COMPUESTOS DE 3-AMINO-1,2-BENZISOTIAZOL PARA COMBATIR LAS PLAGAS DE ANIMALES.

    公开(公告)号:ES2335318T3

    公开(公告)日:2010-03-24

    申请号:ES07727214

    申请日:2007-03-22

    Applicant: BASF SE

    Abstract: Compuestos de 3-Amino-1,2-benzisotiazol de la fórmula I que se representa por las siguientes dos fórmulas isoméricas **(Ver fórmula)** en donde n es 0; R1 se selecciona de alquilo C1-C6, haloalquilo C1-C6, alquenilo C2-C6, haloalquenilo C2-C6, alquinilo C2-C6, haloalquinilo C2-C6, cicloalquilo C3-C8, halocicloalquilo C3-C6, alcoxi C1-C6, haloalcoxi C1-C6, en donde los radicales mencionados pueden ser no sustituidos o pueden llevar 1, 2 o 3 radicales, seleccionados del grupo que consiste de ciano, nitro, amino, alcoxi C1-C4, alquiltio C1-C4, alquilsulfinil C1-C4, alquilsulfonil C1-C4, haloalcoxi C1-C4, haloalquiltio C1-C4, (alcoxi C1-C4)carbonil, (alquilo C1-C4)amino, di(alquilo C1-C4)amino, aminocarbonil, (alquilo C1-C4)aminocarbonil, di(alquilo C1-C4)aminocarbonil, cicloalquilo C3-C8 y fenil, siendo posible para el fenil que no sea sustituido, parcial o completamente halogenado y/o llevar 1, 2 o 3 sustituyentes, independientemente uno del otro seleccionados del grupo que consiste de CN, alquilo C1-C4, haloalquilo C1-C4, alcoxi C1-C4 y haloalcoxi C1-C4 y R2, R3 y R4 son independientemente uno del otro seleccionados del grupo que consiste de hidrógeno, halógeno, ciano, azido, nitro, alquilo C1-C6, cicloalquilo C3-C8, haloalquilo C1-C4, alcoxi C1-C4, alquiltio C1-C4, alquilsulfinil C1-C4, alquilsulfonil C1-C4, haloalcoxi C1-C4, haloalquiltio C1-C4, alquenilo C2-C6, alquinilo C2-C6, (alcoxi C1-C4)carbonil, amino, (alquilo C1-C4)amino, di(alquilo C1-C4)amino, aminocarbonil, (alquilo C1-C4)aminocarbonil, di(alquilo C1-C4)aminocarbonil, sulfonil, sulfonilamino, sulfenilamino, sulfanilamino y C(=O)-R2a o C(=O)-R3a o C(=O)-R4a, y en donde, R2a o R3a o R4a se seleccionan del grupo que consiste de hidrógeno, hidroxi, alcoxi C1-C6, amino, alquilo C1-C6, aril, aril-alquilo C1-C6, (alquilo C1-C6)-amino, di-(alquilo C1-C6)-amino, 3- a 7-miembros heteroarilo o heteroarilo-alquilo C1-C4, en donde el anillo heteroarilo contiene como miembros del anillo 1, 2 o 3 heteroátomos, seleccionados del grupo que consiste de nitrógeno, oxígeno, azufre, un grupo SO, SO2 o NR2b o NR3b o NR4b, y en donde R2b o R3b o R4b son hidrógeno, alquilo C1-C6 o (alquilo C1-C6)-carbonil; R5 se selecciona del grupo que consiste de OR5a, alquilo C1-C10, alquenilo C2-C10, alquinilo C2-C10, cicloalquilo C3-C10, aril-alquilo C1-C4, heteroarilo-alquilo C1-C4, heterociclil-alquilo C1-C4, en donde estos radicales pueden ser no sustituidos, parcial o completamente halogenados y/o pueden llevar 1-4 radicales seleccionados del grupo que consiste de alcoxi C1-C10, alquiltio C1-C10, alquilsulfinil C1-C10, alquilsulfonil C1-C10, haloalcoxi C1-C10, haloalquiltio C1-C10, (alcoxi C1-C10)carbonil, ciano, nitro, amino, (alquilo C1-C10)amino, di-(alquilo C1-C10)amino, cicloalquilo C3-C10 y fenil, siendo posible para el fenil que no sea sustituido, parcial o completamente halogenado y/o llevar 1-3 sustituyentes seleccionados del grupo que consiste de CN, alquilo C1-C6, haloalquilo C1-C6, alcoxi C1-C6, haloalcoxi C1-C6, y en donde R5a se selecciona de hidrógeno, alquilo C1-C10, acil C1-C10, cicloalquilo C3-C10, alquenilo C2-C10, alquinilo C2-C10, aril, aril-alquilo C1-C4, heteroarilo y heteroarilo-alquilo C1-C4, heterociclil o heterociclil-alquilo C1-C4 y en donde todos los radicales pueden ser no sustituidos, parcial o completamente halogenados y/o pueden llevar 1, 2 o 3 radicales, seleccionados del grupo que consiste de ciano, nitro, amino, alcoxi C1-C4, alquiltio C1-C4, alquilsulfinil C1-C4, alquilsulfonil C1-C4, haloalcoxi C1-C4, haloalquiltio C1-C4, (alcoxi C1-C4)carbonil, (alquilo C1-C4)amino, di(alquilo C1-C4)amino y cicloalquilo C3-C8; o los enantiómeros, diastereómeros o sales de estos, con la condición que el compuesto de 3-amino-1,2-benzisotiazol de la fórmula I no sea 4-Metoxi-N-(2-metil-2-fenilpropil)benzo[d]isotiazol-3-amina, no se 4-Metoxi-N-(2-metil-2-(6-metilpiridin-2-il)propil)benzo[d]isotiazol-3-amina o no sea N1-(4-Metilbenzo[d]isotiazol-3-il)propano-1,3-diamina.

