公开(公告)号：DE19729381A1

公开(公告)日：1999-01-14

申请号：DE19729381

申请日：1997-07-10

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  LIANG SHELUE DR ,  SCHWAB EKKEHARD DR ,  WULFF-DOERING JOACHIM DR ,  STERZEL HANS-JOSEF DR

IPC: B01J23/14 ,  B01J23/26 ,  B01J23/34 ,  B01J23/745 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07B41/06 ,  B01J27/224

公开(公告)号：DE19636078A1

公开(公告)日：1998-03-12

申请号：DE19636078

申请日：1996-09-05

Applicant: BASF AG

Inventor： PREISS THOMAS DR ,  HENKELMANN JOCHEM DR ,  WULFF-DOERING JOACHIM DR ,  STUTZ SUSANNE DR

IPC: C07D295/04 ,  B01J31/26 ,  C07C209/60 ,  C07C211/08 ,  C07C211/23 ,  C07C211/25 ,  C07C211/26 ,  C07C211/43 ,  C07C211/54 ,  C07C211/21

Abstract: Preparation of N-alkyl-substituted amino-alkynes of formula R1-C IDENTICAL C-CR2R3-NR4R5 comprises the heterogeneous reaction of an alkyne of formula R1-C IDENTICAL CH, a carbonyl compound of formula R2R3C=O and an amine of formula R4-NH-R5 using an unsupported copper catalyst derived from malachite. R1 = H, alkyl, haloalkyl, cycloalkyl, aryl, alkoxy, alkoxyalkyl or hydroxyalkyl; R2, R3 = H, alkyl, haloalkyl, aryl or alkoxy; R4, R5 = H, alkyl, haloalkyl, aryl, alkoxy or hydroxyalkyl; or NR4R5 = a 5-6 membered heterocycle.

公开(公告)号：DE19507007A1

公开(公告)日：1996-08-29

申请号：DE19507007

申请日：1995-02-28

Applicant: BASF AG

Inventor： MELDER JOHANN-PETER DR ,  WULFF-DOERING JOACHIM DR ,  GUTSCHOVEN FRANK ,  WITZEL TOM DR ,  HARDER WOLFGANG DR

IPC: C07D295/02 ,  B01J23/38 ,  B01J23/46 ,  B01J23/54 ,  B01J23/56 ,  B01J23/89 ,  C07B61/00 ,  C07C209/14 ,  C07C209/16 ,  C07C209/24 ,  C07C209/26 ,  C07C211/03 ,  C07C211/10 ,  C07C213/02 ,  C07C215/14 ,  B01J23/48 ,  B01J27/057 ,  B01J27/185 ,  C07C209/60 ,  C07C211/14 ,  C07C211/16 ,  C07C213/00 ,  C07C215/08 ,  C07D295/023

公开(公告)号：DE59503154D1

公开(公告)日：1998-09-17

申请号：DE59503154

申请日：1995-11-29

Applicant: BASF AG

Inventor： SCHNURR WERNER DR ,  FISCHER ROLF DR ,  WULFF-DOERING JOACHIM DR ,  HESSE MICHAEL DR

IPC: B01J23/10 ,  B01J23/06 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/105 ,  C07C47/14 ,  C07C47/19 ,  C07C47/198 ,  C07C47/228 ,  C07C47/28 ,  C07C47/32

Abstract: Prodn. of aldehydes (I) comprises the gas phase hydrogenation of carboxylic acids or esters (II) at 200-450 degrees C under 0.1-20 bar in the presence of a catalyst having a catalytically active mass comprising 80-99.9 wt.% zirconium oxide and 0.1-20 wt.% lanthanide elements. R1-R4 = H; 1-6C alkyl; 3-6C cycloalkyl; aryl; 7-12C alkylphenyl; or 7-12C phenylalkyl; or R1+R3 = 1-4C alkoxy; OPh; NHMe; NMe2; or halo; or R = OH; or NH2.

公开(公告)号：DE19642553A1

公开(公告)日：1998-04-16

申请号：DE19642553

申请日：1996-10-15

Applicant: BASF AG

Inventor： PREISS THOMAS DR ,  HENKELMANN JOCHEM DR ,  WULFF-DOERING JOACHIM DR ,  STUTZ SUSANNE DR ,  RUEHL THOMAS DR

IPC: C07B61/00 ,  C07C213/00 ,  C07C213/02 ,  C07C215/08 ,  C07C217/08 ,  B01J23/72 ,  C07C215/14

Abstract: Preparation of N-hydroxyalkyl -substituted amino-alkynol derivatives of formula (I) involves reaction of an alkyne of formula R1-C IDENTICAL CH (II) with a 1-oxa-3-aza-heterocycloalkane of formula (III) over a heterogeneous catalyst comprising a compound of a first or second transition group metal. R1= H, alkyl, haloalkyl, cycloalkyl, aryl, alkoxy, alkoxyalkyl, hydroxyalkyl or -CR2R3-N(R4)-A-OH; R2-R4 = H, alkyl, haloalkyl, cycloalkyl, aryl, alkoxy, alkoxyalkyl or hydroxyalkyl; A = 2-5C alkylene (optionally substituted by one or more of alkyl, haloalkyl, aryl, alkoxy, hydroxy and hydroxyalkyl).

