the conversion is carried out in the presence of catalytical amounts of a Lewis acid and catalytical amounts of a phosgenation catalyst
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公开(公告)号：DE10044165A1
公开(公告)日：2002-03-21
申请号：DE10044165
申请日：2000-09-07
Applicant: BASF AG
Inventor： HENKELMANN JOCHEM , MAAS HEIKO , STAMM ARMIN , RINK HEINZ-PETER , JUNG WERNER-ALFONS
IPC: C07C271/12 , C09D5/46 , C07C269/00 , C08G63/91
Abstract: The invention relates to polycarbamates of general formula (I), wherein R and R' are identical or similar and represent alkyl groups comprising 1-4 C atoms and n is a number with an average value of between 2 - 5.
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