    Quinoline derivatives and their use as pesticides

    公开(公告)号:ZA200808722B

    公开(公告)日:2009-12-30

    申请号:ZA200808722

    申请日:2008-10-13

    Applicant: BASF SE

    Abstract: This invention relates to quinoline derivatives of formula I wherein R1, R2, R3 are each independently halogen, hydroxy, cyano, amino, nitro, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C4-alkoxy-C1-C4-alkoxy, C3-C7-cycloalkyl-C1-C4-alkoxy, C(OH)(CF3)2, C1-C6-haloalkyl, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, C(Ra)-O, C(Ra)-NORb, C(-O)ORx, or C(-O)NRxRy; Ra is hydrogen or C1-C4-alkyl; Rb is hydrogen, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, or C2-C4-haloalkenyl; Rx, Ry are each independently hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-thioalkyl-C1-C4-alkyl, C1-C4-alkyl-S(-O)C1-C4-alkyl, C1-C4-alkyl-S(-O)2C1-C4-alkyl, C3-C6-cyloalkyl, C1-C4-alkyl-C3-C6-cycloalkyl, C3-C6-alkenyl, C3-C6-alkinyl; R4, R5, R6, R7 are each independently hydrogen, halogen, cyano, amino, nitro, hydroxy, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, or C(-O)ORc; Rc is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, or C2-C6-alkinyl; m and n are each independently 1, 2, 3, 4, or 5; p is 0, 1, 2, 3, 4, or 5; and the N-oxides, enantiomers, diastereomers and salts thereof, processes and intermediates for the preparation of compounds I, use of compounds I for combating insects, acarids, or nematodes and a method for treating, controlling, preventing or protecting animals against infestation or infection by parasites using compounds I.

    Method for manufacturing aryl carboxamides

    公开(公告)号:AU2009245791A1

    公开(公告)日:2009-11-12

    申请号:AU2009245791

    申请日:2009-05-06

    Applicant: BASF SE

    Abstract: A process for preparing arylcarboxamides of the formula (I) where Ar=a mono- to trisubstituted phenyl, pyridyl or pyrazolyl ring, where the substituents are selected from halogen, C1-C4-alkyl and C1-C4-haloalkyl; M=thienyl or phenyl, which may bear a halogen substituent; Q=direct bond, cyclopropylene, fused bicyclo[2.2.1]heptane or bicyclo[2.2.1]heptene ring; R1=hydrogen, halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, mono- to trisubstituted phenyl, where the substituents are selected from halogen and trifluoromethylthio, or cyclopropyl; by reacting an acid chloride of the formula (II) with an arylamine (III) in a suitable nonaqueous solvent, wherein, in the absence of an auxiliary base, a) the acid chloride (II) is initially charged, b) a pressure of from 0 to 700 mbar is established, c) the arylamine (III) is metered in an approximately stoichiometric amount and d) the product of value is isolated.