公开(公告)号：DE19641707A1

公开(公告)日：1998-04-16

申请号：DE19641707

申请日：1996-10-10

Applicant: BASF AG

Inventor： BECKER RAINER DR ,  BROECKER FRANZ JOSEF DR ,  KAIBEL GERD DR ,  PINKOS ROLF DR ,  WULFF-DOERING JOACHIM DR

IPC: B01J25/02 ,  B01J8/02 ,  B01J8/06 ,  B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  B01J19/26 ,  C07B61/00 ,  C07C29/17 ,  C07C31/20

Abstract: The invention concerns a process for preparing 1,4-butanediol by continuous catalytic hydrogenation of 1,4-butinediol in that 1,4-butinediol is reacted with hydrogen in the liquid continuous phase in the presence of a heterogeneous hydrogenation catalyst at temperatures of between 20 and 300 DEG C, a pressure of between 1 and 200 bar and values of the liquid-side mass transfer coefficients kLa, relative to the volume, of between 0.1 s and 1s , a) with a catalyst suspended in the reaction medium, wherein, when a packed bubble column is used, it is operated in the upwards mode and at a ratio of the amount of gas leaving the reaction vessel to the amount fed thereto of between 0.99:1 and 0.4:1, or b) is guided upwards in parallel flow through a fixed bed reactor operated in the circulating gas mode, the ratio between the amount of gas fed to the reaction vessel and the amount of gas leaving the latter being maintained between 0.99:1 and 0.4:1.

公开(公告)号：DE19616738A1

公开(公告)日：1997-10-30

申请号：DE19616738

申请日：1996-04-26

Applicant: BASF AG

Inventor： HEINEKE DANIEL DR ,  HAGEMEYER ALFRED DR ,  WULFF-DOERING JOACHIM DR ,  RIEKER CHRISTOPHER WILLIAM DR ,  SCHNURR WERNER DR

IPC: B01J21/06 ,  B01J23/02 ,  B01J35/10 ,  C07C5/41 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  C07C5/22 ,  C07C15/00 ,  C07C15/073 ,  C07C15/08

Abstract: This invention concerns a catalyst, particularly for producing aromatic compounds with 6 to 8 atoms from non-aromatic hydrocarbons with straight-chained, branched and/or cyclic alkyl or alkylene chains, respectively, with 6 to 8 carbon atoms containing essentially at least one oxide of a transition metal of the IVB group of the periodic system and, optionally, one alkaline metal or alkaline earth metal compound and/or a compound of the third main or secondary group of the periodic system and/or a rare earth metal zinc compound or a mixture thereof, with the condition that the compounds change into the corresponding oxides upon calcination.

公开(公告)号：DE4443704A1

公开(公告)日：1996-06-13

申请号：DE4443704

申请日：1994-12-08

Applicant: BASF AG

Inventor： SCHNURR WERNER DR ,  FISCHER ROLF DR ,  WULFF-DOERING JOACHIM DR ,  HESSE MICHAEL DR

IPC: B01J23/10 ,  B01J23/06 ,  C07B61/00 ,  C07C45/41 ,  C07C47/02 ,  C07C47/105 ,  C07C47/14 ,  C07C47/19 ,  C07C47/198 ,  C07C47/228 ,  C07C47/28 ,  C07C47/32 ,  C07C47/00 ,  C07B41/00

Abstract: Prodn. of aldehydes (I) comprises the gas phase hydrogenation of carboxylic acids or esters (II) at 200-450 degrees C under 0.1-20 bar in the presence of a catalyst having a catalytically active mass comprising 80-99.9 wt.% zirconium oxide and 0.1-20 wt.% lanthanide elements. R1-R4 = H; 1-6C alkyl; 3-6C cycloalkyl; aryl; 7-12C alkylphenyl; or 7-12C phenylalkyl; or R1+R3 = 1-4C alkoxy; OPh; NHMe; NMe2; or halo; or R = OH; or NH2.

公开(公告)号：DE19720606A1

公开(公告)日：1998-12-10

申请号：DE19720606

申请日：1997-05-16

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PINKOS ROLF DR ,  WULFF-DOERING JOACHIM DR

IPC: C07C29/149 ,  C07B61/00 ,  C07C29/19 ,  C07C31/135 ,  C07C31/27 ,  C07C31/13

Abstract: The invention relates to a method for producing alcohols containing cycloaliphatic groups by hydrogenating, in the presence of a catalyst, carboxylic acids having aromatic rings or anhydrides or esters thereof. According to said method, hydrogenation takes places in a single stage and the catalyst contains at least one element of the group comprising Pd, Ru and Pt as well as the element Re in metallic or oxidic form.

公开(公告)号：DE19653629A1

公开(公告)日：1998-06-25

申请号：DE19653629

申请日：1996-12-20

Applicant: BASF AG

Inventor： WULFF-DOERING JOACHIM DR ,  STICHERT WOLFRAM ,  SCHUETH FERDI PROF DR

IPC: B01J21/06 ,  B01J23/10 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  C01G25/00 ,  C01G25/02 ,  C04B35/48 ,  C04B35/482 ,  B01J27/053 ,  C07B35/02 ,  C07B35/04 ,  C07B61/00 ,  C07B37/00 ,  C07B37/08 ,  C07C1/04 ,  C07C5/00

Abstract: At least 80 wt.% monoclinic zirconium dioxide comprises a BET surface area of NOTLESS 100 m /g. Also claimed are: (a) at least 80 wt.% monoclinic sulphated dioxide with a sulphate content of 0.05-10 wt.%, calculated as SO4, and BET surface area of NOTLESS 100 m /g; (b) methods of preparing the dioxides; (c) zirconium dioxide prepared by these methods; (d) mouldings containing zirconium dioxide of these types; (e) the production of mouldings by pressing the zirconium dioxide; and (f) a catalyst with a support of zirconium dioxide of these types, doped with 0.1-20 wt.% catalytically active metal(s).