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    143.
    发明专利
    未知

    公开(公告)号：DE4400837A1

    公开(公告)日：1995-07-20

    申请号：DE4400837

    申请日：1994-01-14

    Applicant: BASF AG

    Inventor： KANAND JUERGEN ,  ROEPER MICHAEL ,  PINKOS ROLF ,  PACIELLO ROCCO ,  THOME ALFRED

    IPC: B01J21/16 ,  B01J27/18 ,  B01J29/06 ,  C07B61/00 ,  C07C27/00 ,  C07C29/17 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C43/15 ,  C07C45/51 ,  C07C47/02 ,  C07C29/153 ,  C07C29/74 ,  C07C45/42 ,  C07C45/78 ,  C07C45/00

    Abstract: In a process for producing n-butyraldehyde and/or n-butanol, (a) 1,3-butadiene is reacted with an alcohol having the formula ROH, in which the residue R stands for a non-substituted C2-C20-alkyl or alkenyl group that may also be substituted by 1 or 2 C1-C10-alkoxy or hydroxy groups, a C6-C10-aryl or C7-C11-aralkyl group or the methyl group, at a higher temperature and pressure in the presence of a Brönsted acid or in the presence of a compound of an element from groups IB, VIIb or VIIIb of the periodic table of elements with phosphoric or nitrogenated ligands, so as to produce a mixture of addition compounds having the formulas (II) and (III); (b) the addition compound III is isomerised into the addition compound II; (c) the addition compound II is isomerised in the presence of a homogeneous or heterogeneous transition metal element catalyst in liquid phase or in the presence of a heterogeneous transition metal element-containing catalyst in gaseous phase, so as to produce an enol ether having the formula (IV); and (d) n-butyraldehyde and/or n-butanol are generated by reacting said enol ether IV with hydrogen and water or with water in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous transition metal element-containing catalyst in the gaseous phase. The alcohol ROH released is recycled into the partial reaction (a).

    PROCESS FOR PREPARING FORMIC ACID
    144.
    发明专利
    PROCESS FOR PREPARING FORMIC ACID 未知

    公开(公告)号：CA2681508A1

    公开(公告)日：2008-10-02

    申请号：CA2681508

    申请日：2008-03-18

    Applicant: BASF AG

    Inventor： SAVA XAVIER ,  ROEPER MICHAEL ,  CHALLAND NINA

    IPC: C07C51/00 ,  C07C51/02 ,  C07C53/02 ,  C07C53/06

    Abstract: The invention relates to a method for producing formic acid by generating the corresponding ammonium formate by means of catalytic hydrogenation of c arbon dioxide with hydrogen on a catalyst comprising a metal of groups 8 thr ough 10 of the periodic system, in the presence of a primary, secondary, and /or tertiary amine, and by cleaving the ammonium formate by heating it in fo rmic acid and the amine, characterized in that the primary, secondary, or te rtiary amine is selected from the amines of formula I or the mixtures thereo f, R1 through R3 being identical or different and being hydrogen, linear or branched alkyl radicals having 1 to 18 carbon atoms, cycloaliphatic radicals having 5 to 7 carbon atoms, aryl radicals and/or aryl alkyl radicals, at le ast one of the radicals R1 to R3 carrying a hydroxyl group, and that said hy drogenation is performed in a solvent having a boiling point of >=105°C a t normal pressure, and that the formic acid is obtained in the hydrogenation reaction mixture comprising the high-boiling solvent by thermal cleavage of the ammonium formate and distillation of the formic acid.

    146.
    发明专利
    未知

    公开(公告)号：DE102005055817A1

    公开(公告)日：2007-05-24

    申请号：DE102005055817

    申请日：2005-11-21

    Applicant: BASF AG

    Inventor： HANEFELD PHILLIP ,  BOEHM VOLKER ,  SIGL MARCUS ,  CHALLAND NINA ,  ROEPER MICHAEL ,  WALTER HANS-MICHAEL ,  VOIT BRIGITTE ,  KUEHN FRITZ ELMAR ,  HIJAZI AHMED ,  NARAYANAN RADHA KRISHNAN

    IPC: C08F110/10 ,  C08F2/06 ,  C08F4/52 ,  C08F10/10 ,  C08F210/10

    Abstract: Preparation of highly reactive isobutene homo- or copolymers having M n =from 500 to 45 000 by polymerizing isobutene in the liquid phase in the presence of a dissolved, dispersed or supported boron-containing catalyst complex, by using, as the catalyst complex, a protic acid compound I [H + ] m+1 [R 1 R 2 R 3 B-(-A m+ -BR 5 R 6 -) n -R 4 ] (m+1)- .L x (I) R 1 to R 6 each independently aliphatic, heterocyclic or aromatic, fluorinated hydrocarbon radicals having in each case from 1 to 18 carbon atoms, or silyl groups comprising C 1 to C 18 hydrocarbon radicals, A nitrogen-containing bridging member which forms covalent bonds to the boron atoms via its nitrogen atoms, L neutral solvent molecules, n=0 or 1, m=0 or 1 and x is >=0.

    147.
    发明专利
    未知

    公开(公告)号：DE50207666D1

    公开(公告)日：2006-09-07

    申请号：DE50207666

    申请日：2002-09-26

    Applicant: BASF AG

    Inventor： SAVA XAVIER ,  SLANY MICHAEL ,  ROEPER MICHAEL

    IPC: B01J31/28 ,  B01J31/24 ,  C07F9/6568 ,  C07B61/00 ,  C07C51/14 ,  C07C57/03 ,  C07C67/38 ,  C07C69/533 ,  C07F9/6571

    Abstract: A system comprising a diphosphine of the formula R 1 >P-(CH) n -PR 2 R 3 where R 1 is a divalent radical which together with the phosphorus atom to which it is linked forms an unsubstituted or substituted 2-phosphatricyclo[3.3.1.1{3,7}]decyl group or a derivative thereof in which one or more of the carbon atoms are replaced by heteroatoms, R 2 , R 3 are each, independently of one another, a monovalent radical having from 1 to 20 atoms or together form a divalent radical having from 2 to 20 atoms, n is 4 or 5, and a mixture of such diphosphines, and palladium or a palladium compound is suitable as carbonylation catalyst for the carbonylation of a conjugated diene.

    150.
    发明专利
    未知

    公开(公告)号：DE10328713A1

    公开(公告)日：2005-01-20

    申请号：DE10328713

    申请日：2003-06-25

    Applicant: BASF AG

    Inventor： STUEER WOLFRAM ,  SCHEIDEL JENS ,  VOS HARTWIG ,  BASLER PETER ,  ROEPER MICHAEL

    IPC: C07F15/00 ,  C08F4/26 ,  B01J31/40

    Abstract: A process for separating a mixture comprising a) a monoolefinically unsaturated compound which is obtainable by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, or a saturated compound obtained by hydrogenating such a compound, b) a compound which is obtainable by adding more than two of the terminal olefins mentioned in a) or a compound obtained by hydrogenating such a compound, and c) a compound which contains a transition metal, is homogeneous with respect to the mixture and is suitable as a catalyst for preparing a monoolefinically unsaturated compound by adding two terminal olefins which bear the functional groups required to prepare the monoolefinically unsaturated compound containing at least two functional groups, by means of a semipermeable membrane to obtain a permeate and a retentate in such a way that the weight ratio of component b) to component c) in the mixture fed to the semipermeable membrane is smaller than in the retentate.

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