    Method for preparing 1,3,4-substituted pyrazol compounds

    公开(公告)号:AU2009243550A1

    公开(公告)日:2009-11-12

    申请号:AU2009243550

    申请日:2009-05-04

    Applicant: BASF SE

    Abstract: The present invention relates to a process for preparing 1,3-substituted pyrazole compounds of the formula I in which X is especially a CX1X2X3 group in which X1, X2 and X3 are each independently especially hydrogen, fluorine or chlorine, R1 is C1-C4-alkyl or cyclopropyl, and R2 is hydrogen, CN or a CO2R2a group in which R2a is especially C1-C6-alkyl, comprising the following steps: i) reacting a compound of the formula II with a hydrazone of the formula III where the variables X and R2 in formula II are each as defined for formula I, Y is oxygen, an NRy1 group or an [NRy2Ry3]+Z- group, R3 is OR3a or an NR3bR3c group, and where the variable R1 in formula III is as defined for formula I, R4 and R5 are each independently hydrogen, C1-C6-alkyl, optionally substituted phenyl, where at least one of the R4 and R5 radicals is different from hydrogen, and where R4 and R5 together with the carbon atom to which they are bonded may also be a 5- to 10-membered saturated carbocycle; ii) treating the reaction product obtained with an acid in the presence of water.

    COMPUESTOS DE PIRIMIDILMETIL-SULFONAMIDA

    公开(公告)号:PE20091395A1

    公开(公告)日:2009-10-21

    申请号:PE2009000222

    申请日:2009-02-13

    Applicant: BASF SE

    Abstract: SE REFIERE A COMPUESTOS DERIVADOS DE PIRIMIDIN-4-ILMETIL-SULFONAMIDA DE FORMULA (I) DONDE Ra ES HALOGENO, CN, NH2, NO2, ENTRE OTROS; R ES H, ALQUILO(C1-C4), HALOALQUILO(C1-C4), ALCOXI(C1-C4), ENTRE OTROS; A ES FENILENO O HETEROARENODIILO DE 5 O 6 MIEMBROS OPCIONALMENTE SUSTITUIDOS CON Rb, EN DONDE Rb ES HALOGENO, CN, NO2, ALQUILO(C1-C4), ENTRE OTROS; Y ES -O-, -C(=O)-, -O-CH2-, -CH2-, ENTRE OTROS; Het ES HETEROARILO DE 5 O 6 MIEMBROS OPCIONALMENTE SUSTITUIDO CON Rc, EN DONDE Rc ES HALOGENO, NO2, NH2, ENTRE OTROS; n ES DE 0 A 3. SON COMPUESTOS PREFERIDOS: 4-(3-CLORO-5-TRIFLUOROMETIL-PIRIDIN-2-ILOXI)-N-(2-METOXI-PIRIMIDIN-4-ILMETIL)-3-METIL-BENCENOSULFONAMIDA, 4-(3-TRIFLUOROMETIL-PIRIDIN-2-ILOXI)-N-(2-METOXI-PIRIMIDIN-4-ILMETIL)-3-METIL-BENCENOSULFONAMIDA, 4-(5-TRIFLUOROMETIL-PIRIDIN-2-ILOXI)-N-(2-METOXI-PIRIMIDIN-4-ILMETIL)-3-METIL-BENCENOSULFONAMIDA, ENTRE OTROS. SE REFIERE TAMBIEN A UNA COMPOSICION AGROQUIMICA. DICHOS COMPUESTOS TIENEN ACTIVIDAD FUNGICIDA SIENDO UTILES PARA COMBATIR HONGOS DANINOS FITOPATOGENOS

    169.
    发明专利
    未知

    公开(公告)号:AT443990T

    公开(公告)日:2009-10-15

    申请号:AT03725066

    申请日:2003-04-22

    Applicant: BASF SE

    Abstract: 3-Heteroaryl-substituted isoxazolines of the formula I where: X is substituted 5-membered heteroaryl having one to four nitrogen atoms or one to three nitrogen atoms and one oxygen or sulfur atom or one oxygen or sulfur atom; or substituted 6-membered heteroaryl having one to four nitrogen atoms; where the abovementioned 5-membered heteroaryl is not pyrazolyl or thienyl; R 1 -R 7 are hydrogen, alkyl or haloalkyl; Y is unsubstituted or substituted aryl, or benzo[1,4]dioxonyl, benzo[1,3]dioxolanyl, 2,3-dihydrobenzofuranyl or benzimidazole; or unsubstituted or substituted 5- to 6-membered heteroaryl; and their agriculturally useful salts, processes and intermediates for their preparation, and the use of these compounds or of the compositions comprising these compounds for controlling unwanted plants are described.

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